Polyethylene Glycol Coated NiFe2O4 Nanoparticles Produced by Solution Plasma Method for Biomedical Applications

الموضوعات :

Masoud Shabani ¹ , Ehsan Saebnoori ² , Ali Hassanzadeh-Tabrizi ³ , Hamid Reza Bakhsheshi-Rad ⁴

1 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran.
2 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran.
3 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran.
4 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran.

تاريخ الإرسال : 03 الأربعاء , ذو القعدة, 1441 تاريخ التأكيد : 23 الثلاثاء , ذو القعدة, 1441 تاريخ الإصدار : 15 الأحد , ربيع الأول, 1442

الکلمات المفتاحية: nanoparticles, Polyethylene glycol, nickel ferrite, Magnetic properties, Solution Plasma,

ملخص المقالة :

The structural and magnetic properties of the polyethylene glycol (PEG) coated nickel spinel ferrite (NiFe2O4) nanoparticles have been reported in the present study. NiFe2O4 nanoparticles were prepared by solution plasma method using KOH + Na2Co3 as electrolyte. The prepared powder of nickel ferrite nanoparticles was annealed at 800 ˚C for two h and used for further study. The X-ray analysis confirmed the formation of a cubic spinel single-phase structure. The crystallite size, lattice parameter, and X-ray density of the PEG-coated NiFe2O4 nanoparticles were calculated using XRD data. TEM and FTIR studies revealed the presence of PEG on nickel ferrite nanoparticles and reduced agglomeration in the NiFe2O4 nanoparticles. The pulse-field hysteresis loop tracer technique studied the magnetic properties at room temperature. The magnetic parameters such as saturation magnetization, remanence magnetization, and coercivity have been obtained. These magnetic parameters were get decreased by PEG coating.

المصادر:

[1] Y. Sharma, V. Srivastava, Comparative studies of removal of Cr (VI) and Ni (II) from aqueous solutions by magnetic nanoparticles, Journal of Chemical & Engineering Data 56(4) (2011) 819-825.

[2] P.L. Hariani, D. Desnelli, F. Fatma, I.P. Rizki, S. Salni, Synthesis and characterization of Fe3O4 nanoparticles modified with polyethylene glycol as antibacterial material, The Journal of Pure and Applied Chemistry Research 7(2) (2018) 122.

[3] S. Sam, A.S. Nesaraj, Preparation of MnFe2O4 nanoceramic particles by soft chemical routes, Int J Appl Sci Eng 9(4) (2011) 223-239.

[4] Y. Prabhu, K.V. Rao, B.S. Kumari, V.S.S. Kumar, T. Pavani, Synthesis of Fe 3 O 4 nanoparticles and its antibacterial application, International Nano Letters 5(2) (2015) 85-92.

[5] R.H. Vignesh, K.V. Sankar, S. Amaresh, Y.S. Lee, R.K. Selvan, Synthesis and characterization of MnFe2O4 nanoparticles for impedometric ammonia gas sensor, Sensors and Actuators B: Chemical 220 (2015) 50-58.

[6] S. Maensiri, C. Masingboon, B. Boonchom, S. Seraphin, A simple route to synthesize nickel ferrite (NiFe2O4) nanoparticles using egg white, Scripta materialia 56(9) (2007) 797-800.

[7] J. Zhu, D. Xiao, J. Li, X. Yang, Y. Wu, Characterization of FeNi3 alloy in Fe–Ni–O system synthesized by citric acid combustion method, Scripta materialia 54(1) (2006) 109-113.

[8] L. Guo, X. Shen, X. Meng, Y. Feng, Effect of Sm3+ ions doping on structure and magnetic properties of nanocrystalline NiFe2O4 fibers, Journal of Alloys and Compounds 490(1-2) (2010) 301-306.

[9] S.M. Peymani-Motlagh, A. Sobhani-Nasab, M. Rostami, H. Sobati, M. Eghbali-Arani, M. Fasihi-Ramandi, M.R. Ganjali, M. Rahimi-Nasrabadi, Assessing the magnetic, cytotoxic and photocatalytic influence of incorporating Yb 3+ or Pr 3+ ions in cobalt–nickel ferrite, Journal of Materials Science: Materials in Electronics 30(7) (2019) 6902-6909.

[10] P. Sivakumar, R. Ramesh, A. Ramanand, S. Ponnusamy, C. Muthamizhchelvan, Preparation of sheet like polycrystalline NiFe2O4 nanostructure with PVA matrices and their properties, Materials Letters 65(9) (2011) 1438-1440.

[11] M. Shabani, E. Saebnoori, S. Hassanzadeh-tabrizi, H.R. Bakhsheshi-Rad, Novel synthesis of nickel ferrite magnetic nanoparticles by an in‐liquid plasma, Journal of Materials Science: Materials in Electronics 32(8) (2021) 10424-10442.

[12] Y. Toriyabe, S. Watanabe, S. Yatsu, T. Shibayama, T. Mizuno, Controlled formation of metallic nanoballs during plasma electrolysis, Applied physics letters 91(4) (2007) 041501.

[13] S. Samimi-Sedeh, E. Saebnoori, A. Hassanzadeh, An optimization and characterization study on sodium ferrate production by electrochemical method, Journal of Advanced Materials and Processing 7(4) (2019) 3-11.

[14] M. Jalaly, M. Enayati, P. Kameli, F. Karimzadeh, Effect of composition on structural and magnetic properties of nanocrystalline ball milled Ni1− xZnxFe2O4 ferrite, Physica B: Condensed Matter 405(2) (2010) 507-512.

[15] L. Whittig, X‐ray diffraction techniques for mineral identification and mineralogical composition, Methods of Soil Analysis: Part 1 Physical and Mineralogical Properties, Including Statistics of Measurement and Sampling 9 (1965) 671-698.

[16] K. Kombaiah, J.J. Vijaya, L.J. Kennedy, M. Bououdina, Studies on the microwave assisted and conventional combustion synthesis of Hibiscus rosa-sinensis plant extract based ZnFe2O4 nanoparticles and their optical and magnetic properties, Ceramics International 42(2) (2016) 2741-2749.

[17] S. Yadav, S. Shinde, A. Kadam, K. Rajpure, Structural, morphological, dielectrical and magnetic properties of Mn substituted cobalt ferrite, Journal of Semiconductors 34(9) (2013) 093002.

[18] P.G. Rasmussen, Far-infrared and Raman spectra ofpseudo-tetrahedral complexes of ethylenedimorpholene, Transition Metal Chemistry 11(11) (1986) 416-418.

[19] Z. Zhou, J. Xue, J. Wang, H. Chan, T. Yu, Z. Shen, NiFe 2 O 4 nanoparticles formed in situ in silica matrix by mechanical activation, Journal of applied physics 91(9) (2002) 6015-6020.

[20] S. Saafan, T. Meaz, E. El-Ghazzawy, M. El Nimr, M. Ayad, M. Bakr, AC and DC conductivity of NiZn ferrite nanoparticles in wet and dry conditions, Journal of magnetism and Magnetic materials 322(16) (2010) 2369-2374.

[21] C.-S. Lin, C.-C. Hwang, T.-H. Huang, G.-P. Wang, C.-H. Peng, Fine powders of SrFe12O19 with SrTiO3 additive prepared via a quasi-dry combustion synthesis route, Materials Science and Engineering: B 139(1) (2007) 24-36.

[22] Z.E. Gahrouei, S. Labbaf, A. Kermanpur, Cobalt doped magnetite nanoparticles: Synthesis, characterization, optimization and suitability evaluations for magnetic hyperthermia applications, Physica E: Low-dimensional Systems and Nanostructures 116 (2020) 113759.

[23] M. Lickmichand, C.S. Shaji, N. Valarmathi, A.S. Benjamin, R.A. Kumar, S. Nayak, R. Saraswathy, S. Sumathi, N.A.N. Raj, In vitro biocompatibility and hyperthermia studies on synthesized cobalt ferrite nanoparticles encapsulated with polyethylene glycol for biomedical applications, Materials Today: Proceedings 15 (2019) 252-261