Investigation of the Factors Affecting on the Granulation of ZrB2 Nano-Particles Synthesized by Using Na Metal as Reductant
الموضوعات :
mehdi emamalizadeh
1
(1. Ph.D. Student, Department of Chemistry, Faculty of Sciences, Malek-e-Ashtar University of Technology, Shahin-Shahr, Iran)
Mohammad Mahdavi
2
(Associate Professor, Department of Chemistry, Faculty of Sciences, Malek-e-Ashtar University of Technology, Shahin-Shahr, Iran)
Arash Shokrolahi
3
(Assistant Professor, Department of Chemistry, Faculty of Sciences, Malek-e-Ashtar University of Technology, Shahin-Shahr, Iran)
الکلمات المفتاحية: Zirconium Diboride, Ultrahigh-temperature ceramics, Low-temperature synthesis,
ملخص المقالة :
In the present research, as the initial phase, the ZrB2 nano-powders are synthesized at low-temperature through heating a mixture of ZrCl4, B2O3, and Na metal in a molar ratio of 1:2:4 at 650 to 950 ºC under pure argon atmosphere. The effect of various parameters involved in the phase transformation and morphology of the ZrB2 nano-powders are investigated. Also examined systematically are the influence of the stoichiometry of the reactants and different factors bearing upon the granulation of ZrB2 particles. In particular, we have studied the effects of adding NaCl salt as well as thermodynamic parameters playing roles in the above synthesis process. The morphology of samples is characterized with the help of scanning and transmission electron microscopy. The XRD results shows the presence of ZrB2 single phase in the product. The obtained images indicate that the synthesized powders have a crystallite nano metric size ranging from 11 to 26 nm. The TEM images and statistical size distribution also reveal the presence of a narrow size distribution of ZrB2 nano-particles. Also explored and reported are various enhancement parameters like temperature, reaction time, and diluent component on the quality of the synthesized ZrB2 nano-powders.
[1] M.S. Asl, B. Nayebi, Z. Ahmadi, M.J. Zamharir, and M. Shokouhimehr, Effects of carbon additives on the properties of ZrB2-based composites: A review, Ceram. Int., 44(2018), No. 7, p. 7334.
[2] W.G. Fahrenholtz, G.E. Hilmas, I.G. Talmy, and J.A. Zaykoski, Refractory diborides of zirconium and hafnium, J. Am. Ceram. Soc., 90(2007), No. 5, p. 1347.
[3] F. Monteverde, R. Savino, and M. De Stefano Fumo, Dynamic oxidation of ultra-high temperature ZrB2–SiC under high enthalpy supersonic flows, Corros. Sci., 53(2011), No. 3, p. 922.
[4] Z. Amirsardari, R.M. Aghdam, M. Salavati-Niasari, and S. Niasari, enhanced thermal resistance of GO/C/phenolic nanocomposite by introducing ZrB2 nanoparticles, Composites Part B, 76(2015), p. 174.
[5] F. Monteverde, A. Bellosi, and S. Guicciardi, Processing and properties of zirconium diboride-based composites, J. Eur. Ceram. Soc., 22(2002), No. 3, p. 279.
[6] S.Q. Guo, Densification of ZrB2-based composites and their mechanical and physical properties: A review, J. Eur. Ceram. Soc., 29(2009), No. 6, p. 995.
[7] Y. Zhang, R. Li, Y. Jiang, B. Zhao, H. Duan, J. Li, and Z. Feng, J. Solid State Chem. 184 (8) (2011). 2047.
[8] G. H. Liu, J. T. Li, and K. X. Chen, Advances in Applied Ceramics. 112 (3) (2013) 109- 124.
[9] Gadakary Saikumar, Asit K. Khanra, and R. Veerabau, Advances in Applied Ceramics.113 (7) (2014) 419- 426.
[10] W.M. Guo, G.J. Zhang, Reaction processes and characterization of ZrB2 powder prepared by boro/carbothermal reduction of ZrO2 in vacuum, J. Am. Ceram. Soc. 92 (2009) 264-267.
[11] C.W. Bale, E. Bélisle, P. Chartrand, S.A. Decterov, G. Eriksson, K. Hack, I.H. Jung, Y.B. Kang, J. Melançon, A.D. Pelton, C. Robelin, and S. Petersen, FactSage thermochemical software and databases ― recent developments, Calphad, 33(2009), No. 2, p. 295.
[12] W. M. Guo, G. J. Zhang, L. Silvestroni, New borothermal reduction route to synthesize submicrometric ZrB2 powders with low oxygen content, J. Am. Ceram. Soc. 94 (2011) 3702-3705.
[13] J.K. Sonber and A.K. Suri, Adv. Appl. Ceram., 110, (2011).321-334.
[14] R.A. Andrievskii, S.E. Kravchenko, S.P. Shilkin, Inorg. Mater. 31 (1995) 965.
[15] H. Kobayashi, M. Katoh, Y. Kamiyama and T. Mitamura, J. Ceram. Soc. Jpn, 100, (1992). 172-177.
[16] H. Morito, K.Koshijib, H. Yamaneb, Low-temperature synthesis of ZrB2 powder from oxides using Na, J. of Asian Ceramic Societies 5 (2017) 479-481.
[17] Outokumpu HSC. Chemistry for Windows, v 6.0. Outokumpu Research on Information Service, Pori.
[18] H. Zhu, H. Li, H. Song, Sh. Liao. Front. Chem. China, 4(2) (2009) 154–159.
[19] S. Gadakarya, M. J. Davidsonb, R. Veerababuc, A.K. Khanra, J. Min. Metall. Sect. B-Metall. 52 (1) B (2016) 69–76.
