Theoretical study of the effect of internal strain on the bond length and rate of hydrolysis in cyclic amides
الموضوعات : International Journal of Heterocyclic Chemistry
Mahdieh Entezari
1
(Department of Chemistry, Islamic azad university, mahshahr branch, Mahshahr, Iran)
Shahab Zomorod bakhsh
2
(Department of Chemistry, Islamic azad university, mahshahr branch, Mahshahr, Iran)
الکلمات المفتاحية:
ملخص المقالة :
The internal strain in cyclic amides are explained as a factor of resonance that are effected on the bond length C-N and are a major factor of rates of hydrolysis. The cyclic amides in this study are optimized by Gaussian program and the bond length of C-N in the rings are studied by HF/6-31G*.
