Aminolysis of selected methylpyrimidines in protic solvents
الموضوعات : International Journal of Heterocyclic Chemistry
Hossein Eshtiagh-Hosseini
1
(Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, Mashhad, P.O. Box 917791436, Iran)
Masoud Mirzaei
2
(Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, Mashhad, P.O. Box 917791436, Iran)
الکلمات المفتاحية: Protein, Hybrid, Proline, Hydrogen bonding, Polyoxometallates, Molybdenum, Keggin, Peptide,
ملخص المقالة :
Crystallographic data analyses indicate that three types of prolinium cations, along with two types of hydrogen bonding, produce and stabilize the helical structure of triprolinium 12-phosphomolybdate. There are similarities between this organic-inorganic compound and peptides/proteins. The stronger “conventional” hydrogen bonds and the less common C-H…O attractions play critical roles in generating and stabilizing the DNA-like network.
