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  • حذف فلز روی از محلول های آبی با استفاده از نانو ذرات دی اکسید منگنز

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عنوان URL للمقالة


رقم المقالة : JEST-1607-2803 (R1) زيارة : 73 الصفحة: 109 - 123

10.22034/jest.2018.11038

نوع المخطوط: ابحاث

حذف فلز روی از محلول های آبی با استفاده از نانو ذرات دی اکسید منگنز

الموضوعات :

سید مهدی حسینی فرد 1 (دانشجوی دکتری مهندسی محیط زیست، دانشکده مهندسی عمران، دانشگاه صنعتی شاهرود *( مسوول مکاتبات).)
هادی قربانی 2 (دانشیار ، گروه مهندسی آب وخاک ،دانشگاه صنعتی شاهرود)

تاريخ الإرسال : 30 الثلاثاء , رمضان, 1437 تاريخ التأكيد : 27 الأربعاء , ذو الحجة, 1437 تاريخ الإصدار : 08 الجمعة , شوال, 1439

الکلمات المفتاحية: حذف روی, نانو ذرات دی اکسید منگنز, سنتز الکتروشیمیایی کاتدی, محلول های آبی,

ملخص المقالة :

زمینه و هدف: آلودگی آب به فلزات سنگین یکی از معضلات مهم زیست محیطی است. هدف از این پژوهش بررسی میزان حذف فلز روی از محلول های آبی با استفاده از نانو ذرات دی اکسید منگنز بود. روش بررسی: ابتدا نانو ذرات دی اکسید منگنز به روش ترسیب الکتروشیمیایی کاتدی سنتز گردید و تاثیر پارامترهای pH، زمان تماس، غلظت نانو ذرات و اثر غلظت اولیه بر فرآیند جذب روی در سیستم ناپیوسته مورد بررسی قرار گرفت. جهت شناسایی نانو ذرات دی اکسید منگنز از پراش پرتو ایکس(XRD)، طیف سنج مادون قرمز(FT-IR) و میکروسکوپ الکترونی روبشی(SEM) استفاده گردید. ایزوترم های جذب لانگمیر و فرندلیچ و همچنین سینتیک های جذب فلز روی توسط جاذب نانو ذرات دی اکسید منگنز بر اساس مدل های شبه مرتبه اول و شبه مرتبه دوم بررسی شد.یافته ها: تصاویر میکروسکوپ الکترونی روبشی نشان داد که اندازه این ذرات 30 تا 50 نانومتر است. نتایج نشان داد که با افزایش pH، درصد حذف و ظرفیت جذب روی افزایش یافت و در pH 6 به حداکثر خود یعنی 4/90 درصد رسید. افزایش زمان تماس و میزان جاذب باعث افزایش راندمان جذب شد. در بررسی ایزوترم های جذب، داده های آزمایشی مطابقت بیشتری با مدل لانگمیر نشان دادند. ظرفیت جذب لانگمیر 71/285 میلی گرم بر گرم بدست آمد. همچنین داده های بدست آمده در این تحقیق برای جاذب نشان داد که جذب روی از مدل سینتیک شبه مرتبه دوم تبعیت می کند.بحث و نتیجه گیری: نتایج این پژوهش نشان داد که نانو ذرات دی اکسید منگنز به عنوان جاذب مناسب توانایی بالایی در جذب فلز روی از محیط های آبی دارند.

المصادر:


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  16. Su Q. , Pan B. , Wan S. , Zhang W. , Lv L. , (2010). “Use of hydrous manganese dioxideasa potential sorbent for selective removal of lead, cadmium, and zinc ions from water”. J.Colloid Interface Sci. 349, 607–612.
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  18. M. Hosseinifard, H. Ghorbani, M. Aghazadeh, M. Hosseinifard. (2016). The syntheses of Manganese Dioxide Nano-particles (MnO2) and its Efficiency on Copper Removal from Aqueous Solutions. J.of Water & Wastewater (Ab va Fazilab), Vol. 27, No.3 (103).(In Persian).
    19.
  19. M. Aghazadeh, M. Hosseinifard .(2013)."Electrochemical preparation of ZrO2nanopowder: Impact of the pulse current on the crystal structure, composition andmorphology".Ceramics International, Volume 39, Issue 4, Pages 4427-4435.
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  21. Ho YS, Wase  DAJ, Forster CF.(1996). “Kinetic studies of competitive heavy metaladsorption by sphagnum moss peat”. Environmental Technology. 17(1):71-77.
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  22. Othman Hakami; Yue Zhang; Charles J. Banks. (2012). “Thiol-functionalisedmesoporous silica-Coated magnetite nanoparticles for high efficiency removal and recovery of  Hg from water”, water research, Volume 46, Issue 12, p. p. 3913-3922, August.
    23.
  23. Jooyoung Song; Hyeyoung Kong; Jyonjsik Jang.(2011). “Adsoption of heavy metal ionsfrom aqueous solution by polyrhodanine-encapsulated magnetic nanoparticles”. J. ofColloid and Interface Science, Valume 359, P. P. 505-511, Joly.
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  29. Donglin Zhao , Xin Yang, Hui Zhang , Changlun Chen , Xiangke Wang .(2010). “Effect of  environmental conditions on Pb(II) adsorption on-MnO2”. Chemical  EngineeringJournal, 164, 49-55.
    30.
  30. F. Ge, M. M. Li, H. Ye, B. X. Zhao.(2012).Effective removal of heavy metal ions Cd2+, Zn2+, Pb2+, Cu2+ from aqueous solution by polymer-modified magnetic nanoparticles. J. of Hazardous Materials 211– 212, 366– 372.
    31.
  31. Lijing Dong, Zhiliang Zhu, Hongmei Ma, Yanling Qiu, Jianfu Zhao.(2010)”Simultaneos  adsorption of  lead and cadmium on Mno2-loaded resin”. Journal of Environmental science,  22(2), 225-229.
    32.
  32. Donghee, P., Lim, S.R., Yun, Y.S., and Park, J.M.. (2008).“Development of a newCr(VI) biosorbent fromagricultural biowaste.” Bioresource Technology, 99 (18), 8810-8818.
    33.
  33. Ozcar, M; and Sengil, I.A, .(2005) "Adsorption of metal complex dyes fromaqueous Solutions by pin sawdust." J. of Bioresource Technology, 96(7), 791-795.
    34.
  34. Qingdong Qin , Qianqian Wang , Dafang Fu , Jun Ma . (2011).“An efficient  approach for  Pb(II) and Cd(II) removal using manganese dioxide formed insitu”.Chemical Engineering Journal,  172, 68-74.
    35.
  35. Katal, R., Hasani, E., Farnam, M., Sharifzadeh, M., Ghayyam, A. (2009). “Charcoal ash as nanoadsorbent for Ni2+ adsorption and its application for wastwarer treatment”. Journal of chemical and Engineering Data, DOI: 10.1021/Je 200953h.
    36.
  36. Yueming Ren, Ni Yan, Jing Feng, Jun Ma, Qing Wen, Nan Li, Qing Dong .(2012).“Adsorptionmechanism of copper and lead ions onto graphene nanosheet/d-MnO2”.Materials Chemistryand Physics,136:538e544.
    37.
  37. M. Hosseinifard, H. Ghorbani, M. Aghazadeh, M. Hosseinifard.(2016) Removal of lead from Aqueous Solutions Using Manganese Dioxide Nanoparticles Synthesized by Electrochemical Method. J.of Environmental Sciences, Vol. 13, No.4.(In Persian)
    38.
  38. Chao Luo, Rongyan Wei, Dan Guo, Shengfang Zhang, Shiqiang Yan. (2013)."Adsorptionbehavior of MnO2  functionalized multi-walled carbon nanotubes for the removal ofcadmium from aqueous solutions". Chemical Engineering Journal 225, 406-415.
    39.

 

 

 

 

 

 

 

 

 

_||_

  1. Sobhi, N., (1998). “Removal of heavy metals from industrial wastewater by ash (dissertation)”.Tehran:  Tarbiat  Modarres University; (In Persian).
    2.
  2. Kumar, Y.P., King, P., and Prasad, V.S.R.K. (2006). “Removal of copper from aqueous solution using Ulva fasciata sp.—a marine green algae.” J. Hazard. Mater. 137, 367-373.
    3.
  3. Huang, G.L., Zhang, H.Y., Shi, J.X. and Langrish, T.A.G. (2009). “Adsorption of chromium(VI) from aqueous solutions using cross-linked magnetic chitosan beads.” Ind. Eng. Chem. Res., 48, 2646-2651.
    4.
  4. Sahu, R.C., Patel, R., and Ray, B.C. (2011). “Adsorption of Zn (II) on activated red mud: Neutralized by CO2.” Desalination, 266 (1-3), 93-97.
    5.
  5. O, Connell, D. W., Birkinshaw, C., and O,Dwyer, T. F. (2008). “Heavy metal adsorbents prepared from the modification of cellulose”. J. Bioresource Technol., 99(15), 6709-6724.
    6.
  6. Samadi MT, Saghi MH, Ghadiri K, Hadi M,Beikmohammadi M.(2010). “Performance ofsimple nano zeolite Y and modified nano zeolite Y in phosphor removal from aquesolutions”.Iranian Journal of Health and Environment. 2010;3(1):27- 36 (In Persian).
    7.
  7. Chen, J.H., Wang, Y.J., Cui, Y.X., Wang, S.Q., and Chen, Y.C. (2010). “Adsorption anddesorption of Cu (II), Zn (II), Pb (II), and Cd (II) on the soils amended with nanoscalehydroxyapatite.” J. of Environmental Progress and Sustainable Energy, 29(2), 233-241.
    8.
  8. M. A. Salam, R. C. Burk.(2010). Thermodynamics and kinetics studies of pentachlorophenol adsorption from aqueous solutions by multi-walled carbon nanotubes, Water, Air, and Soil Pollution 210, 101–111.
    9.
  9. J. Senthilnathan, Ligy Philip.(2010). Removal of mixed pesticides from drinking water system using surfactant assisted Nano-TiO2, Water, Air, and Soil Pollution 210, 143–154.
    10.
  10. X. Liu, Q. Hu, Z. fang, X. Zhang, B. Zhang. (2009). Magnetic chitosan nanocomposites: a useful recyclable tool for heavy metal ion removal, Langmuir 25, 3–8.
    11.
  11. J. F. Liu, Z. S. Zhao, G.B. Jiang.(2007).Coating Fe2O4 magnetic nanoparticles with humic acid for high efficient removal of heavy metals in water, Environmental Science and Technology 42, 6949–6954.
    12.
  12. J. Hu, M.C. Irene, G. Chen(2005).Fast removal and recovery of Cr(VI) using surface-modified jacobsite (MnFe2O4) nanoparticles, Langmuir 21, 11173–11179.
    13.
  13. A. Rahmani, H. Zavvar Mousavi, M. Fazli. (2010)Effect of nanostructure alumina on adsorption of heavy metals, Desalination 253,  94–100.
    14.
  14. T. Sheela, Y. Arthoba Nayaka ⁎, R. Viswanatha, S. Basavanna, T.G. Venkatesha (2012).Kinetics and thermodynamics studies on the adsorption of Zn(II), Cd(II) and Hg(II) from aqueous solution using zinc oxide nanoparticles. Powder Technology 217, 163–170.
    15.
  15. Zaman M.I. , Mustafa S. , Khan S. , Xing B. , (2009). “Effect of phosphate complexationon Cd2+ sorption by manganese dioxide (ˇ-MnO2) ”, J. Colloid Interface Sci. 330,  9-19.
    16.
  16. Su Q. , Pan B. , Wan S. , Zhang W. , Lv L. , (2010). “Use of hydrous manganese dioxideasa potential sorbent for selective removal of lead, cadmium, and zinc ions from water”. J.Colloid Interface Sci. 349, 607–612.
    17.
  17. Meng Xu, Hongjie Wang, Di Lei, Dan Qu, Yujia Zhai, YiliWang.(2013). “Removal  of Pb(II) from aqueous solution by hydrous manganese dioxide: Adsorption  behavior amechanism''. Journalof Environmental Sciences, 25(3) 479– 486.
    18.
  18. M. Hosseinifard, H. Ghorbani, M. Aghazadeh, M. Hosseinifard. (2016). The syntheses of Manganese Dioxide Nano-particles (MnO2) and its Efficiency on Copper Removal from Aqueous Solutions. J.of Water & Wastewater (Ab va Fazilab), Vol. 27, No.3 (103).(In Persian).
    19.
  19. M. Aghazadeh, M. Hosseinifard .(2013)."Electrochemical preparation of ZrO2nanopowder: Impact of the pulse current on the crystal structure, composition andmorphology".Ceramics International, Volume 39, Issue 4, Pages 4427-4435.
    20.
  20. Lagergren, S.(1898). “Absolute theory of so called adsorption of soluble substances”.Handlinger. 24(4):1-39.
    21.
  21. Ho YS, Wase  DAJ, Forster CF.(1996). “Kinetic studies of competitive heavy metaladsorption by sphagnum moss peat”. Environmental Technology. 17(1):71-77.
    22.
  22. Othman Hakami; Yue Zhang; Charles J. Banks. (2012). “Thiol-functionalisedmesoporous silica-Coated magnetite nanoparticles for high efficiency removal and recovery of  Hg from water”, water research, Volume 46, Issue 12, p. p. 3913-3922, August.
    23.
  23. Jooyoung Song; Hyeyoung Kong; Jyonjsik Jang.(2011). “Adsoption of heavy metal ionsfrom aqueous solution by polyrhodanine-encapsulated magnetic nanoparticles”. J. ofColloid and Interface Science, Valume 359, P. P. 505-511, Joly.
    24.
  24. Langmuir, I. (1916). “The constitution and fundamental properties of solids and liquids”. Part. 1. Solids, J. ofAm. Chem. Soc., 38, 2221-2295.
    25.
  25.  Freundlich, H.M.F.(1906). “Over the adsorption in solution”. J. of Phys. Chem., 57, 385-470.
    26.
  26. Bystrom, A.M. (1949). Acta Chem. Scand. 3 , 163.
    27.
  27. Zwicker, W.K., et al. (1962). Am. Mineral 47 , 246.
    28.
  28. Ananth, M.V., Pethkar, S., Dakshinamurthi, K. (1998).  J. Power Sour. 75, 278e282.
    29.
  29. Donglin Zhao , Xin Yang, Hui Zhang , Changlun Chen , Xiangke Wang .(2010). “Effect of  environmental conditions on Pb(II) adsorption on-MnO2”. Chemical  EngineeringJournal, 164, 49-55.
    30.
  30. F. Ge, M. M. Li, H. Ye, B. X. Zhao.(2012).Effective removal of heavy metal ions Cd2+, Zn2+, Pb2+, Cu2+ from aqueous solution by polymer-modified magnetic nanoparticles. J. of Hazardous Materials 211– 212, 366– 372.
    31.
  31. Lijing Dong, Zhiliang Zhu, Hongmei Ma, Yanling Qiu, Jianfu Zhao.(2010)”Simultaneos  adsorption of  lead and cadmium on Mno2-loaded resin”. Journal of Environmental science,  22(2), 225-229.
    32.
  32. Donghee, P., Lim, S.R., Yun, Y.S., and Park, J.M.. (2008).“Development of a newCr(VI) biosorbent fromagricultural biowaste.” Bioresource Technology, 99 (18), 8810-8818.
    33.
  33. Ozcar, M; and Sengil, I.A, .(2005) "Adsorption of metal complex dyes fromaqueous Solutions by pin sawdust." J. of Bioresource Technology, 96(7), 791-795.
    34.
  34. Qingdong Qin , Qianqian Wang , Dafang Fu , Jun Ma . (2011).“An efficient  approach for  Pb(II) and Cd(II) removal using manganese dioxide formed insitu”.Chemical Engineering Journal,  172, 68-74.
    35.
  35. Katal, R., Hasani, E., Farnam, M., Sharifzadeh, M., Ghayyam, A. (2009). “Charcoal ash as nanoadsorbent for Ni2+ adsorption and its application for wastwarer treatment”. Journal of chemical and Engineering Data, DOI: 10.1021/Je 200953h.
    36.
  36. Yueming Ren, Ni Yan, Jing Feng, Jun Ma, Qing Wen, Nan Li, Qing Dong .(2012).“Adsorptionmechanism of copper and lead ions onto graphene nanosheet/d-MnO2”.Materials Chemistryand Physics,136:538e544.
    37.
  37. M. Hosseinifard, H. Ghorbani, M. Aghazadeh, M. Hosseinifard.(2016) Removal of lead from Aqueous Solutions Using Manganese Dioxide Nanoparticles Synthesized by Electrochemical Method. J.of Environmental Sciences, Vol. 13, No.4.(In Persian)
    38.
  38. Chao Luo, Rongyan Wei, Dan Guo, Shengfang Zhang, Shiqiang Yan. (2013)."Adsorptionbehavior of MnO2  functionalized multi-walled carbon nanotubes for the removal ofcadmium from aqueous solutions". Chemical Engineering Journal 225, 406-415.
    39.

 

 

 

 

 

 

 

 

 

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