The Effect of Hydrogen Bonding and π–π Stacking to Stabilization of 3D Networks of a New Proton Compound, (a-6-mpyH)(Hpyzd) H2O

الموضوعات : Journal of Physical & Theoretical Chemistry

R. Mohammadinasab ¹ , M. Tabatabaee ² , M. A. Seyed Sadjadi ³

1 - -
2 - -
3 - -

تاريخ الإرسال : 15 الإثنين , رجب, 1436 تاريخ التأكيد : 15 الإثنين , رجب, 1436 تاريخ الإصدار : 13 الأربعاء , رمضان, 1433

الکلمات المفتاحية: (Hamp-6-pic)(Hpyzd).H2O, Proton transfer, hydrogen bonds, π…π stacking,

ملخص المقالة :

A new proton transfer compound, formulated as (Hamp-6-pic)(Hpyzd) ∙H2O (1), has been synthesized from the reaction of pyrazine-2,3-dicarboxylic acid (H2pyzd) and 2-amino-6-methyl pyridine (amp-6-pic), in 1:1 molar ratio. Extensive O−H×××O, N−H×××N and O−H×××O hydrogen bonds involving (Hamp-6-pic)+ cation, (Hpyzd)- anion and co-crystal water molecule٫ static electronic٫ and π…π stacking interactions form a three-dimensional network.