Novel ZrO2 ion-selective electrode based on 4,7,13,16,21,24-hexa oxa- 1,10- diazabicyc1o[8,8,8]-hexa cosane as neutral carrier in PVC matrix
الموضوعات : Journal of Physical & Theoretical ChemistryM. Aghaie 1 , K. Zare 2 , M. Giahi 3
1 - Not-mentioned
2 - Not-mentioned
3 - Not-mentioned
الکلمات المفتاحية: Potentiometry, ZrO2+ sensor, PVC membrane, lonophore,
ملخص المقالة :
In this work, a novel Zr02+ PVC-based membrane sensor based on 4,7,13,16,21,24-hexa oxa-1,10- diazabicyclo[8,8,8]- hexa cosane (HODBHC) as a new ionophore is presented. The sensor displays a linear dynamic rangebetween 1.0x 10-1 and 1.0x10 6 M, with a near Nernstian slope of 29.9 ± 0.4 mV per decade in an acidic solution(pH=1). The limit of detection is 8.0 x 1 0 7 M. The electrodes possess advantages of low resistance, very fastresponse time, relatively long lifetimes and, especially, good selectivities relative to a wide variety of othercations. It was used as indicator electrode in potentiometric determination of ZrO2+ ion by standard additionmethod at pH 1.0 in two samples.
