Adsorption of Benzyl Paraben Dye from Aqueous Solutions Using synthesized Mn-doped PbS (PbS:Mn) nanoparticles
الموضوعات :
Journal of Physical & Theoretical Chemistry
elham mosavi
1
(Department of Chemistry, Dashtestan Branch, Islamic Azad University, Dashtestan, Iran)
alireza geramizadegan
2
(Department of Chemistry, Dashtestan Branch, Islamic Azad University, Dashtestan, Iran)
تاريخ الإرسال : 21 الأربعاء , محرم, 1442
تاريخ التأكيد : 28 الأربعاء , جمادى الثانية, 1442
تاريخ الإصدار : 26 الإثنين , ربيع الأول, 1443
الکلمات المفتاحية:
Benzyl Paraben (BP) dye,
Adsorption,
Isotherms,
Kinetic,
langmuir,
ملخص المقالة :
Precipitation method was applied to synthesize pure and PbS (1−x) Mn (x = 0%, 5%, 10% and 15%) nanoparticles. There have been reports on the usefulness of Mn-doped PbS (PbS:Mn) nanoparticles in removal Benzyl Paraben (BP) dye from aqueous solutions. The distinctive features of this novel material were identified using different techniques like BET, XRD, SEM and FT-IR. The optimal conditions for the (BP) dye removal were found to be 2, 15 min, 100 mg/L, and 0.1 g for pH, contact time and adsorbent dosage, respectively. Regarding the Kinetic models both pseudo-first-order and pseudo-second-order diffusion models of (BP) dye revealed that the kinetic of adsorption process followed second-order equation model. After using various Isotherm models to fit the experimental equilibrium data with, the adequacy and applicability of Langmuir model has been proven. Adsorption mechanism for these adsorbents was considered to be physical which was confirmed by the E (kJ mol-1) obtained from DubininRadushkevich isotherm for pure PbS, PbS/Mn-5%, PbS/Mn-10% and PbS/Mn-15% were roughly -710.0, -780.0, -830.0 and -920.0 (kJmol-1) respectively. The thermodynamic parameters including enthalpy, entropy and Gibbs energy were calculated for the adsorption of these (BP) dye using Mn-doped PbS nanoparticles suitable, spontaneous and exothermic. The maximum adsorption capacity of the (BP) dye for pure PbS, PbS/Mn-5%, PbS/Mn-10% and PbS/Mn-15% were roughly 80.0, 105.0, 131.0 and 145.0 mg/g, respectively. The findings revealed the appropriateness of Mn-doped PbS (PbS:Mn) nanoparticles as an adsorbent for (BP) dye deletion from aqueous solutions.
المصادر:
Zubair, I. Ihsanullah, N. Jarrah, A. Khalid, M.S. Manzar, T.S. Kazeem, M.A. Al- Harthi, Starch-NiFe-layered double hydroxide composites: efficient removal of methyl orange from aqueous phase.J. Molecular Liquids. 249 (2018) 254–264.
Anastopoulos, I. Pashalidis, A.G. Orfanos, I.D. Manariotis, T. Tatarchuk, L. Sellaoui, A. Bonilla-Petriciolet, A. Mittal, A. Nunez-Delgado, Removal of caffeine, nicotine and amoxicillin from (waste) waters by various adsorbents. A review. J. Environ. Management. 261 (2020) 110236.
Arora, S. Soni, S. Sahu, J. Mittal, P. Kumar, P.K. Bajpai, Iron based metal organic framework for efficient removal of methylene blue dye from industrial waste. J. Molecular Liquids. 284 (2019) 373-352.
Kumar, P. Saharan, A.K. Sharma, A. Umar, I. Kaushal, Y. Al-Hadeethi, B. Rashad, A. Mittal, Silver doped manganese oxide-carbon nanotube nanocomposite for enhanced dye-sequestration: Isotherm studies and RSM modelling approach. J. Ceramics International. 46 (2020) 10309–10319.
P. Mashile, A. Mpupa, A. Nqombolo, K. M. Dimpe, Philiswa, N. Nomngongo, Recyclable magnetic waste tyre activated carbon-chitosan composite as an effective adsorbent rapid and simultaneous removal of methylparaben and propylparaben from aqueous solution and wastewater. J. Water. Process. Eng. 33 (2020) 101011.
Pargari, F. Marahel, B. Mombini Godajdar, Ultrasonic Assisted Adsorption of Propyl Paraben on Uultrasonically Synthesized TiO2 nano particles loaded on activated carbon: Optimization, kinetic and equilibrium studies. J. Desal. Water. Treat. 112 (2020) 1-9.
Atheba, N. Guadi, B. Allou, P. Drogui, A. Trokourey, Adsorption kinetics and thermodynamics study of butylparaben on activated carbon coconut based. J. Encapsul. Adsorpt. Sci. 8 (2018) 39–57.
Yusoff, N. Yahaya, N. Saleh, M. Raoov, A study on the removal of propyl, butyl, and benzyl parabens via newly synthesised ionic liquid loaded magnetically confined polymeric mesoporous adsorbent. RSC Adv. 8 (2018) 25617–25635.
Asfaram, M. Ghaedi, F. Yousefi, M. Dastkhoon, Experimental design and modeling of ultrasound assisted simultaneous adsorption of cationic dyes onto ZnS: Mn-NPs-AC from binary mixture, Ultrason Sonochem. 33 (2016) 77-89.
P. Chin, S. Mohamad, M. R. Bin Abas, Removal of parabens from aqueous solution using ß-cyclodextrin cross-linked polymer. Int. J. Mol. Sci. 11 (2010) 3459–3471.
Bagheri, H. Aghaei, M. Ghaedi, M. Monajjemi, K. Zare, Novel Au–Fe3O4 NPs Loaded on Activated Carbon as a Green and High Efficient Adsorbent for Removal of Dyes from Aqueous Solutions Application of Ultrasound Wave and Optimization, Eur. J. Anal. Chem. 13(3) (2018) 1-10.
Ito, S. Yazawa, Y. Nakagawa, Y. Sasaki, S. Yajima, Effects of alkyl parabens on plant pathogenic fungi. Bioorganic Med. Chem. Lett. 25 (2015) 1774–1777.
Asfaram, M. Ghaedi, S. Agarwal, I. Tyagi, V. Kumar Gupta, Removal of basic dye Auramine-O by ZnS: Cu nanoparticles loaded on activated carbon, optimization of parameters using response surface methodology with central composite design. RSC. 5 (2015) 18438–18450.
Kiani, S. Bagheri, N. Karachi, E. Alipanahpour Dil, Adsorption of purpurin dye from industrial wastewater using Mn-doped Fe2O4 nanoparticles loaded on activated carbon. J. Desal. Water. Treat. 60 (2019) 1-8.
Liu, C. Cui, C. Luo, L. Zhang, Y. Guo, S. Yan, Synthesis of manganese dioxide/iron oxide/graphene oxide magnetic nanocomposites for hexavalent chromium removal. RSC. Adv. 4 (2014) 55162–55172.
H. Ahmadi, P. Davar, A. Manbohi, Adsorptive Removal of Reactive Orange 122 from Aqueous Solutions by Ionic Liquid Coated Fe3O4 Magnetic Nanoparticles as an Efficient Adsorbent. Iran. J. Chem. Chem. Eng. 35 (2016) 63-73.
P. Utomo, E. Santoso, G. Yuhaneka, A.I. Triantini, M.R. Fatqi, M.F. Hudadan, N. Nurfitria, Studi Adsorpsi zat warna Naphthpl Yellow S pada limbah cair Menggunakan aktif dari ampas tebu, Journal. Kimia. (Journal of chemistry). 13 (2019) 104-116.
Gaur, P. Jeevanandam, PbS micro-nanostructures with controlled morphologies by a novel thermal decomposition approach, J. Nanopart. Res. 18 (2016) 80.
Suresh Babu, C. Vijayan, R. Devanathan, Strong quantum confinement effects in polymer- based PbS nanostructures prepared by ion-exchange method, Mater. Lett. 58 (2004) 1223- 1226.
Liu, H. Yu, Z. Wu, W. Wang, J. Peng, Y. Cao, Size-tunable near-infrared PbS nanoparticles synthesized from lead carboxylate and sulfur with oleylamine as stabilizer, Nanotechnology. 19 (2008) 345602.
Long, B. Barman, S. Delikanli, Y. Tsung Tsai, P. Zhang, A. Petrou, H. Zeng, Carrier-dopant exchange interactions in Mn-doped PbS colloidal quantum dots, Appl. Phys. Lett. 101 (2012) 062410.
R. Smith, W. J. Padilla, D. C. Vier, S.C. Nemat-Nasser, S. Schultz, Composite medium with simultaneously negative permeability and permittivity, Phys. Rev. Lett. 84 (2000) 4184–4187.
Mahmoudi Chenari, B. Ramezanpour, H. Kangarlou, Metamaterial Mn-doped PbS nanoparticles: Synthesis, size-strain linebroadening analysis and Kramers-Kronig study. Ceramics International. 6 (2017) 109.
S. Ghazi Mokri, N. Modirshahla, M.A. Behnajady, B. Vahid, Adsorption of C.I. Acid Red 97 dye from aqueous solution onto walnut shell: kinetics, thermodynamics parameters, isotherms. Int. J. Environ. Sci. Technol. 12 (2015) 1401–1408.
Zhao, J. Zou, W. Shi, In situ synthesis and characterization of PbS nano crystallites in the modified hyperbranched polyester by gamma-ray irradiation, Mater. Sci. Eng. 121 (2005) 20-24.
Gode, O. Baglayan, E. Guneri, P-Type nano structure PbS Thin films prepared by the silar method. Chalcogenide Letters. 12 (2015) 519-528.
S. Shyju, S. Anandhi, R. Sivakumar, R. Gopalakrishnan, Studies on Lead Sulfide (PbS) Semiconducting Thin Films Deposited from Nanoparticles and Its NLO Application. Int. J. NanoScience. 13 (2014) 1450001- 1450012.
Ghaedi, B. Sadeghian, A. A. Pebdani, R. Sahraei, A. Daneshfar, C. Duran, Kinetics, thermodynamics and equilibrium evaluation of direct yellow 12 removal by adsorption onto silver nanoparticles loaded activated carbon, Chem. Eng. J. 187 (2012) 133–141.
H. Haghdoost, Removal of Reactive Red 120 from Aqueous Solutions Using Albizia lebbeck Fruit (Pod) Partical as a Low Cost Adsorbent, J. Phys. Theore. Chem. 15 (3, 4) (2019) 141-148.
Manohar, V. S. Shrivastava, Adsorption removal of carcinogenic acid violet19 dye from aqueous solution by polyaniline-Fe2O3 magnetic nano-composite. J. Mater. Environ. Sci. 6 (2015) 11-21.
Ghodratollah Absalan, A. Bananejad, M. Ghasemi, Removal of Alizarin Red and Purpurin from Aqueous Solutions Using Fe3O4 Magnetic Nanoparticles, Anal. Bioanal. Chem. Res. 4 (2017) 65-77.
S. Ho, G. Mc Kay, The Kinetics of Sorption of Divalent Metal ions onto Sphagnum Moss Peat. Water. Res. 34 (2000) 735-742.
Hajati, M. Ghaedi, H. Mazaheri, Removal of methylene blue from aqueous solution by walnut carbon: optimization using response surface methodology, J. Desal. Water. Treat. 57 (2016) 3179-3193.
Hajati, M. Ghaedi, B. Barazesh, F. Karimi, R. Sahraei, A. Daneshfar, A. Asghari, Application of high order derivative spectrophotometry to resolve the spectra overlap between BG and MB for the simultaneous determination of them: ruthenium nanoparticle loaded activated carbon as adsorbent, J. Ind. Eng. Chem. 20 (2014) 2421–2427.
Langmuir, The adsorption of gases on plane surfaces of glass, mica and platinum. J. American. Chem. Soc. 40 (1918) 1361–1403.
M. F. Freundlich, Over the adsorption in solution. J. Phys. Chem. 57 (1906) 385–470.
M. Dubinin, The potential theory of adsorption of gases and vapors for adsorbents with energetically non-uniform surface, Chem. Res. 60 (1960) 235–266.
M. Dubinin, Modern state of the theory of volume filling of micropore adsorbents during adsorption of gases and steams on carbon adsorbent, Zh. Fiz. Khim. 39 (1965) 1305 –1317.
Toor, B. Jin, Adsorption Characteristics, Isotherm, Kinetics, and Diffusion of Modified Natural Bentonite for Removing Diazo Dye. Chem. Eng. J. 187 (2012) 79-88.
S. Ho, Review of Second-order Models for Adsorption Systems, J. Hazar. Mater. 136 (2006) 681-689.
Bouaziz, M. Koubaa, F. Kallel, R.E. Ghorbel, S.E. Chaabouni, Adsorptive Removal of Malachite Green from Aqueous Solutions by Almond Gum: Kinetic Study and Equilibrium Isotherms, Int. J. Biolog. Macromolecules. 105 (2017) 56-65.
Banerjee, G.C. Sharma, R.K. Gautam, M.C. Chatto padhyaya, S.N. Upadhyay, Y.C. Sharma, Removal of Malachite Green, a Hazardous Dye from Aqueous Solutions Using Avena Sativa Hull as a Potential Adsorbent, J. Molecular Liquids. 213 (2016) 162-172.
H. Vatan khah, A. Kohmareh, Enhanced removal of Bismark Brown (BB) dye from aqueous solutions using activated carbon from raw maize tassel: Equilibrium, thermodynamic and kinetics. J. Phys. Theore. Chem. 14(3) (2018) 237-249.
A. Achmad, J. Kassim, T. Kim Suan, Equilibrium, Kinetic and Thermodynamic Studies on the Adsorption of Direct Dye onto a Novel Green Adsorbent Developed from Uncaria Gambir Extract. J. Phys. Sci. 23 (2012) 1-13.
