Removal Phenol from Aqueous Solutions Using Environmental friendly and Effective Adsorbent onto Mn-doped Fe2O4 nanoparticles loaded on activated carbon
الموضوعات :
Journal of Physical & Theoretical Chemistry
Moslem Rahmani piani
1
(Department of Chemistry, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran)
Maryam abrishamkar
2
(Department of Chemistry, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran.)
Bijan Mombeni Goodajdar
3
(Department of Chemistry, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran)
تاريخ الإرسال : 20 السبت , ذو القعدة, 1441
تاريخ التأكيد : 23 الثلاثاء , ربيع الثاني, 1442
تاريخ الإصدار : 26 الإثنين , ربيع الأول, 1443
الکلمات المفتاحية:
Kinetic,
Isotherm Study,
Thermodynamic,
Phenol,
Adsorption,
ملخص المقالة :
The applicability of Mn-doped Fe2O4 nanoparticles loaded on activated carbon for removing Phenol from aqueous solutions has been reported. This novel material was characterized by different techniques such as FT-IR, XRD and SEM. The influence of nanoparticle dosage, pH of the sample solution, individual Phenol concentration, contact time between the sample and the adsorbent, temperature, and ionic strength of the sample solution were studied by performing a batch adsorption technique. The maximum removal of 5-25 mg L-1 of individual Phenol from an aqueous sample solution at pH 6.0 for Phenol was achieved within 30 min when an adsorbent amount of 0.1 g was used. It was shown that the adsorption of Phenol follows the Langmuir isotherm model best described the experimental adsorption data with maximum adsorption capacities of 4.27 mg/g. The kinetic data were best described by the pseudo-second order model (R2 = 0.9997) explains equilibrium data. Isotherms had also been used to obtain the thermodynamic parameters such as free energy (ΔG0), enthalpy (ΔH0) and entropy (ΔS0) of adsorption. The negative value of (ΔGo, ΔHo and ΔSo) confirmed the sorption process was endothermic reflects the affinity of Mn-doped Fe2O4 nanoparticles loaded on activated carbon functionalized towards Phenol. These results indicate that the pretreatment of Mn-doped Fe2O4 nanoparticles loaded on activated carbon can optimize the removal of Phenol from aqueous solution.
المصادر:
Bayramoglu, I. Gursel, Y. Tunali, M.Y. Arica, Biosorption of phenol and 2-chlorophenol by Funalia trogii pellets. Bioresour. Technol. 100(10) (2009) 2685-2691.
A. Sajadi, H. Biglari, M. Afsharnia, N. Javan, Phenol Removal from Aqueous Solutions by Adsorption on Activated Carbon of Miswak’s Root Treated with KMnO4, Iran. J. Health. Sci. 4 (2016) 20-30.
Bazrafshan, H. Biglari, A. H. Mahvi, Phenol removal by electrocoagulation process from aqueous solutions. Journal of Fresenius Environmental Bulletin. 21(2) (2012) 364-371.
Kadirvelu, R. D. Kumar, G. K. Kannan, Bioremediation of hazardous pollutants Phenol from water and waste water using Poplar tree wood activated carbon. Environ Risk Assess Remediat. 2 (2018) 6-13.
Saiedi, Investigation of adsorbtion phenol from polluted water with the help of activated carbon, carbons of shell note and walnut. Journal of Environmental Science and Technology. 10(4) (2008) 218-231.
Chakraborty, D. Deva, A. Sharma, N. Verma, Adsorbents based on carbon microfibers and carbon nanofibers for the removal of phenol and lead from water. J. Colloid. Interface. Sci. 359 (2011) 228-239.
Li, L. Sun, J. Xue, C. Zhang, W. Zheng, L. Zhang, Adsorption of phenol from water on activated carbon prepared from shaddock peel by ZnCl2 and H3PO4: equilibrium, kinetics and thermodynamics, Desalination and Water Treatment. 58 (2017) 181-191.
I. Yousef, B. El-Eswed, A. H. Al-Muhtaseb, Adsorption characteristics of natural zeolites as solid adsorbents for phenol removal from aqueous solutions: Kinetics, mechanism, and thermodynamics studies. Chem. Eng. J. 171(3) (2011) 1143-1149.
Zeng, Y. Fan, G. Wu, C. Wang, R. Shi, Enhanced adsorption of phenol from water by a novel polar post-crosslinked polymeric adsorbent. J. Hazard. Mater. 169(1-3) (2009) 1022-1028.
K. Vidya, R. Ramanjaneyulu, G. Srinikethan, Biological phenol removal using immobilized cells in a pulsed plate bioreactor: effect of dilution rate and influent phenol concentration. J. Hazard. Mater. 149(2) (2007) 452-459.
B. Senturk, D. Ozdes, A. Gundogdu, C. Duran, M. Soylak, Removal of phenol from aqueous solutions by adsorption onto organomodified Tirebolu bentonite: equilibrium, kinetic and thermodynamic study. J. Hazard. Mater. 172 (2009) 353-362.
Kermani, H. Pourmoghaddas, B. Bina, Z. Khazaei, Removal of phenol from aqueous solutions by rice husk ash and activated carbon. Pak. J. Biol. Sci. 9(10) (2006) 1905-1910.
Liu, Z. Guo, S. Zheng, Z. Xu, Adsorption of tannic acid and phenol on mesoporous carbon activated by CO2. Chem. Eng. J. 183 (2012) 244-252.
Yang, Y. Zhu, P. Li, C.P. Huang, Prepration of amagnetic reduced – grapheme Oxide/tea waste composite for high efficiency sorption of uranium. Journal of the Taiwan Insttitute of Chemical Engineers. 68 (2019) 80-89.
Bagheri, H. Aghaei, M. Ghaedi, A. Asfaram, M. Monajemi, A. A. Bazrafshan, Synthesis of nanocomposites of iron oxide/gold (Fe3O4/Au) loaded on activated carbon and their application in water treatment by using sonochemistry: Optimization study, Ultrasonics – Sonochemistry. 41 (2018) 279–287.
M. Vargas, A. C. Martins, V. C. Almeida, Ternary adsorption of acid dyes onto activated carbon from flamboyant pods (Delonix regia): analysis by derivative spectrophotometry and response surface methodology. Chem. Eng. J. 195 (2012) 173-179.
M. Coelho, E. Vidotti, M. Rollemberg, A. Medina, M. Baesso, N. Cella, A. Bento, Photoacoustic spectroscopy as a tool for determination of food dyes: comparison with first derivative spectrophotometry. Talanta. 81 (2010) 202-207.
Kakavandi, A. Raofi, S. M. Peyghambarzadeh, B. Ramavandi, M. Hazrati Niri, M. Ahmadi, Efficient adsorption of cobalt on chemical modified activated carbon: characterization, optimization and modeling studies. Journal Desalination and Water Treatment. 111 (2018) 310-321.
Kiani, M. O. Dostalia, A. Rostami, A.R. Khataee, Adsorption studies on the removal of Malachite Green from aqueous solutions onto halloysite Nanotubes. Applied Clay Science. 54 (2011) 34–39.
Liu, G. Cui, C. Luo, L. Zhang, Y. Guo, S. Yan, Synthesis of manganese dioxide/iron oxide/graphene oxide magnetic nanocomposites for hexavalent chromium removal, RSC. Adv. 4 (2014) 55162–55172.
Rezaei Kalantary, E. Dehghanifard, A. Esrafili, B. Kakavandi, Nitrate adsorption by synthetic active carbon magnetic nanoparticles: Kinetic, isotherms and thermodynamic studies.Journal Desalination and Water Treatment. 57 (2016) 16445-16455.
H. Ahmadi, P. Davar, A. Manbohi, Adsorptive Removal of Reactive Orange 122 from Aqueous Solutions by Ionic Liquid Coated Fe3O4 Magnetic Nanoparticles as an Efficient Adsorbent. Iran. J. Chem. Chem. Eng. 35 (2016) 63-73.
J. Kulkarni, R. W. Tapre, S. V. Patil, M. B. Sawarkar, Adsorption of Phenol from Wastewater in Fluidized Bed Using Coconut Shell Activated Carbon, Chemical, Civil and Mechanical Engineering Tracks of 3rd Nirma University International Conference, Sciverse ScienceDirect. 24 (2012) 300-307.
Bagheri, Application of response surface methodology to modeling and optimization of removal of Bismarck Brown and Thymol Blue by Mn-Fe2O4-NPs-AC: kinetics and thermodynamic studies, Orient. J. Chem. 32 (2016) 549–565.
Ghaedi, S. Hajati, A. Goudarzi and A. A. Bazrafshan, Spectrochim. Acta, Part A. 145 (2015) 203-212.
D. Waldron, Infrared Spectra. of Ferrites. Phys. Rev. 99 (1955) 1727.
Asfaram, M. Ghaedi, S. Agarwal, I. Tyagi, V. Kumar Gupta, Removal of basic dye Auramine-O by ZnS:Cu nanoparticles loaded on activated carbon: optimization of parameters using response surface methodology with central composite design. RSC. 5 (2015) 18438–18450.
Demey-Cedeno, M. Ruiz, J. A. Barron-Zambrano, A.M. Sastre, Boron removal from aqueous solutions using alginate gel beads in fixed-bed systems. Journal of Chemical Technology & Biotechnology. 89 (2014) 934–940.
T. Mohd Din, B. H. Hameed, A. L. Ahmad, Batch adsorption of phenol onto ysiochemical-activated coconut shell. J. Hazard. Mater. 161(2-3) (2009) 1522-1529.
Kilic, E. Apaydin-Varol, A. E. Putun, Adsorptive removal of phenol from aqueous solutions on activated carbon prepared from tobacco residues: Equilibrium, kinetics and thermodynamics. J. Hazard. Mater. 189 (2011) 397-403.
Cherifi, S. Hanini, F. Bentahar, Adsorption of phenol from wastewater using vegetal cords as a new adsorbent. Desalination. 244 (2009) 177-187.
Achmad, J. Kassim, T. Kim Suan, Equilibrium, Kinetic and Thermodynamic Studies on the Adsorption of Direct Dye onto a Novel Green Adsorbent Developed from Uncaria Gambir Extract. Journal of Physical Science. 23 (2012) 1-13.
Mizutani, A.H. Mahvi, A. Maleki, A. Eslami, Potential of rice husk and rice husk ash for phenol removal in aqueous systems. Am. J. Appl. Sci. 1 (2004) 321-326.
Zhao, Z. Tang, P. Liu, Removal of methylene blue from aqueous solution with silica nano-sheets derived from vermiculite. J. Hazard. Mater.158 (2008) 43-51.
S. Ho, G. Mc Kay, THE KINETICS OF SORPTION OF DIVALENT METAL IONS ONTO SPHAGNUM MOSS PEAT. Water. Res. 34 (2000) 735–742.
Langmuir, The adsorption of gases on plane surfaces of glass, mica and platinum, J. Am. Chem. Soc. 40 (1918) 1361–1403.
Freundlich, Uber die adsorption in lِsungen, Zeitschrift für physikalische Chemie. 57 (1907) 385–470.
Temkin, V. Levich, Adsorption equilibrium on hetrogeneous surfaces, J. Phys. Chem. 20 (1964) 1441-1452.
Juang, F. Wu, R. Tseng, The ability of activated clay for the adsorption of dyes from aqueous solutions. Environ. Technol. 18 (1997) 525–531.
J. Weber, J. C. Morris, Kinetics of adsorption on carbon from solution, J. Sanit. Eng. Div. 89 (1963) 31–60.
S. Ho, Second- order kinetic model for the sorption of cadmium onto tree fern: acomparison of line arandnon- linearmethods. Water. Res. 40 (2006) 119–125.
Varghese, V. P. Vinod, T. S. Anirudhan, Kinetic and equilibrium characterization of phenols adsorption onto a novel activated carbon in water treatment. Indian. J. Chem. Technol. 11 (2004) 825-833.
Mehrabi, E. A. Dil, Investigate the ultrasound energy assisted adsorption mechanism of nickel (II) ions onto modified magnetic cobalt ferrite nanoparticles: multivariate optimization, Ultrason. Sonochem. 37 (2017) 37–46.
Bouaziz, M. Koubaa, F. Kallel, R.E. Ghorbel, S.E. Chaabouni, Adsorptive Removal of Malachite Green from Aqueous Solutions by Almond Gum: Kinetic Study and Equilibrium Isotherms, International Journal of Biological Macromolecules. 105 (2017) 56-65.
Mehrizad, M. Aghaie, P. Gharbani, S. Dastmalchi, M. Monajjemi, K. Zare, Comparison of 4-Chloro-2-Nitrophenol Adsorption on Single-Walled and Multi-Walled Carbon Nanotubes. Iranian Journal of Environmental Health Science and Engineering. 9 (2012) 5-13.
H. Al-Muhtaseb, K. A. Ibrahim, A. B. Albadarin, O. Ali-Khashman, G. M. Walker, M. N. M. Ahmad, Remediation of phenol-contaminated water by adsorption using poly (methyl methacrylate) PMMA). Journal. Chem. Eng. 168(2) (2011) 691-699.
