Thermodynamic study of (pb2+) removal by adsorption onto modified magnetic Graphene Oxide with Chitosan and Cysteine

الموضوعات : فصلنامه نانوساختارهای اپتوالکترونیکی

Ghazaleh Ramezani ¹ , Bizhan Honarvar ² , masoomeh emadi ³

1 - Department of Chemical Engineering, Marvdasht Branch, Islamic Azad University,Marvdasht, Iran
2 - Department of Chemical Engineering, Marvdasht Branch, Islamic Azad University,Marvdasht, Iran
3 - Department of Chemistry, Marvdasht Branch, Islamic Azad University, Marvdasht, Iran

تاريخ الإرسال : 19 الأربعاء , شعبان, 1440 تاريخ التأكيد : 08 الثلاثاء , شوال, 1440 تاريخ الإصدار : 29 الخميس , ذو القعدة, 1440

الکلمات المفتاحية: Nanoparticles, Magnetic Graphene Oxide, Surface modification, Removal of lead, Adsorption thermodynamics,

ملخص المقالة :

A new modified magnetic Graphene Oxide with Chitosan and Cysteine was
synthesized for removing Pb2+ ions from aqueous solution. The properties of this
adsorbent were characterized by Field Emission Scanning Electron Microscopy (FESEM),
Vibrating Sample Magnetometer (VSM) and Energy Dispersive Analysis System
of X-ray (EDAX). Physicochemical parameters such as effect of pH, contact time,
adsorbent dosage and initial concentration of Pb 2+ was also studied. The results showed
that the maximum capacity of absorbent in Lead ions adsorption (at Equilibrium
concentration of 120 ppm) occurred at pHOptimum= 5.75, tOptimum= 30 min and
adsorbent 85.4 mg/g dosage=0.1 gr. Maximum empirical adsorption capacity (qmax) was
calculated 85.4 mg/g. The thermodynamic parameters (ΔHᵒ, ΔGᵒ and ΔSᵒ) showed that
the adsorption process of Pb 2+ on modified magnetic Graphene Oxide with Chitosan
and Cysteine was endothermic and spontaneous. Removal percentage was reduced to
15% after five stages of Sorption/desorption studies. So, modified magnetic Graphene
Oxide with Chitosan and Cysteine can be used as a complementary process for removal
of Pb2+ ions from water and wastewater.

المصادر:

[1] H. Ramezani, M. Sharif and A.K Shokooh. Graphene-Based Polymer
Nanocomposites. Polymerization Quarterly. (2015) 86–107.
Available:http://basparesh.ippi.ac.ir/article_1149_dca2849d5ace80b335142
9fbf19a064e.pdf
[2] M. Khazaei, S. Nasseri, M.R. Ganjali, M. Khoobi, R. Nabizadeh, E.
Gholibegloo and S. Nazmara. Selective Removal of Lead Ions from Aqueous
Solutions using 1, 8-Dihydroxyanthraquinone (DHAQ) Functionalized
Graphene Oxide; Isotherm, Kinetic and Thermodynamic Studies. RSC Advances. 8(11) (2018)5685-5694.
Available: https://pubs.rsc.org/en/content/articlehtml/2018/ra/c7ra13603j
[3] R. Seenivasan, W.J. Chang and S. Gunasekaran. Highly Sensitive Detection and Removal of Lead Ions in Water using Cysteine-Functionalized Graphene Oxide /Polypyrrole Nanocomposite Film Electrode. ACS applied materials & interfaces.7(29) (2015)15935-15943.
Available: https://pubs.acs.org/doi/abs/10.1021/acsami.5b03904
[4] D.Vilela, J. Parmar, Y. Zeng, Y.Zhao and S. Sánchez. Graphene-Based Microbots for Toxic Heavy Metal Removal and Recovery from Water. Nano letters.16(4) (2016) 2860-2866.
Available: https://pubs.acs.org/doi/full/10.1021/acs.nanolett.6b00768
[5] D. Mehta, S. Mazumdar and S.K. Singh. Magnetic Adsorbents for the Treatment of Water/ Wastewater. Journal of Water Process Engineering. 100(7) (2015) 244-265.
Available: https://www.sciencedirect.com/science/article/pii/S221471441530026X
[6] H. Rahimi. Absorption Spectra of a Graphene Embedded One Dimensional Fibonacci Aperiodic Structure. Journal of Optoelectronical Nanostructures. 3(4) (2018) 45-58
Available: http://jopn.miau.ac.ir/article_3259.html
[7] A. Abdykian and Z. Safi. Finding Electrostatics Modes in Metal Thin Films by using of Quantum Hydrodynamic Model. Journal of Optoelectronical Nanostructures.1(3) (2016) 43-50.
Available: http://jopn.miau.ac.ir/article_2193.html
[8] M. Nayeri, P. keshavarzian, M. Nayeri. A Novel Design of Penternary Inverter Gate Based on Carbon Nano Tube. Journal of Optoelectronical Nanostructures. 3(1) (2018) 15-26
Available: http://jopn.miau.ac.ir/article_2820.html
[9] K.S. Novoselov, V.I. Fal, L. Colombo, P.R. Gellert, M.G. Schwab and K. Kim. A Roadmap for Graphene. Nature.490(7419) (2012)192-200.
Available: https://www.nature.com/articles/nature11458
[10] A. Abdikian, G. Solookinejad, Z. Safi. Electrostatics Modes in Mono-Layered Graphene. Journal of Optoelectronical Nanostructures. 1(2) (2016) 1-8.
Available: http://jopn.miau.ac.ir/article_2044.html
[11] D.R. Dreyer, S. Park, C.W. Bielawski and R.S. Ruoff. The Chemistry of Graphene Oxide. Chemical Society Reviews.39(1) (2010) 228-240.
Available: https://pubs.rsc.org/en/content/articlehtml/2010/cs/b917103g
[12] D.R. Dreyer, R.S. Ruoff and C.W. Bielawski. From Conception to Realization: an Historial Account of Graphene and Some Perspectives for its Future. Angewandte Chemie International Edition.49(49) (2010) 9336-9344.
Available: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201003024
[13] S. Pei and H.M. Cheng. The Reduction of Graphene Oxide. Carbon.50(9) (2012) 3210-3228.
Available: https://www.sciencedirect.com/science/article/pii/S0008622311008967
[14] K. Kalantari, M.B. Ahmad, H.R.F. Masoumi, K. Shameli, M. Basri and R. Khandanlou. Rapid and High Capacity Adsorption of Heavy Metals by Fe3O4/Montmorillonite Nanocomposite using Response Surface Methodology: Preparation, Characterization, Optimization, Equilibrium Isotherms, and Adsorption Kinetics Study. Journal of the Taiwan institute of Chemical Engineers.49 (2015) 192-198.
Available: https://www.sciencedirect.com/science/article/pii/S1876107014003265
[15] Handbook of Membranes for Industrial Wastewater Recovery and Re-us, 1st ed., Elsevier Science & Technology Books,2003 ,7-9.
[16] T. Kuilla, S. Bhadra, D.Yao, N.H. Kim, S. Bose and J.H. Lee. Recent Advances in Graphene Based Polymer Composites. Progress in polymer science.35(11) (2010) 1350-1375.
Available: https://www.sciencedirect.com/science/article/pii/S0079670010000699
[17] Y.A. El-Reash. Magnetic Chitosan Modified with Cysteine-Glutaraldehyde as Adsorbent for Removal of Heavy Metals From Water. Journal of Environmental Chemical Engineering. 4 (4) (2016) 3835-3847.
Available: https://www.sciencedirect.com/science/article/pii/S2213343716303001
[18] V. Chandra, J. Park, Y. Chun, J.W. Lee, I.C. Hwang and K.S. Kim. Water-Dispersible Magnetite-Reduced Graphene Oxide Composites for Arsenic Removal. ACS Nano. 4(7) (2010) 3979-3986.
Available: https://pubs.acs.org/doi/abs/10.1021/nn1008897
[19] S. Tripathi, G.K. Mehrotra and P.K Dutta. Preparation and Physicochemical Evaluation of Chitosan/poly (vinyl alcohol)/Pectin
Ternary Film for Food-Packaging Applications. Carbohydrate Polymers.79(3) (2010)711-716.
Available: https://www.sciencedirect.com/science/article/pii/S0144861709005335
[20] L. Qi and Z. Xu. Lead Sorption from Aqueous Solutions on Chitosan Nanoparticles. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 251(1) (2004)183-190.
Available: https://www.sciencedirect.com/science/article/pii/S0927775704006995
[21] K.A. Janes, M.P. Fresneau, A. Marazuela, A. Fabra and M.J. Chitosan Nanoparticles as Delivery Systems for Doxorubicin. Alonso. Journal of controlled Release. 73(2) (2001) 255-267.
Available: https://www.sciencedirect.com/science/article/pii/S0168365901002942
[22] Y.A. El-Reash. Magnetic Chitosan Modified with Cysteine-Glutaraldehyde as Adsorbent for Removal of Heavy Metals from Water. Journal of Environmental Chemical Engineering. 4(4) (2016) 3835-3847.
Available: https://www.sciencedirect.com/science/article/pii/S2213343716303001
[23] D.D. Lefebvre and C. Edwards, Decontaminating Heavy Metals from Water using Photosynthetic Microbes, In Emerging Environmental Technologies, 2 (2009) 57-73.
Available: https://link.springer.com/chapter/10.1007/978-90-481-3352-9_3
[24] R. Wilfried E. Structure and Function of Metal Chelators Produced by Plants. Journal of Cell biochemistry and biophysics. 31(1) (1999) 19-48.
Available: https://link.springer.com/article/10.1007/BF02738153
[25] G. Scarano and E. Morelli. Properties of Phytochelatin-Coated CdS Nanocrystallites Formed in a Marine Phytoplanktonic Alga (Phaeodactylum tricornutum, Bohlin) in response to Cd. Journal of Plant Science.165(4) (2003) 803-810.
Available: https://www.sciencedirect.com/science/article/pii/S0168945203002747
[26] M.R. Lasheen, I.Y. El-Sherif., M.E. Tawfik, S.T. El-Wakeel and M.F. El-Shahat. Preparation and Adsorption Properties of Nano Magnetite Chitosan Films for Heavy Metal Ions from Aqueous Solution. Journal of Materials Research Bulletin.80 (2016) 344-350.
Available: https://www.sciencedirect.com/science/article/pii/S0025540816301696
[27] R.A. Khera, M. Iqbal, S. Jabeen, M. Abbas,A. Nazir, J. Nisar, A. Ghaffar, G.A. Shar and M.A. Tahir. Adsorption Efficiency of Pitpapra under Single and Binary Metal Systems. Journal of Surfaces and Interfaces.14 (2019)138-145
Available: https://www.sciencedirect.com/science/article/pii/S2468023018305571
[28] C.P. Poole Jr, F.J. Owens, Introduction to Nanotechnology, in Introduction to Nanotechnology,1st ed.Chicago, 2003.
[29] C.H. Yang.J. Derivation of the Freundlich Adsorption Isotherm from Kinetics. Journal of chemical Education.Colloid interface Sci.86(11) (1998) 379-387.
Available: https://pubs.acs.org/doi/abs/10.1021/ed086p1341