یک روش نوین برای سنتزِ سبز نانوذرات Fe3O4 با استفاده از عصاره گیاه آلیاسه و بررسی خواص آن‌ها

الموضوعات : فصلنامه علمی - پژوهشی مواد نوین

علی محمد امانی ¹ (گروه نانوپزشکی، دانشکده علوم و فناوری نوین پزشکی، دانشگاه علوم پزشکی شیراز، شیراز، ایران)
کاظم جمالی ² (استادیار، مرکز تحقیقات ترومای شهید رجایی(امتیاز)شیراز،دانشگاه علوم پزشکی شیراز)
علی جنگجو ³ (استادیار، گروه اورژانس، دانشکده پزشکی، بیمارستان آموزشی نمازی، دانشگاه علوم پزشکی شیراز، شیراز، ایران)
احسان وفا ⁴ (دانشجوی پسادکتری، گروه نانوپزشکی، دانشکده علوم و فناوری نوین پزشکی، دانشگاه علوم پزشکی شیراز، شیراز، ایران)
میلاد عباسی ⁵ (دانشجوی کارشناسی ارشد، گروه نانوپزشکی، دانشکده علوم و فناوری نوین پزشکی، دانشگاه علوم پزشکی شیراز، شیراز، ایران)
ساره مصلح شیرازی ⁶ (استادیار، دانشکده مهندسی و علم مواد، دانشگاه صنعتی شیراز، شیراز، ایران)
سید رضا کسایی ⁷ (استادیار، مرکز تحقیقات غدد و متابولیسم شیراز، دانشگاه علوم پزشکی شیراز، شیراز، ایران)
احمد واعظ ⁸ (استادیار، گروه مهندسی بافت، دانشکده علوم و فناوری نوین پزشکی، دانشگاه علوم پزشکی شیراز، شیراز، ایران)

تاريخ الإرسال : 17 الثلاثاء , شعبان, 1445 تاريخ التأكيد : 24 الأربعاء , رمضان, 1445 تاريخ الإصدار : 08 الإثنين , ربيع الثاني, 1445

الکلمات المفتاحية: نانوذرات مگنتیت, آلیوم هوشیدریا, سنتز سبز,

ملخص المقالة :

چکیده مقدمه: در سال‌های اخیر، نانوذرات مغناطیسی مبتنی بر اکسید آهن برای انواع کاربردهای زیست‌محیطی و پزشکی، از جمله خالص‌سازی و جداسازی آلودگی‌های دارویی، رنگی و فلزات سنگین و همچنین سیستم‌های تحویل دارو و برچسب‌گذاری، به‌طور گسترده مورد استفاده قرار گرفته‌اند. با توجه به این که مگنتیت (Fe₃O₄) دارای ویژگی‌های مغناطیسی و الکتریکی برتری است، در میان بسیاری از مواد نانوساختار اکسید آهن بیشترین علاقه را به خود جلب کرده است. روش: در این پژوهش، نانوذرات مگنتیت (Fe₃O₄) با استفاده از یک فرآیند سبز با موفقیت سنتز شد. این روش، روشی ساده، سریع، مقرون به صرفه و زیست‌سازگار است. عصاره گیاه آلیوم هوشیدریا (آلیاسه) به‌ عنوان یک عامل تثبیت کننده و کاهنده در این فرایند استفاده شد. برای مشخصه یابی و بررسی خواص موروفولوژی نانوذرات Fe₃O₄ از روش­هایی همچون مغناطیس سنج نمونه ارتعاشی (VSM)، پراش پرتو ایکس (XRD)، تبدیل فوریه مادون‌قرمز (FTIR)، طیف‌سنجی پرتو ایکس پراکنده انرژی (EDS)، میکروسکوپ الکترونی عبوری (TEM) و میکروسکوپ الکترونی روبشی (SEM) استفاده شد. یافته ­ها: نتایج آزمون XRD نشان داد که نانوذرات سنتز شده با خلوص بالا و ساختار FCC  است.  نتایج FTIR اتصال گروه عاملی موجود در این گیاه و نانوذرات Fe₃O₄ را اثبات کرد. همچنین، در آنالیز FTIR ، وجود دو پیک جذبی cm^-1 96/559 و  cm^-1 57/432 سنتز موفقیت­آمیز نانوذرات Fe₃O₄ را تایید کرد. تصاویر SEM و TEM نشان داد که نانوذرات Fe₃O₄ تولید شده عمدتاً به‌شکل کروی بوده و به‌طور متوسط دارای اندازه 73/35 نانومتر است. نتیجه ­گیری: بنابراین می توان نتیجه گرفت که نانو ذرات سنتز شده می­توانند برای استفاده در نانوپزشکی آینده مناسب باشند. 

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