The Catalytic potential of biosynthesized silver nanoparticles from Malva Sylvestris and Beetroot extracts for methylene blue Reduction
الموضوعات : Journal of Nanoanalysis
Sima Mehdizadeh
1
,
Nahid Ghasemi
2
1 - گروه شیمی، واحد آشتیان، دانشگاه آزاد اسلامی، آشتیان، ایران
2 - دانشگاه آزاد اسلامی واحد اراک
الکلمات المفتاحية: Biosynthesis, Silver Nanoparticles, Malva Sylvestris, Beetroot, Catalytic degradation,
ملخص المقالة :
Silver nanoparticles (AgNPs) were effectively synthesized via a biosynthesis method using aqueous extracts of Malva Sylvestris (MS) and Beetroot (BR). The phenolic and flavonoid compounds in these extracts served as potent reducing and stabilizing agents. A comprehensive investigation was conducted to examine the effect of various synthesis parameters, including pH, extract volume, salt concentration, temperature, and time, on the formation of nanoparticles. The synthesized AgNPs were characterized using ultraviolet-visible (UV-Vis) spectrophotometry, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Fourier-transform infrared spectroscopy (FTIR). Both types of AgNPs exhibited a face-centered cubic crystal structure, with maximum absorbance peaks at 439 nm for AgNPs.BR and 434 nm for AgNPs.MS. Catalytic activity in reducing methylene blue was verified through surface plasmon resonance (SPR) spectroscopy. Kinetic data were analyzed using pseudo-first-order, pseudo-second-order, intraparticle diffusion, and Elovich models. The enhanced reduction of methylene blue (MB) in the presence of 0.008 g AgNPs.BR and 0.005 g AgNPs.MS, with rate constants of 0.024 min⁻¹ and 0.097 min⁻¹ respectively, demonstrated the significant catalytic potential of these nanoparticles.
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