Study of kinetics, and thermodynamics of nikel adsorption from aqueous solutions using modified nano-graphene oxide by melamine
الموضوعات :nazanin parsa 1 , hassan rezaei 2
1 - Gorgan University of Agricultural Sciences and Natural Resources.
2 - Gorgan University of Agricultural Sciences and Natural Resources
الکلمات المفتاحية: Kinetics, Isotherms, Nickel, Nano graphene oxide,
ملخص المقالة :
one of the most important issues in water resources today is pollution caused by heavy metals. Nickel is a heavy metal that is widely used in various industries. Nickel is one of the most important pollutants in the environment and its removal is very important. There are different methods for separating heavy metals from aqueous media. Among all methods, surface adsorption is a low-cost and simple method and for removing heavy metals in low and medium concentrations. The aim of this study was to investigate the adsorption efficiency of nickel ions from aqueous solutions using melamine modified nano-graphene oxide.The experiments were performed under discontinuous conditions and the five parameters of initial concentration, contact time, temperature, pH and adsorbent dose were optimized. The pseudo-first-order and psedo-second-order kinetic models were investigated. Finally, thermodynamic parameters such as enthalpy and entropy change and Gibbs free energy were calculated.In the kinetic study, by comparing the coefficient of explanation of the pseudo-first-order model (0.3084) and the pseudo -second-order model (0.997), it was found that pseudo -second-order model better shows the adsorption process of nickel by the adsorbent. oxide nanoparticles is spontaneous and the reaction is accompanied by an increase in irregularity and endotherm. The adsorbent surface is multilayered, non-uniform and the adsorbent material on the adsorbent is heterogeneous. Nano graphene oxide modified by melamine has a special surface and high potential and is a suitable adsorbent for removing nickel from aqueous solutions and has a high absorption.
Ain Q, UmarFarooq M, Jalees M.I. (2020). Application of Magnetic Graphene Oxide for Water Purification: Heavy Metals Removal and Disinfection. Journal of Water Process Engineering. Volume 33. https://doi.org/10.1016/j.jwpe.2019.101044
Al-Rub F. A., El-Naas M., Benyahia F.Ashour I. (2004).Biosorption of nickel on blank alginate beads, free and immobilized algal cells. Process Biochem. 39(17): 1767-1773
Amiri M, Rezaee Kalantari R, Kermani M, Yeganeh M, Gholami M. (2019).Investigation of chlorpyriphos removal using chitosan graphene oxide composite form aquatic solution: study of kinetics, isotherms and thermodynamics. SJKU .24 (2) :119-138
Arjaghi SK, Alasl MK, Sajjadi N, Fataei E, Rajaei GE, (20201). Green Synthesis of Iron Oxide Nanoparticles by RS Lichen Extract and its Application in Removing Heavy Metals of Lead and Cadmium, Biological Trace Element Research.199 (2), 763-768.
Barakat M.(2011). New Trends in Removing Heavy Metals from Industrial Wastewater. Arabian Journal of Chemistry. 4(4): 361-377
Basso M., Cerrella E. and Cukierman A. (2002). Activated carbons developed from a rapidly renewable biosource for removal of cadmium (II) and nickel (II) ions from dilute aqueous solutions. Indust. Eng. Chem. Res. 41(5): 180-189
Brown P A, Gill S A, Allen S J. (2000). Metal removal from wastewater using peat, Wat Res. 34 (16):3907-3916
Ebrahimi R, Hayati B, Rezaee R, Shahmoradi B, Safari M, Harikaranahalli Puttaiah S, Maleki A. (2020). Adsorption of cadmium and nickel from aqueous environments using a dendrimer. Journal of Advances in Environmental Health Research.8(1): 19-24.
Ebrahimzadeh Rajaei G, Aghaie H, Zare K, Aghaie M. (2012), Adsorption of Ni (II) and Cd (II) ions from aqueous solutions by modified surface of Typha latifolia L. root, as an economical adsorbent, Journal of Physical & Theoretical Chemistry, 9 (3), 137-147.
Enriqe perez Ramirez E, de la Luz-Asunción M, Martínez-Hernández A, Velasco-Santos C. (2016).Graphene Materials to Remove Organic Pollutants and Heavy Metals from Water: Photocatalysis and Adsorption,Intech open:492-521
Esdaki Z, Ansari R, Ostovar F.( 2019). Removal of Nickel (II) ions from aqueous solutions using Iron (III) oxide nanoparticles: study of kinetic, isotherm and thermodynamic models. Ijhe.12 (3) :383-396
Fan H.L, Zhou S.F, Jiao W.Z, Qi G.S, Liu Y.Z. (2017). Removal of heavy metal ions by magnetic chitosan nanoparticles prepared continuously via high-gravity reactive precipitation method. Carbohydrate Polymers .174:1192–1200
Gooran Ourimi, H., Nezhadnaderi, M. (2020). Comparison of the application of Heavy metals adsorption methods from aqueous solutions for development of sustainable environment', Anthropogenic Pollution, 4(2), pp. 15-27. doi: 10.22034/ap.2020.1902797.1066
Hasar H. (2003).Adsorption of nickel (II) from aqueous solution onto activated carbon prepared from almond husk. J. Hazard. Mater.97(8): 49-57
jedokun A. T, Bello O. S. (2016). Sequestering Heavy Metals from Wastewater Using Cow Dung. Water Resources and Industry.13 :7-13
Khalili Arjaghi S, Ebrahimzadeh Rajaei G, Sajjadi N, Kashefi Alasl M, Fataei E. (2020). Removal of Mercury and Arsenic Metal Pollutants from Water Using Iron Oxide Nanoparticles Synthesized from Lichen Sinensis Ramalina Extract, Journal of Health, 11 (3), 397-408.
Madaeni. S. S., Heidary F, Salehi E. (2013). Co-Adsorption/ Filtration of Heavy Metal Ions from Water Using Regenerated Cellulose UF Membranes Modified with Deta Ligand," Separation Science Technology. 48(9): 1308-1314
Maibach H. I. and Menné T. (1989). Nickel and the Skin: Immunology and Toxicology. CRC Press.101(2): 20- 35.
Mohammadnia A., Hadavi Far M, Wesi H. octobr.(2017). Functionalization of graphene oxide nanoparticles to remove heavy metals from aqueous media. Fourth International Conference on Applied Research in Chemistry and Biology. (in Persian).
Nouri Dodaran, P., Fataei, E., Khanizadeh, B., (2019) study on photocatalytic and sonocatalytic activity of bi2o3 synthesized by sol-gel method in removing organic compounds of Ardabil textile factory effluents, Journal of Water and Wastewater;Ab va fazilab (in Persian) 30(4),67-77
Omrani, M., Fataei, E. (2018). Synthesizing Colloidal Zinc Oxide Nanoparticles for Effective Disinfection; Impact on the Inhibitory Growth of Pseudomonas aeruginosa on the Surface of an Infectious Unit. Polish Journal of Environmental Studies, 27(4), 1639-1645. https://doi.org/10.15244/pjoes/77096
Peng W, Li H, Liu Y, Song S. (2017).A review on heavy metal ions adsorption from water by graphene oxide and its composites. J Mol Liq. Elsevier. 230: 496-504
Qare Biglu, M. Izadkhah,D. Erfannia,C. and Entezami, A.(2016).Improve the mechanical and thermal properties of chemically modified graphene oxide/polypropylene nanocomposites. Modares Mechanical Engineering Journal.16 (8): 196-206. (in persian).
Rajaei GE, Aghaie H, Zare K, Aghaie M. (2013).Adsorption of Cu (II) and Zn (II) ions from aqueous solutions onto fine powder of Typha latifolia L. root: kinetics and isotherm studies. Research on Chemical Intermediates, 39 (8), 3579-3594.
Rajaei GE, Khalili-Arjaghi S, Fataei E, Sajjadi N, Kashefi-Alasl M. (2020). Fabrication and characterization of polymer-based nanocomposite membrane modified by magnetite nanoparticles for Cd and Pb removal from aqueous solutions. Comptes Rendus. Chimie, 23 (9-10), 563-574.
Rastgar S, Rezaei H, Yousefi, H. (2020). Study of kinetics, isotherms and thermodynamics of lead adsorption from aqueous solutions using Lignocellulose Nano-fibers (LCNFs). Environmental Resources Research.8(1): 64-82.
Rezaei H, Kulkarni SD, Saptarshi PG. (2011). Study of Physical Chemistry on Biosorption of Nickel by using Chlorella pyrenoidosa, Oriental Journal of Chemistry 27 (2), 595-602.
Robati D, Mirza B, Rajabi M, Moradi O, Tyagi I, Agarwal S, Gupta VK. (2016). Removal of hazardous dyes-BR 12 and methyl orange using graphene oxide as an adsorbent from aqueous phase. Chem Eng j.284: 687-97
Strivastava S K, Gupta VK, Mohen D.( 1997). Removal of lead and chromium by activated slag-A blast-furnace waste, Journal of Environmental Engineering/123(5):461-468.
Yakout S. M, and Elsherif E. (2010).Batch kinetics, isotherm and thermodynamic studies of adsorption of strontium from aqueous solutions onto low cost rice-straw based carbons. Carbon - Science and Technology.3(1):144-153
Zhang Q, Hou Q, Huang G, Fan Q. (2020). Removal of heavy metals in aquatic environment by graphene oxide composites: a review. Environ Sci Pollut
