Investigation of Ambient Aromatic Volatile Organic Compounds in Mosimi Petroleum Products Depot, Sagamu, Nigeria
الموضوعات :
ismail muhibbu-din
1
(
faculty of engineering and technology
university of ilorin
)
الکلمات المفتاحية: BTEX, occupational exposure, VOCs, Industrial Pollution, Acute and Chronic Inhalations,
ملخص المقالة :
Among chemical industries, petroleum depots have been identified as large emitters of Volatile Organic Compounds (VOCs).They affect air quality and constitute serious health and environmental problems on the ecosystem. Air samples were collected over activated charcoal, using a low volume air sampler. The sampler was placed at a human breathing height of 1.5 m for a sampling period of 8 hours at seven different sampling locations as follows; Workshop area, Slop Tanks area, Gate 1, Tank Farm area, Gate 2, Otiyelu Village and Marketer’s Block. Desorption process was performed on the adsorbed activated charcoal using a solvent extraction method. The extracted solutions were subjected to Flame Ionization Detection analysis in a Gas Chromatograph using a capillary column HP 5MS with length, inner diameter and particle size set at (30 m × 0.25 mm × 0.25 μm). The Gas Chromatograph was powered with ChemStation RevA09.01 software to determine the concentrations of each of the VOCs species present. The sampling collection and quantitative analysis described above is consistent with ANSI/ASTM D-1605-60 procedure. The identified VOCs species emitted were characterized by toluene (52.84%), benzene (37.61%), xylene (5.67%), and ethyl benzene (3.88%). The observed concentrations uncovered the air tolerance limits set by United States Environmental Protection Agency and the Agency for Toxic Substances and Diseases Registry.
Akanni C.O., ‘Physical government in Ogun State; Local and Regional Perspective, Centre for Sandwich programme (CESAP)’, Ogun State University, Ago-Iwoye. (2000).
Akeredolu, F.A., and Sonibare, J.A., ‘Ambient air measurements of Benzene, Toluene and Xylene (BTX) within a Nigerian Refinery and its environs by the Carbon Adsorption /GC-FID Techniques’. Journal of the Nigerian Society of Chemical Engineers, 16:123-132. (1997).
ANSI/ASTM Procedure D-1605-60, “Standard recommended practices for sampling atmospheres for analysis of gases and vapour”. (1990). https://onlinelibrary.wiley.com/doi/full/10.1002/3527600418.amsampgase0011
ATSDR (Agency for Toxic Substances and Disease Registry),’ Toxicological profile for Toluene’. PB/95/100228/AS. US Department of Health and Human Services, public health service. 2015 http://www.atsdr.cdc.gov/toxprofiles/tp116.html
ATSDR.,” Agency for Toxic Substances and Disease Registry, Minimal Risk Levels “(MRLs). 2015 https://www.atsdr.cdc.gov/mrls/index.asp
ATSDR (Agency for Toxic Substances and Disease Registry). “Toxicological Profile for Toluene” (Update). PB/95/100228/AS.US Department of Health and Human Services, Public Health Service. 2000. http://www.atsdr.cdc.gov/toxprofiles/tp116.html
ATSDR,” Interaction Profile of Benzene, Ethyl benzene, Toluene and Xylene (BTEX)” (Draft for public comment), Atlanta: Agency for Toxic Substances and Diseases Registry, U.S Dept of Health and Human services. 2001 https://www.atsdr.cdc.gov/interactionprofiles/ip05.html
Chattopadhyay, G., Samanta ,G., Chatterjee S, Chakroborti,P.,” Determination of benzene, toluene and xylene in ambient air of Calcutta for three years during winter”. Environ.Technol. 18:211–218. (1997).
Cerón-Bretón J G, Cerón-Bretón R M, Kahl J D W, et al. Diurnal and seasonal variation of BTEX in the air of Monterrey, Mexico: preliminary study of sources and photochemical ozone pollution[J]. Air Quality, Atmosphere & Health (2014): 1-14.
De Nevers, N.,” Air Pollution Control Engineering”. McGraw Hill. Discusses various features of air pollution engineering (pollution control techniques, NOxchemistry, plume dispersion) (1995)
Kalabokas, P. D., Hatzianestis, J., Bartzis, J. G. and Papagiannakopoulos, P., Atmospheric concentrations of saturated and aromatic hydrocarbons around a Greek oil refinery, Atmospheric. Environent 35(14), 2545–2555. (2001)
Kerbachi, R., Boughedaoui, M., Bounoue, L., and keddam, M. “Ambient Air pollution by Aromatic hydrocarbons in Algiers”. Atmospheric Environment; 40:3995-4003. (2006)
Brocco D.; Fratarcangelli R.; Lepore L.; Petricca M.; Ventrone I.,” Determination of aromatic hydrocarbons in urban air of Rome”. Atmos Environ. 31:557–66 (9 pages). (1997) https://dx.doi.org/10.1 016%2FS1352-2310(96)00226-9
Cetin, E. ; Odabasi, M. ; Seyfioglu, R., “Ambient volatile organic compound concentration Around a petro-chemical complex and petroleum refinery”. Sci. Total Environ. 55:197-199 (3 pages). (2003) https://www.ncbi.nlm.nih.gov/pubmed/12873403
Chen, M., and Zheng, X. M.,”The effect of K and Al over NiCO2O4 catalyst on its character and catalytic oxidation of VOCs”. Molecular Cellular Toxicology, 221:77-80. (2004)
Chin L. C.; Hung, Y. F.; Chi-Min S., “Source location and characterization of volatile organic compound emissions at a petrochemical plant in Kaohsiung, Taiwan”. Air and waste management Association, 10:121-125 (4pages) (2005). https://www.ncbi.nlm.nih.gov/pubmed/16295274
Clayton, L.D.; Woodall, G.M.,” A review of the mutagenicity and rodent carcinogenetic of ambient air”. Mutation Research. 636 (1):36-94. 2007 https://www.ncbi.nlm.nih.gov/pubmed/17451995
Dybing, E.; O‟Brien, J.; Renwick, A.G.; Sanner, T., “Risk assessment of dietary exposures to compounds that are genotoxic and carcinogenic” – An over view. Toxicology letters, 180(2):110-117 (7 pages). (2008). https://www.ncbi.nlm.nih.gov/pubmed/18584977
Federal Ministry Petroleum. NNPC crude oil and product pipeline network. (2014) https://www.slideshare.net/TransformNG/ministry-of-petroleum-resources
Finlayson- Pitts, B.;Pitts J., Jr.,” Atmospheric chemistry: fundamental and experimental technique”, New York, Wiley Inter-Science. 1986. https://searchworks.stanford.edu/view/1202278
Finlayson-Pitts, B.J.; Pitts, J.N., “Chemistry of the upper and lower atmosphere”. Academic Press, San Diego. (2000). https://www.ncbi.nlm.nih.gov/pubmed/12873403
Gelencsér A; Siszler K.; Hlavay J., “Toluene–benzene concentration ratio as a tool for characterizing the distance from vehicular emission sources”. Environ. Sci. Tech., 31: 2869 – 2872 (3 pages). (1997). https://pubs.acs.org/doi/abs/10.1021/es970004c doi: 10.1021/es970004c.
Kean, A.J.; Grosjeans, E.; Grosjeans, D.; Harley, R.A.,” On- road measure of carbonyls in California light duty vehicle emissions”. Environmental Science and Technology, 35: 4198-4204 (6 pages). (2001) https://europepmc.org/abstract/med/1171833
Kerbachi, R.; Boughedaoui, M.; Bounoue, L.; keddam, M., Ambient air pollution by Aromatic hydrocarbons in Algiers. Atmospheric environment; 40:3995-4003 (8 pages), (2006).
Kim, Y.M.; Hamad, S.; Harrison, R.M., Concentrations and sources of VOCs in urban and public micro environments. Environment Science Technology. 35(6), 997-1004 (7 pages) (2001). https://pubs.acs.org/doi/abs/10.1021/es000192y.
Khoshand A, Shahbazi Sehrani M, Kamalan HR, Bodaghpour S. 2017, Prediction of Ground-Level Air Pollution Using Artificial Neural Network in Tehran, Anthropogenic Pollution, 1 (1), 2017: 61-67. DOI: 10.22034/apj.2017.1.1.6167.
Lee, S. C.; Chiu, M.Y.; Ho, K.F.; Zou, S. C.; Wang, N.,”Volatile organic compounds (VOCs) in urban atmosphere of Hong Kong”. Chemosphere 48(3): 372-382 (10 pages), (2002).. https://www.sciencedirect.com/science/article/pii/S0045653502000401
Lee, SC.; Chiu, MY; Ho, K.F.; Zou, SC. and Wang, X.,.” Volatile Organic Compounds (VOCs) in urban atmosphere of Hong Kong”. Chemosphere 48(3): 372-382 (10 pages) 2002. http://europepmc.org/abstract/MED/12146626
Millet, D.B.; Goldstein, A.H.; Allan, J. D., “Volatile organic compound measurement at aerosol residence times”. Journal of geophysical research atmosphere, 109: 23 – 29 (6 pages). 2004. https://agupubs.onlinelibrary.wiley.com/doi/abs/10029/2003JD004026%4010.1002/%28ISSN%292169-8996.ITCTPEACE1
Molina, L.T., Kolb, C.E., Defroy, B., Lamb, B.K., Brune, W.H., Jimemez, J.C., Ramos-Vikegass, R., Saarmiento,J., Paramo –Figueroa V.H., Cardenas, B., Gutiernez –Aveday,V,. andMolina,M.I. “Volatile organic compounds in Urban and Industrial Atmosphere: Measurement techniques and data Analysis”. International Journal of Environmental Analytical chemistry, 83:199-217, (2007).
Muhibbu-din, I.E., “Investigation of ambient volatile organic compounds in Mosimi petroleum products depot, Sagamu, Nigeria”. M.Sc Thesis Ladoke Akintola University of Technology, Ogbomoso. (2017).
Nelson P.F.; Quigley S.M.,”The m, p-xylenes: ethylbenzene ratio. A technique for estimating hydrocarbon age in ambient atmospheres”. Atmos Environ. ; 17: 659 – 662 (3 pages), (1983). www.sciencedirect.com/science/article/pii/0004698183901415?via%3Dihub
NESREA,” National Environmental Standards and Regulations Enforcement Agency Air Quality Guideline”, (2009).
Ojiodu, C.C.; Okuo, J.M.; Olumayede, E.G,” Background level of VOCs in rural fishing community of take, Lagos state, South Westerner, Nigeria”. Journal of Science and Technology.58 - 63 (5 pages). (2011). https://www.ajol.info/index.php/ejesm/article/view/96667.
PANDYA G.H. , A.G. GAVANE, A.D. BHANARKAR AND V.K. KONDAWAR Concentrations of volatile organic compounds (VOCs) at an oil refinery. International Journal of Environmental Studies, Vol. 63, No. 3, June 2006, 337–351
Prinn, R.; Cunnold, D.; Rasmussen, R.; Simmonds, P.; Alyea, F.; Crawford, A.; Fraser, P.; Rosen, R., “Atmospheric trends in methyl chloroform and the global average for the hydroxyl radical “. Science 238: 945 –95 (50 pages), (1987). http://europepmc.org/abstract/MED/178293600
Quiram, E.R.; Biller, W.F.,” Determination of trace quantities at hydrocarbons in the Atmosphere”. Analytical chemistry, 30(7):1166-71(1958). https://pubs.acs.org/doi/abs/10.1021/ac60139a001
Rezazadeh, M. A.; Naghavi, Z .K. Zayeri, F.; Salehpour, S.; Seyedi, M.D.,”Occupational exposure of petroleum depot workers to BTEX compounds”. International Archive of Applied Sciences and Technology. Volume 3 [2]: 92 – 96 (4 pages), (2012). https://www.semanticscholar.org/paper/Occupational-exposure-of-petroleum-depot-workers-to-Azari-Konjin/9707550d107e5ca841c6b782171c0c36a28337db
Rnlgesh, K., Singh, Ramteke, D.S.; H.D.; Juneja,; Pandya, G.H., “Ambient air Quality monitoring in terms of volatile organic compounds (VOCs) Occupational Health Exposure at petroleum refinery”. International Journal Environmental Protection, 6:40-49 (9 pages),(2013). www.academicpub.org/DownLoadPaper.aspx?PaperID=4217
Singh, A.K.; Neetu, T.; Jain, C.l., “Concentration of Volatile Organic Compounds (VOCs) in urban atmosphere of National Capital, Delhi, India”. International Journal of Pharmaceutical, Chemical and Biological 2(2), 159-165 (10 pages), (2012). www.ijpcbs.com/files/volume2-2-2012/6.pdf
Srivastava, A., Joseph, A.E., Patil, S., More, A., Dixit, R.C., Prakash, M., “Air toxics in ambient air of Delhi”. Atmos Environ. 2005; 39:59–71. (2005). doi: 10.1016/j.atmosenv.2004.09.053
Srivastava, A.; Sengupta, B.;Dutta, S.A., “Source apportionment of ambient VOCs in Delhi City”. Sci. Total Environ. 343: 207 – 220 (13 pages). (2005). doi: 10.1016/j.scitotenv.2004.10.008.
Srivastava, A,; Joseph A.E,; Devotta S., “Volatile organic compounds in ambient air of Mumbai-India”. Atmos. Environ. 40: 892–903 (11 pages). (2006). https://www.researchgate.net/publication/223035813
Srivastava, A.; Sengupta, B. Dutta, S.A., “Source apportionment of ambient VOCs in Delhi city”. Sci Total Environ. 343: 207–220 (13 pages), (2005). doi: 10.1016/j.scitotenv.2004.10.008.
Suleimanov, R.A., “Comparative characteristics of atmospheric emissions from petrochemical and petroleum processing industries”. NII Med. Truda I Ekol. Cheloveka, Ufa, Russia. Gig Sanit.1:8–10 (2 pages). (1997). http://europepmc.org/abstract/MED/9081889
Tunsaringkarn T, Prueksasit T, Morknoy D, et al. Seasonal and spatial variation of ambient air volatile organic compounds in pathumwan district,Bangkok, Thailand[J]. J Health Res 29 (2015): 135-142.
United State Environment Protection Agency (EPA),”Regional Approaches to improving Air Quality particulate matter”. 200l. www.epa.gov/oar/oaqps/airtrans/pm. html.
United State Environmental Protection Agency, IRIS Assessments 2018, Website; http //www.epa.gov/iris/htm
US-EPA, Air trends. Website;http://www.epa.gov/airtrends/ozone/htm.
Zou Y, Deng X, Li F. Health risk assessment of atmospheric benzene compounds in Guangzhou. Journal of Environment and Health 12 (2014): 1079-1081.
Zhonghua, L.; Dong, W.; Sheng, Z.Y.,” DNA damage and changes of antioxidative enzymes in chronic benzene poisoning mice”. Bing ZaZhi 21: 423 - 425 (2 pages), (2003). https://www.ncbi.nlm.nih.gov/pubmed/1476135
