Kinetic and Equilibrium Studies for Dye Adsorption onto Sugarcane Bagasse and Rice Husks
الموضوعات :Noorul Hudai Abdullah 1 , Nur Atikah Abdul Salim 2 , Baizura Binti Hamid 3 , Muhammad Azri Nizamdin 4 , Muhammad Fauzul Mubarak Ahmad Fadhil 5 , Nurhana Syahira Azman 6 , Nur Farhan Zon 7 , Masiri Kaamin 8 , Amir Khan Suwandi 9 , Noraziah Ahmad 10 , Zainab Mat Lazim 11 , Maria Nuid 12 , Nur Azmira Zainuddin 13
1 - Centre for Diploma Studies, Faculty of Civil Engineering, Universiti Tun Hussein Onn Malaysia, 84600 Muar, Johor, Malaysia
2 - Centre for Diploma Studies, Faculty of Civil Engineering, Universiti Tun Hussein Onn Malaysia, 84600 Muar, Johor, Malaysia
3 - Centre for Diploma Studies, Faculty of Civil Engineering, Universiti Tun Hussein Onn Malaysia, 84600 Muar, Johor, Malaysia
4 - Centre for Diploma Studies, Faculty of Civil Engineering, Universiti Tun Hussein Onn Malaysia, 84600 Muar, Johor, Malaysia
5 - Centre for Diploma Studies, Faculty of Civil Engineering, Universiti Tun Hussein Onn Malaysia, 84600 Muar, Johor, Malaysia
6 - Centre for Diploma Studies, Faculty of Civil Engineering, Universiti Tun Hussein Onn Malaysia, 84600 Muar, Johor, Malaysia
7 - School of Civil Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor, Malaysia
8 - Centre for Diploma Studies, Faculty of Civil Engineering, Universiti Tun Hussein Onn Malaysia, 84600 Muar, Johor, Malaysia
9 - Centre for Diploma Studies, Faculty of Civil Engineering, Universiti Tun Hussein Onn Malaysia, 84600 Muar, Johor, Malaysia
10 - School of Civil Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor, Malaysia
11 - School of Civil Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor, Malaysia
12 - School of Civil Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor, Malaysia
13 - School of Civil Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor, Malaysia
الکلمات المفتاحية: Isotherms, Dye, kinetic, Rice husks, Sugarcane bagasse,
ملخص المقالة :
The textile industry discharges large quantities of highly colored wastewater from industrial processes using chemical components. Many dyes are designed to be chemically stable so that they are difficult to decolorize due to their complex structure and synthetic origin. The dye waste is subsequently released directly to water bodies during the textile finishing process. This improper released has adverse effects on the environment and may reduce photosynthesis in aquatic plants. Even though adsorption techniques have been widely used to remove textile dye from waters, the kinetic models used to describe the adsorption of textile dye onto a porous material is still not yet fully understood. This study investigated different applications of absorbent from sugarcane bagasse (SB) and rice husks (RH) in removing color from aqueous solution and the application of kinetic model for adsorption of color from aqueous solutions onto SB and RH. A batch study was carried out under various mass of adsorptions and contact time with constant with the initial concentration of aqueous solution was 400ADMI. The data obtained from batch experiments showed that the removal of RH (93%) was more efficient than SB (49%). This study also advanced the understanding on the kinetic adsorption study of RH and SB to prove that the adsorbents have potential to reduce dye from synthetic solution. The contribution of this study in the removal of significant dye pollutants from industrial wastewater will require future assessment in a prospective wastewater treatment facility setting.
1. Pearce C.I., Lloyd J.R., Guthrie J.T., 2003. The removal of colour from textile wastewater using whole bacterial cells: a review. Dyes and Pigments. 58, 179–196.
2. Titchou F.E., Akbour R.A., Assabbane A., Hamdani M., 2020. Removal of cationic dye from aqueous solution using Moroccan pozzolana as adsorbent: Isotherms, kinetic studies, and application on real textile wastewater treatment. Groundwater for Sustainable Development. 11, 100405.
3. Çelekli A., Al-Nuaimi A. I., Bozkurt H., 2019. Adsorption kinetic and isotherms of Reactive Red 120 on Moringa oleifera seed as an eco-friendly process. Journal of Molecular Structure. 1195, 168–178.
4. Prescott L.M., Harley J.P., Klein D.A., 2002. Microbiology: Food and Industrial Microbiology. 5th Edition, McGraw-Hill, Boston, 978-981.
5. El Haddad M., 2016. Removal of Basic Fuchsin dye from water using mussel shell biomass waste as an adsorbent: Equilibrium, kinetics, and thermodynamics. Journal of Taibah University for Science. 10(5), 664–674.
6. Mall I.D., Srivastava V.C., Agarwal N. K., 2006. Removal of Orange-G and Methyl Violet dyes by adsorption onto bagasse fly ash - Kinetic study and equilibrium isotherm analyses. Dyes and Pigments. 69(3), 210–223.
7. Huang W., Chen J., He F., Tang J., Li D., Zhu Y., Zhang Y., 2014. Applied Clay Science Effective phosphate adsorption by Zr / Al-pillared montmorillonite: insight into equilibrium, kinetics and thermodynamics. Applied Clay Science. 104, 252–260.
8. Worch E., 2012. Adsorption technology in water treatment: Fundamentals, processes, and modeling. In Walter de Gruyter.
9. Ye H., Chen F., Sheng Y., Sheng G., Fu J., 2006. Adsorption of phosphate from aqueous solution onto modified palygorskites. Separation and Purification Technology. 50(3), 283–290.
10. Liang S., Guo X., Feng N., Tian Q., 2010. Isotherms, kinetics and thermodynamic studies of adsorption of Cu2+ from aqueous solutions by Mg2+/K+ type orange peel adsorbents. Journal of Hazardous Materials. 174(1–3), 756–762.
11. Zhu W.L., Cui L.H., Ouyang Y., Long C.F., Tang X.D., 2011. Kinetic Adsorption of Ammonium Nitrogen by Substrate Materials for Constructed Wetlands. Pedosphere. 21(4), 454–463.
12. Abdul Salim N.A., Abdullah N.H., Khairuddin M.R., Rudie Arman M.A.Z., Khamidun M.H., Fulazzaky M.A., Puteh M.H., 2018. Adsorption of phosphate from aqueous solutions using waste mussel shell. MATEC Web of Conferences. 250, 06013.
13. Ruíz-Baltazar Á., 2020. Kinetic adsorption models of silver nanoparticles biosynthesized by Cnicus Benedictus: Study of the photocatalytic degradation of methylene blue and antibacterial activity. Inorganic Chemistry Communications. 120, 108158.
14. Jung J., Yoon J.H., Chung H.H., Lee M.J., 2002. Radiation treatment of secondary effluent from a sewage treatment plant. Radiation Physics and Chemistry. 65(4–5), 533–537.
15. Vieillard J., Bouazizi N., Bargougui R., Fotsing P.N., Thoumire O., Ladam G., Azzouz A., 2019. Metal-inorganic-organic core–shell material as efficient matrices for CO2 adsorption: Synthesis, properties and kinetic studies. Journal of the Taiwan Institute of Chemical Engineers. 95, 452–465.
16. Çelekli A., Al-Nuaimi A.I., Bozkurt H., 2019. Adsorption kinetic and isotherms of Reactive Red 120 on Moringa oleifera seed as an eco-friendly process. Journal of Molecular Structure. 1195, 168–178.
17. Chen W.T., Lin C.W., Shih P.K., Chang W.L., 2012. Adsorption of phosphate into waste oyster shell: Thermodynamic parameters and reaction kinetics. Desalination and Water Treatment. 47(1–3), 86–95.
18. Ali M., Atikah N., Salim A., Hudai N., Rahim A., Yusoff M., Paul E., 2014. Precipitation of iron-hydroxy-phosphate of added ferric iron from domestic wastewater by an alternating aerobic – anoxic process. Chemical Engineering Journal. 253, 291–297.
