A Comparative Study of the Adsorption Capacity of Tea Leaves and Orange Peel for the Removal of Fe (III) Ion from Wastewater
الموضوعات :
Kazi Mamun
1
(Chemistry Discipline, Khulna University, Khulna-9208, Bangladesh)
Nirob Saha
2
(Chemistry Discipline, Khulna University, Khulna-9208, Bangladesh)
Sumon Chakrabarty
3
(Chemistry Discipline, Khulna University, Khulna-9208, Bangladesh)
الکلمات المفتاحية: Contamination, Heavy metal, Adsorption, Low Cost Adsorbents,
ملخص المقالة :
Adsorption is a very promising and interesting technique for removal of heavy metal ions. In this study orange peel and waste tea leaves were used as low cost adsorbents for removal of iron (III) ion from wastewater. Batch adsorption studies were employed to investigate the influence of pH, time, doges and initial metal ion concentration. The maximum removal capacity of orange peel and waste tea leaves were observed at pH 9 for iron (III) removal. For both adsorbents 75 min was required in order to achieve equilibrium for the adsorption of Fe (III) ion. The influence of adsorbent dose was checked by using different dosage of adsorbents. Adsorption parameters were investigated by using Langmuir and Freundlich isotherm. The removal of Fe (III) ion by using both adsorbents moderately fit the Langmuir and Freundlich isotherm. From the result it was observed that the adsorption capacity of waste tea leaves is higher than orange peel.
1. Ahluwalia S.S., Goyal D., 2007. Microbial and plant derived biomass for removal of heavy metals from wastewater. Biores. Technol. 98, 2243–2257.
2. Lane T.W., Morel F.M., 2000. A biological function for cadmium in marine diatoms. Proc Natl Acad Sci. 97, 4627–4631.
3. Liu X., Hu Q., Fang Z., Zhang X., Zhang B., 2008. Magnetic chitosan nanocomposites: a useful recyclable tool for heavy metal ion removal. Langmuir. 25, 3-8.
4. Alvarez-Ayuso E., Garcia-Sanchez A., Querol X., 2003. Purification of metal electroplating waste waters using zeolites. Water Res. 37, 4855-4862.
5. Ruparelia J., Duttagupta S., Chatterjee A., Mukherj S., 2008. Potential of carbon nanomaterials for removal of heavy metals from water. Desalination. 232, 145-156.
6. Öztaş N.A., Karabakan A., Topal Ö., 2008. Removal of Fe(III) ion from aqueous solution by adsorption on raw and treated clinoptilolite samples. Microporous and Mesoporous Materials. 11, 200–205.
7. Meril D., Shamim A., Jahan A., Cristian B., West P., 2012. Groundwater Iron Assessment and Consumption by Women in Rural Northwestern Bangladesh. International Journal for Vitamin and Nutrition Research. 82, 5-14.
8. Grazuleviciene R., Nadisauskiene R., Buinauskiene J., Grazulevicius T., Effects of Elevated Levels of Manganese and Iron in Drinking Water on Birth Outcomes. Polish Journal of Environmental Studies. 18, 819-825.
9. Coup M.R., Campbell A.G., 1964. The Effect of Excessive Iron Intake upon the Health and Production of Dairy Cows. New Zealand Journal of Agricultural Research. 7, 624-638.
10. Hua M., Zhang S., Pan B., Zhang W., Lv L., Zhang Q., 2012. Heavy metal removal from water/wastewater by nanosized metal oxides: A review. Journal of Hazardous Materials. 211, 317– 331.
11. Fu F., Wang Q., 2011. Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management. 92, 407-418.
12. Jaishankar M., Tseten T., Anbalagan N., Mathew B.B., Beeregowda K.N., 2014. Toxicity, mechanism and health effects of some heavy metals. Interdiscip Toxicol. 7, 60-72.
13. Sheibani A., Shishehbor M.R., Alaei H., 2012. Removal of Fe(III) ions from aqueous solution by hazelnut hull as an adsorbent. International Journal of Industrial Chemistry. 3, 1-4.
14. Wang J., Chen C., 2009. Biosorbents for Heavy Metals Removal and Their Future. Biotechnology Advances. 27, 195-226.
15. Yin P., Xu Q., Qu R., Zhao G., Sun Y., 2009. Adsorption of transition metal ions from aqueous solutions onto a novel silica gel matrix inorganic-organic composite material. J Hazard Mater. 173, 710–716.
16. Gautam R.K., Mudhoo A., Lofrano G., Chattopadhyaya M.C., 2014. Biomass-derived biosorbents for metal ions sequestration: Adsorbent modification and activation methods and adsorbent regeneration. J Environ Chem Eng 2, 239-259.
17. Modin H., Persson K.M., Andersson A., van Praagh M., 2011. Removal of metals from landfill leachate by sorption to activated carbon, bone meal and iron fines. Journal of Hazardous Materials. 189, 749-754.
18. Dakiky M., Khamis M., Manassra A., Mer’eb M., 2002. Selective Adsorption of Cr (VI) in Industrial Wastewater Using Low-Cost Abundantly Available Adsorbents. Advances in Environmental Research. 6, 533-540.
19. Meunier N., Laroulandie J., Blais J.F., Tyagi R.D., 2003. Cocoa shells for heavy metal removal from acidic solutions. Bioresource Technology. 90, 255-263.
20. Bulut Y., Tez Z., 2007. Removal of heavy metals from aqueous solution by sawdust adsorption. Journal of Environmental Sciences. 19, 160–166.
21. Saeed A., Waheed A.M., Iqbal M., 2005. Removal and Recovery of Heavy Metals from Aqueous Solution using Papaya Wood as a New Biosorbent. Separation and Purification Technology. 45, 25-31.
22. Babarinde N.A.A., Babalola J., Adebowale R., 2006. Biosorption of lead ions from aqueous solution by maize leaf International Journal of Physical Sciences. 1, 23-26.
23. Bhattacharya A.K., Mandal S.N., Das S.K., 2006. Adsorption of Zn (III) from Aqueous Solution by Using Different Adsorbents. Chemical Engineering Journal. 123, 43-51.
24. Nascimento M., Soares P.S.M., Souza V.P.D., 2009. Adsorption of heavy metal cations using coal fly ash modified by hydrothermal method. Fuel. 88, 1714-1719.
25. Iman E.S., Nady A.F., Adli A.H., 2013. Removal of Mn (II) and Fe (II) ions From Aqueous Solution Using Precipitation and Adsorption Methods. Journal of Applied Sciences Research. 9. 233-239.
26. Lo S.F., Wang S.Y., Tsai M.J., Lin L.D., 2012. Adsorption capacity and removal efficiency of heavy metal ions by Moso and Ma bamboo activated carbons. Chemical Engineering Research and Design. 90, 1397-1406.
27. Bernard E., Jimoh A., Odigure J.O., 2013. Heavy metals removal from industrial wastewater by activated carbon prepared from coconut shell. Research Journal of Chemical Sciences. 3, 3- 9.
28. Barka N., Qourzal S., Assabbane A., Nounah A., Ait-Ichou Y., 2011. Removal of reactive yellow 84 from aqueous solutions by adsorption onto hydroxyapatite. J Saudi Chem Soc. 15, 263–267.
29. Panday K.K., Prasad G., Singh V.N., 1985. Copper (III) removal from aqueous solutions by fly ash. Water Res. 19, 869–73
30. BadilloAlmaraz V., Trocellier P., Da´vila R.I., 2003. Adsorption of aqueous Zn (III) species on synthetic zeolites. NuclInstrum Methods Phys Res. 210, 424–428.
