An Investigation on Cd and Pb Concentrations of Soils around the Kurdistan Cement Factory in Western Iran
الموضوعات :
1 - Deptartment of Environment, Faculty of Natural Resources and Environment, Malayer University, Malayer, Hamedan, Iran
الکلمات المفتاحية: Iran, soil, Spatial analysis, Cement, Metals,
ملخص المقالة :
   Heavy metals, e.g. Cd and Pb emit and release into the environment during cement production and are deposited into soils. This research was carried out to determine the concentration and spatial distribution of trace elements in top soils around the Kurdistan Cement Factory, west of Iran in order to evaluate the effect of cement factory on the environment. Twenty-four soil samples were collected from surface soils around the factory. Cadmium and lead concentrations in soil samples were determined using acid extraction procedure and atomic absorption spectrophotometric methods. Soils were sampled in four directions of north, south, west and east of cement factory and at intervals of 400 m to 800 m distance from the factory. Ordinary kriging technique in ArcGIS was performed to map the spatial patterns of heavy metals. The results showed that concentrations of Pb and Cd were weakly correlated with each other indicating these metals in soils may be from the different pollution source. No distinct spatial trends of Pb with its low accumulation in the soils demonstrate that Pb content was mainly influenced by soil factors. The spatial pattern of the cadmium showed that the cement factory emission has an impact on the soil’s cadmium content, since the highest level in area close to the cement factory. Estimated Pollution Load Index (PLI) showed that the soils around the factory were practically uncontaminated by metals.Â
- Kabir E., Ray S., Kim KH., Yoon H.O., Jeon E.C., Kim Y.S., Cho Y.S., Yun S.T., Brown R.J.C., 2012. Current status of trace metal pollution in soils affected by industrial activities. Sci World J. Article ID 916705. 18 pages. doi:10.1100/2012/916705.
- Mahmood A., Malik R.N., 2014. Human health risk assessment of heavy metals via consumption of contaminated vegetables collected from different irrigation sources in Lahore, Pakistan. Arab J Chem. 7, 91âââ99.
- Adekola F.A., Inyinbor A.A., Abdul Raheem A.M.O., 2012. Heavy metals distribution and speciation in soils
- around a mega cement factory in north-central Nigeria. Ethiopian J Environ Stud Manag. 5(1),11-19.
- Kulkarni D.K., Delbari, A.S., Mahajan D.M., 2104. Bio concentration factor (BCF) for heavy metals detection and selection of hyper-accumulator plants case study of Pune-india and Tehran -Iran. Indian J Fundamental Appl Life Sci. 4(1), 163-170.
- Sharma S.S., Dietz K.J., 2008. The relationship between metal toxicity and cellular redox imbalance. Trends Plant Sci. 14, 43âââ50.
- Isikli B., Demir T.A., ÃÅrer S.M., Berber A., Akar T., Kalyoncu C., 2003. Effects of Chromium exposure from a cement factory. Environ Res. 91, 113-118.
- Bilen S., 2010. Effect of cement dust pollution on microbial properties and enzyme activities in cultivated and no-till soils. Afr J Microbiol Res. 4, 2418-2425.
- Demir T.A., Isikli B., Urer S.M., Berber A., Akar T., Canbek M., Kalyoncu C., 2005. Nickel exposure and its effects: Biometals. 18, 7-13.
- Ahiamadjie H., Adukpo O.K., Tandoh J.B., Gyampo O., Nyarku M., Mumuni I.I., Agyemang O., Ackah M., Dampare S.B., 2011. Determination of the Elemental Contents in Soils Around Diamond Cement Factory, Aflao. Res J Environ Earth Sci. 3(1), 46-50.
- Al-Khashman O.A., Shawabkeh R.A., 2006. Metal distribution in soils around the cement factory in Southern Jordan. Environ Pollut. 140, 387-394.
- Schuhmacher M., Bocio A., Agramunt M.C., Domingo J.L., De Kok H.A.M., 2002. PDCC/F and metal concentration in soil and herbage samples collected in the vicinity of a cement plant. Chemosphere. 48, 209-217.
- Addo M.A., Darko E.O., Gordon C., Nyarko B.J.B., Gbadago L.J.K., Nyarko E., Affum H.A., Botwe B.O., 2012. Evaluation of Heavy Metals Contamination of Soil and Vegetation in the Vicinity of a Cement Factory in the Volta Region, Ghana. Int J Sci Technol. 2(1), 40-50.
- Ogunkunle C.O., Fatoba P.O., 2013. Pollution Loads and the Ecological Risk Assessment of Soil Heavy Metals around a Mega Cement Factory in Southwest Nigeria. Pol J Environ Stud. 22, 2, 487-493.ââŽ
- Moslempour M.E., Shahdadi S., 2013. Assessment of Heavy Metal Contamination in Soils around of Khash Cement Plant, SE Iran. Iran J Earth Sci. 5, 111-118.
- Lafta J.G., Fadhil H.S., Hussein A.A., 2013. Heavy Metals Distribution and the Variation of Soil Properties around Alqaim Cement Factory in Anbar Governorate - Iraq. Int J Engin Adv Technol (IJEAT). 3(1), 289-291.
- Dbkowska- Naskrt H., Jaworska H., DÃ âugosz J., 2014.Assessment of the Total Nickel Content and its Available Forms in the Soils Around Cement Plant Lafarge Poland. Int J Environ Res. 8(1), 231-236.
- Muller G., 1969. Index of geo-accumulation in sediments of Rhine River. Geochem J. 2, 108 âââ 118.
- HÃÂ¥kanson L., 1980. An ecological risk index for aquatic pollution control-a sedimentological approach. Water Res. 14, 975-1001.
- Tijani M.N., Jinno K., Hiroshiro Y., 2004. Environmental impact of heavy metal distribution in water and sediment of Ogunpa River, Ibadan area, southwestern Nigeria. J Min Geol. 40(1), 73-83.
- Tomilson D.C., Wilson J.G., Harris C.R., Jeffrey D.W., 1980. Problems in assessment of heavy metals in estuaries and the formation of pollution index. Helgol Meeresunlters. 33, 566-575.
- Sadhu K., Adhikari K., Gangopadhyay A., 2012. Assessment of Heavy Metal Contamination of Soils In and Around Open Cast Mines of Raniganj Area, India. Int J Environ Engin Res. 1(2), 77-85
- Taylor S.R., 1964. Abundance of chemical elements in the continental crust: a new table. Geochimicu et Cosmochimicn Acta. 28, 1273-1285.
- Krige D.G., 1951. A statistical approach to some basic mine valuation problems on the Witwatersrand. J Chem Metallur Mining Soc South Af. 52, 119âââ139.
- Webster R., Oliver M.A., 2001. Geostatistics for Environmental Scientists; Wiley: Chichester, UK.
- Goovaerts P., 1999. Geostatistics in soil science: state-of-the-art and perspectives. Geoderma. 89, 1-45.
- TakáàP., Szabová, T., ý Benková K.M., 2009. Heavy metals and their bioavailability from soils in the long-term polluted Central Spià ¡ region of SR. Plant Soil Environ. 55(4), 167âââ172.
- Ogunkunle C.O., Fatoba P.O., 2014. Contamination and spatial distribution of heavy metals in topsoil surrounding a mega cement factory. Atmospheric Pollut Res. 5, 270âââ282.
- Kakareka S., Kukharchyk T., 2011. Towards improvement of heavy metals emission assessment methodology from cement production in EMEP/EEA AEI Guidebook. Proceedings 12th Joint Tfeip/Eionet Meeting. 2011, May 2âââ3, Stockholm, Sweden.
- OSPAR 2002. Commission. Hazardous Substances Series. Cadmium.
- Liu Z.P., Shao M.A., Wang Y.Q., 2013. Large-scale spatial interpolation of soil pH across the Loess Plateau, China. Environ Earth Sci. 69, 2731âââ2741.
- Addo M.A., Darko E.O., Gordon C., Nyarko B. J. B., 2013. Contamination of soils and loss of productivity of Cowpea (Vigna unguiculata L.) caused by cement dust pollution. Int J Res Chem Environ. 3(1), 272-282.
- Estifanos S., 2014. Investigating the Distribution of Selected Major and Trace Metals in Lithogenic Environment near Cement Factory, Mekelle, Ethiopia. J Environ Protec. 5, 144-155.