Synthesis and characterization of some antifungal Oalkyl (O-aryl) trithiophosphato derivatives of 1,3,2- dioxaborinanes
الموضوعات : Journal of the Iranian Chemical ResearchAlok Chaturvedi 1 , Mukesh Gupta 2 , Kiran Sankhala, 3
1 - Synthetic and Surface Science Laboratory, Dept. of Chemistry, Govt. College, Ajmer (Raj.), India
2 - Synthetic and Surface Science Laboratory, Dept. of Chemistry, Govt. College, Ajmer (Raj.), India
3 - Synthetic and Surface Science Laboratory, Dept. of Chemistry, Govt. College, Ajmer (Raj.), India
الکلمات المفتاحية: 2-chloro-1, 3, 2-dioxaborinanes, O-alkyl(O-aryl)trithiophosphates (1H, 11B, 31P )spectral studies, Antifungal activity,
ملخص المقالة :
Complexes of the type (OCH2C(CH3)2CH2OB)2S2P(S)OR (where R=Me,Et,Pri,Bui,Ph,CH2Ph) have beensynthesized by the reactions of 2-chloro-1,3,2-dioxaborinanes and potassium salt of O-alkyl (O-aryl)trithiophosphates in 2:1 molar ratio in refluxing benzene. The product are formed as white or light yellowcoloured monomeric solid, soluble in common organic solvents and exhibit high sensitivity towardsatmospheric moisture. These complexes have been characterized by elemental analysis (C,H,S,B), molecularweight measurement, IR and NMR (1H,11B,31P) spectral studies. On the basis of above studies it is postulatedthat boron is in three coordinated state. The newly synthesized complexes show effectiveness againstpowdery mildew disease at a fixed interval of days.
[1] O.P.Singh, A.Chaturvedi, D.B. Saxena, R.K. Mehrotra, G.Srivastava, Monatshafte fur Chemie, 125
(1994) 607-613.
[2] A. Chaturvedi, P.N. Nagar, G.Srivastava, Phosphorus Sulfur and Silicon, 90 (1994) 229-233.
[3] G.E.Mc Achran, S.G. Shore, Inorg. Chem, 5 (1966) 2044-2049.
[4] S.K.Mehrotra, G. Srivastava, R.C. Mehrotra, Synth. React Inorg. Met. Org-Chem, 4 (1974) 27-36.
[5] P.N.Bhardwaj, G. Srivastava, J. Indian Chem. Soc. 59 (1982) 300-307.
[6] P.N. Nagar, G. Srivastava, R.C. Mehrotra, Synth. React. Inorg. Met-Org. Chem., 12 (1982) 749-759.
[7] O.P. Singh, R.K. Mehrotra, G. Srivastava, Synth. React. Inorg. Met Org. Chem., 21 (1991) 717-728.
[8] A.S. Kothiwal, A. Singh, A.K. Rai, R.C. Mehrotra, Ind. J. Chem. 24 (1985) 828-834.
[9] Y.P. Singh, P. Rupani, A. Singh, A.K. Rai, R.D. Rogers, J.L. Atwood, Inorg. Chem., 25 (1985) 3076-
3081.
[10] A. Chaturvedi, C.S. Sharma, P.N. Nagar, Phosphorus sulfur and Silicon, 178 (2003) 1923-1929.
[11] L. Chordia, A. Chaturvedi, Phosphorus, Sulfur and Silicon, 182 (2007) 2821-2831.
[12] Y. Kimuva, T. Wakabayashi, K. Okada, T. Wada, H. Nishikawa, Wear, 232 (1999) 199-206.
[13] M. Lovell, C.F. Higgs, P. Deshmukh, A.J. Mobleymat, Pro. Teeh, 177 (2006) 87-90.
[14] C.C. Klepper, J.M. Williams, J.J.J. Truhan, J. Qu, L. Riestev, R.C. Hazelton, J.J. Moshchella, P.J. Blau,
J.P. Anderson, O.O. Popooia, M.D. Keitz, Thin Solid films, 516 (2008) 3070-3080.
[15] J.H.Wu, B.S.Phillips, W.Jiang, J.H.Sanders, J.S. Zabinsk, A.P. Malshe, Wear 261 (2006) 592-599.
[16] B.A. Baldwin, Wear, 45 (1977) 345-353.
[17] Z.S. Hu, Y. Yie, L.G. Wang, G.X. Chen, J.X. Dong, Tribol. Lett. 8 (2000) 45-50.
[18] W. Liu, Z. Jin, Q. Xue, Lubricat. Sci.7 (1994) 49-60.
[19] J.M. Herdan, Lubricat Sci. 2 (2000) 265-276.
[20] W. Liu, Q. Xue, X. Zhang, H. Wang, C. Huang, Tribol. Trans. 48 (1992) 475-479.
[21] G. Shen, Z. Zheng, Y. Wan, X. Xu, L. Cao, Q. Yue, T. Sun, A. Liu, Wear, 246 (2000) 55-58.
[22] L. Chordia, A. Chaturvedi, Main group Met. Chem. 31 (2008) 319-329.
[23] L. Chordia, A. Chaturvedi, J. Chin. Chem. Soc. 56 (2009) 636-641.
[24] P.N. Bhardwaj, G. Srivastava, Bull. Chem. Soc. Japan 51 (1978) 524-531.
[25] A.I. Vogel. A Textbook of Qualitative Inorganic Analysis ELBS, IV Edition 1973.
[26] A.K.Sobti, A.K. Mathur, B.S. Siradhana, India Phytopathology 45 (1992) 200-208.
