Determination of lead and cadmium in water samples by cloud point extraction prior to flame atomic absorption spectrometry determination
الموضوعات : Journal of the Iranian Chemical ResearchYaping Ding 1 , Li Li 2 , Ruixiang Bian 3 , Dongsheng Zhao, 4
1 - Department of Chemistry, Shanghai University, Shanghai 200444, PR. China
2 - Department of Chemistry, Shanghai University, Shanghai 200444, PR. China
3 - Department of Chemistry, Shanghai University, Shanghai 200444, PR. China
4 - Department of Chemistry, Shanghai University, Shanghai 200444, PR. China
الکلمات المفتاحية: Cadmium, Lead, Cloud point extraction, Flame atomic absorption spectrometry, Diethyldithiocarbamate,
ملخص المقالة :
Pb and Cd in water samples were determined by cloud point extraction (CPE) with sodiumdiethyldithiocarbamate (DDTC) as the chelating agent and octylphenoxypolyethanl (Triton X-114) asthe surfactant prior to flame atomic absorption spectrometry (FAAS) determination. The main factorsof affecting the extraction and detection processes were optimized. The preconcentration of 10 mL ofstandard solutions gave enhancement factors of 35 and 75 and the detection limits of 9.41 and 0.40ng mL-1 for Pb and Cd, respectively. The proposed method was applied satisfactorily to thedetermination of Pb and Cd in seawater and lake water. Good agreement was obtained between theadded and measured analyte amounts through the recovery of experiments.
[1] L. Elçi, U. Sahin, Ş. Öztaş, Talanta 44 (1997) 1017.
[2] G. Doner, A. Ege, Anal. Chim. Acta 547 (2005) 14.
[3] S. Saracoglu, M. Soylak, L. Elci, J. Anal. Chem. 58 (2003) 1127.
[4] D.J. Mackey, J.E. O’Sullivan, R.J. Watson, G. Dal Pont. Mar. Chem. 59 (1997) 113.
[5] E. Pehlivan, A. Turkan, J. Hazard. Mater. 140 (2007) 299.
[6] M. Soylak, U. Divrikli, L. Elci, M. Dogan, Talanta 56 (2002) 565.
[7] O. Marta, M. Luconi, F. Silva, A. Roberto, P. Liliana, Talanta 51 (2000) 123.
[8] J. Manzoori, Gh. Karim-Nezhad, Anal. Chim. Acta 521 (2004) 173.
[9] F. Ahmadi, A. Khanmohammadi, Z. Tavakoli, J. Jafarpour, J. Iran. Chem. Res. 1 (2008) 1.
[10] J.G. Chen, H.W. Chen, S.H. Chen, Chem. Res. Chinese Uuniv. 23 (2007) 143.
[11] R.A. Pedro, A.G. Raul, M. Susana, E.D. Irma, D.M. Luis, Talanta 75 (2008) 307.
[12] N. Shokoufi, F. Shemirani, F. Memarzadeh, Anal. Chim. Acta 601 (2007) 204.
[13] M.G.A. Korn, J.B. Andrade, D.S. Jesus, Talanta 69 (2006) 16.
[14] C. Ortega, S. Cerutti, R.A. Olsina, L.D. Martínez, M.F. Silva, J. Pharm. Biomed. Anal. 36 (2004)
721.
[15] A. Ohashi, T. Hashimoto, H. Imura, K. Ohashi, Talanta 73 (2007) 893.
[16] S. Shariati, Y. Yamini, M.K. Zanjani, J. Hazard. Mater. 156 (2008) 583.
[17] H. Cesur. J. Trace Microprobe T. 21 (2003) 627.
[18] M. Kompany-Zareh, A. Massoumi, H. Tavallali. Microchem. J. 63 (1999) 257.
[19] C.G. Yuan, G.B. Jiang, Y.Q. Cai, B. He, J.F. Liu. Atom. Spectrosc. 25 (2004) 170.
[20] E.K. Paleologos, C.D. Stalikas, S.M. Tzouwara-Karayanni, M.I. Karayannis, Anal. Chim. Acta 436
(2001) 49.
[21] E.K. Paleologos, D.I. Giokas, M.I. Karayannis, Trac-Trend. Anal. Chem. 24 (2005) 426.
[22] A. Safavi, H. Abdollahi, M.R. Hormozi Nezhad, R. Kamali, Spectrochim. Acta A 60 (2004) 2897.
