4-Chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (BINOL-PCl) as a Bulky and Efficient Reagent for the Transformation of Symmetric and Asymmetric Benzoins to Corresponding Benziles
الموضوعات : Journal of the Iranian Chemical ResearchNader Noroozi Pesyan 1 , Mahnaz Saraei 2 , Bakhshali Massoumi 3 , Maryam Sarbazi 4
1 - Department of Chemistry, Faculty of Science, Urmia University, 57159, Urmia, Iran
2 - Department of Chemistry, Tabriz Payam-e-noor University, Tabriz, Iran
3 - Department of Chemistry, Tabriz Payam-e-noor University, Tabriz, Iran
4 - Department of Chemistry, Tabriz Payam-e-noor University, Tabriz, Iran
الکلمات المفتاحية: 4-Chloro-3, 5-dioxaphosphacyclohepta[2, 1-, 3, 4-']dinaphthalene, Transformation reagent, Benzoin, Benzil,
ملخص المقالة :
4-Chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (BINOL-PCl) was found to be an efficient, bulky and selective reagent for the transformation of symmetric and asymmetric benzoins to the corresponding benziles at 0 °C to room temperature under nitrogen atmosphere in good yield.
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