ابرخازن‌های پایه مکسن و چشم‌‏انداز آینده آن

الموضوعات :

طیبه محبی ¹ , مجید میرزایی ² , مسعود همدانیان ³

1 - دانشجوی دکتری گروه شیمی، دانشگاه کاشان، کاشان، ایران.
2 - استادیار گروه پژوهشی مواد غیرفلزی، پژوهشگاه نیرو، تهران، ایران.
3 - عضو هیات علمی گروه نانوشیمی(دانشیار)، دانشگاه کاشان، گروه شیمی،کاشان، ایران صندوق پستی: 51167-87317

تاريخ الإرسال : 06 الثلاثاء , صفر, 1445 تاريخ التأكيد : 21 الأحد , صفر, 1446 تاريخ الإصدار : 26 الجمعة , صفر, 1446

الکلمات المفتاحية: چندسازه, مکسن, ابرخازن,

ملخص المقالة :

       مکسن‌‏‌‌ها (MXene) به‌­دلیل ساختار بی­‌همتا و گروه‏های عامل شیمیایی قابل‌تنظیم، یک سری ویژگی شگفت‏‌انگیز دارند. کاربرد مکسن‌‏ها در ذخیره‏‌سازی انرژی الکتروشیمیایی به­ویژه نشان‌­دادن پتانسیل بالا در کاربردهای ابرخازن توجه ویژه‏ای را به خود جلب کرده است. در مقایسه با سایر مواد، مکسن‌‏ها انعطاف مکانیکی بالا، چگالی انرژی بالا و کارایی الکتروشیمیایی خوبی دارند. بنابراین، به ویژه به­‌عنوان مواد الکترود برای ابرخازن­‌ها مناسب هستند. با این حال، مشابه سایر مواد دو بعدی، به­‌دلیل نیروهای قوی واندروالس، لایه‌های مکسن به‌ناچار انباشته می‌شوند که منجر به از دست­دادن شدید مکان‌های فعال الکتروشیمیایی می‌شوند. اگر بتوان تجمع لایه‌های مکسن را به‌طور مؤثری مهار کرد، کارایی الکتروشیمیایی آن‌ها افزایش می‌یابد. بهینه‏‌سازی ساختاری مکسن‌‏‏ها و دوپه‌­شدن آن­ها با مواد دیگر دو راه­برد موثر چشمگیر است. این مقاله، پیشرفت‌های اخیر در سنتز مکسن، ویژگی اساسی، و مواد چندسازه را با تمرکز بر آخرین کارایی الکتروشیمیایی الکترودها/دستگاه‌های مبتنی بر مکسن مرور می‌کند و چالش‌ها و فرصت‌های جدیدی را که مکسن در زمینه ذخیره‌سازی انرژی با آن مواجه است، ارائه می‌کند.

 

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