[B(OH)3]0.78[B(OH)2(OSO3H)]0.22 as a new, cheap and eco-friendly catalyst for synthesis of acylals at room temperature under solvent free conditions
الموضوعات : Iranian Journal of CatalysisBiBi Fatemeh Mirjalili 1 , Abdolhamid Bamoniri 2 , Fahimeh Kalantari 3
1 - Department of Chemistry, College of Science, Yazd University, P. O. Box 89195-741, Yazd. Iran.
2 - Department of Organic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran.
3 - Department of Chemistry, College of Science, Yazd University, P. O. Box 89195-741, Yazd. Iran.
الکلمات المفتاحية: Aldehyde, Protecting group, [B(OH)3]0.78[B(OH)2(OSO3H)]0.22, Acylal, BSA,
ملخص المقالة :
[B(OH)3]0.78[B(OH)2(OSO3H)]0.22 or (BSA) was simply prepared by addition of chlorosulfonic acid to commercial boric acid at room temperature. This cheap and green solid acid was used as an efficient catalyst for synthesis of acylals from aldehydes under solvent-free conditions at room temperature.
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