Facile and mild synthesis of 1-substituted-1H-1,2,3,4-tetrazoles catalyzed by methanesulfonic acid under solvent-free conditions

الموضوعات : Iranian Journal of Catalysis

Hossein Naeimi ¹ , Fatemeh Kiani ² , Mohsen Moradian ³

1 - Department of Organic Chemistry, Faculty of Chemistry, University of Kashan, P.O. Box: 87317-51167, Kashan, I.R. Iran.
2 - Department of Organic Chemistry, Faculty of Chemistry, University of Kashan, P.O. Box: 87317-51167, Kashan, I.R. Iran.
3 - Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, P.O. Box: 87317-51167, I.R. Iran.

تاريخ الإرسال : 05 الأربعاء , ذو القعدة, 1434 تاريخ التأكيد : 13 الإثنين , صفر, 1435 تاريخ الإصدار : 28 الأحد , محرم, 1435

الکلمات المفتاحية: Solvent-free, Methanesulfonic acid, Room temperature, 1H-tetrazoles, Primary amines,

ملخص المقالة :

Methanesulfonic acid (MSA) was found to be an efficient catalyst for the synthesis of 1-substituted-1H-1,2,3,4-tetrazoles. A series of 1-substituted tetrazole compounds were synthesized from the reaction of various primary amines, sodium azide and triethyl orthoformate in the presence of catalytic amounts of MSA at room temperature. In this protocol, some of the tetrazole derivatives were synthesized in good to excellent yields and convenient reaction times. This method has the advantages of simple methodology and easy work-up.

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