Kinetics inversion of chloro-olefine in the solid acid system
الموضوعات : Iranian Journal of Catalysis
1 - Faculty of Science, Chemistry Department, Golestan University, Gorgan, Iran
الکلمات المفتاحية: Heterogeneous catalysis, Isomerization of chloro- olefin, Kinetics, Mossbauer spectroscopy,
ملخص المقالة :
The reaction kinetics of the isomerization 3,4-dichlorobutene-1 to 1,4-dichlorobutene-2 was investigated by using gas-liquid chromatography method in the presence of Fe2O3/MgO as solid catalyst in the temperature range 25-55°C. Fe2O3/MgO has been prepared by the support saturation method, tested in the isomerization of 3, 4-dichlorobutene-1 into 1, 4-dichlorobutene-2. This catalyst shows a high activity opposite to pure MgO in this reaction. The present investigation focuses on the reactivity of Fe2O3/MgO with the 5 wt % Fe2O3 on the surface of MgO. At the optimizing conditions, the activation parameters have been evaluated using the Arrhenius and Eyring plots. The structure of catalyst was investigated by using Mossbauer spectroscopy.
[1] A.YU. Bogomolov, P.Y. Gerasimov, V.V. Smirnov, T.N. Rostovshchikova, Kinet. Catal. 36 (1995) 607-612.
[2] A.YU. Bogomolov, V.V. Smirnov, T.N. Rostovshchikova, P.Y. Gerasimov, Kinet. Catal. 36 (1995) 232-240.
[3] V.V. Smirnov, E.N. Golubeva, T.N. Rostovshchikova, Kinet. Catal. 33 (1992) 58-68.
[4] T.N. Rostovshchikova, V.V. Smirnov, E.V. Vovk, Kinet. Catal. 33 (1992) 682-687.
[5] T.N. Rostovshchikova, V.V. Smirnov, A.Yu. Bogomolov, Vestn. Mosk, Univ. Ser. 2. Khim. 36 (1995) 145-151.
[6] G. Henrici-Olivé, S. Olivé, J. Organomet. Chem. 29 (1971) 307–311.
[7] T.N. Rostovshchikova, V.V. Smirnov, A.I. Kokorin, J. Mol. Catal. A: Chem. 129 (1998) 141-145.
[8] T.N. Rostovshchikova, V.V. Smirnov, V.M. Kozhevin, D. A. Yavsin, S.A. Gurevich, Kinet. Catal. 44 (2003) 555-559.
[9] L.I. Trakhtenberg, G.N. Gerasimov, V.K. Potapov, T.N. Rostovshchikova, V.V. Smirnov, V.Yu. Zufman, Vestn. Mosk, Univ., Ser. 2. Khim. 42 (2001) 325-332.
[10] C. Kurts, Y. Arita, W. Weiss, W. Ranke, R. Schlogel, Topics Catal. 14 (2001) 111-117.
[11] H. Hayashi, L.Z. Chen, T. Tago, M. Kishida, K. Wakabayshi, Appl. Catal. A: Gen. 231 (2002) 81-86.
[12] N.N. Greenwood, The Moss Bauer spectra of chemical compounds, Chemistry in Britain, 1967.
[13] I.P. Suzdalev, Dynamic effects in the γ- resonance spectroscopy, Atomized, Moscow, 1979.
[14] H.R. Verma, Atomic and nuclear analytical methods, Springer-Verlag Berlin Heidelberg, 2007.
[15] M.V. Tsodikov, V.Ya. Kugel, E.V. Slivinskii, G.N. Bondarenko, Yu.V. Maksimov, M.A. Alvarez, M.C. Hudalgo, J.A. Navio, Appl. Catal. A: Gen. 193 (2000) 237-247.
[16] I.P. Suzdalev, V.N. Buravtsev, V.K. Imshennik, Yu.V. Maksimov, V.V. Matveev, A.V. Volynskaya, A.X. Trautwein, H. Winkler, Z. Phys. D, At. Mol. Clusters 36 (1996) 163-169.
[17] M.V. Tsodikov, T.N. Rostovshchikova, V.V. Smirnov, O.I. Kiseleva, Y.V. Maksimov, I.P. Suzdalev, V.N. Ikorskii, Catal. Today 105 (2005) 634-640.
[18] T.N. Rostovshchikova, V.V. Smirnov, M.V. Tsodikov, O.V. Bukhtenko, Y.V. Maksimov, O.I. Kiseleva, D.A. Pankratov, Russ. Chem. Bull. Int. Ed. 54 (2005) 1418-1426.
[19] E.M. Asatryan, N.L. Saakyan, E.V. Golneva, G.T. Martirosyan, Arm. Khim. Zhur. 39 (1986) 584-590.
[20] T.N. Rostovshchikova, O.I. Kiseleva, V.V. Smirnov, Yu.V. Maksimov, I.P. Suzdalev, V.E. Prusakov, M.V. Tsodikov, V.N. Ikorskii, Russ. Chem. Bull. Int. Ed. 55 (2006) 1768-1774.
