Ionic liquids as efficient catalysts for synthesis of phosphorylated dialkyl succinates containing phthalazin-1-one moieties
الموضوعات : Iranian Journal of Catalysis
Ziba Tavakoli
1
(Department of Chemistry, Islamic Azad University, Science and Research Branch, Ponak Tehran, Iran.)
Elnaz Ghasemi
2
(Department of Chemistry, Islamic Azad University, Science and Research Branch, Ponak Tehran, Iran.)
Issa Yavari
3
(Department of Chemistry, Islamic Azad University, Science and Research Branch, Ponak Tehran, Iran.)
الکلمات المفتاحية: Ionic Liquid, Phosphorylation, Organocatalysis, 2H-Phthalazin-1-one, Acetylenic ester,
ملخص المقالة :
Ionic liquids such as 1,3-dialkylimidazolium salts make excellent catalysts and solvents for synthesis of dialkyl 2-(dialkoxyphosphoryl)-3-(1-oxo-1-H-phthalazin-2-yl)succinates from 2H-phthalazin-1-one, dialkyl acetylenedicarboxylates, and trialkyl phosphites. Under similar conditions, triphenyl phosphite led to dialkyl 2-(diphenoxyphosphoryl)-3-(1-oxo-1-H-phthalazin-2-yl)succinates. The ionic liquid was readily recycled and can be reused four times without significant loss of activity or mass.
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