Sulfonated porous carbon catalyzed esterification of free fatty acids
الموضوعات : Iranian Journal of CatalysisArash Shokrolahi 1 , Abbas Zali 2 , Hamid Pouretedal 3
1 - Chemistry Department, Malek-ashtar University of Technology, Shahin-shahr, P.O.Box 83145-115, I.R. Iran
2 - Chemistry Department, Malek-ashtar University of Technology, Shahin-shahr, P.O.Box 83145-115, I.R. Iran
3 - Chemistry Department, Malek-ashtar University of Technology, Shahin-shahr, P.O.Box 83145-115, I.R. Iran
الکلمات المفتاحية: Solid acid, Sulfonated Porous Carbon, Esterification, fatty acids,
ملخص المقالة :
The esterification of free fatty acids (FFA) with methanol is studied using Sulfonated Porous Carbon (SPC) as catalyst. In compare to the amorphous sugar catalyst and protonated Nafion, the proposed catalyst shows stability and high efficient performance in biodiesel production. The highest initial rate of oleic acid conversion is obtained at catalyst loading of 1 mmol H+ and mole ratio of MeOH/Oleic acid of 10. The prepared Sulfonated Porous Carbon reused at least three times without loss of activity.
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