Brönsted acidic ionic liquid ([Hmim][HSO4]) as a green, efficient and reusable catalyst for the tetrahydropyranylation of alcohols
الموضوعات : Iranian Journal of CatalysisAbdol Hajipour 1 , Fatemeh Rafiee 2
1 - Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan 84156, IRAN
Department of Pharmacology, University of Wisconsin Medical School, 1300 University Avenue, Madison, WI, USA 53706-1532
2 - Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan 84156, IRAN
الکلمات المفتاحية: Alcohols, Brönsted acidic ionic liquids, Catalyst, Tetrahydropyranylation,
ملخص المقالة :
A simple and mild method for tetrahydropyranylation of alcohols is reported at room temperature using a catalytic amount of 3-methylimidazolinium hydrogensulfate([Hmim]HSO4) as a green, efficient and reusable catalyst. Using solvent-free conditions, non-toxic and inexpensive materials, modest and clean work-up, short reaction times and high yields of the products are the advantages of this method.
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