Oxidation of benzylic alcohols with molecular oxygen catalyzed by Cu3/2[PMo12O40]/SiO2

الموضوعات : Iranian Journal of Catalysis

Hamid Aliyan ¹ (Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran.)
Razieh Fazaeli ² (Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran.)
Ahmad Reza Massah ³ (Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran.)
Hamid Javaherian Naghash ⁴ (Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran.)
Saeed Moradi ⁵ (Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran.)

تاريخ الإرسال : 11 الإثنين , ربيع الأول, 1432 تاريخ التأكيد : 29 الثلاثاء , جمادى الأولى, 1432 تاريخ الإصدار : 29 الأربعاء , جمادى الثانية, 1432

الکلمات المفتاحية: green chemistry, aerobic alcohol oxidation, Polyoxometalates (POMs),

ملخص المقالة :

The aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using Cu3/2[PMo12O40]/SiO2 as catalyst under mild reaction condition. This reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.

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