Transition-metal modified mesoporous silica nanoparticles as highly effective heterogeneous catalysts for discoloration of Basic red 5 in aqueous solution

الموضوعات : Iranian Journal of Catalysis

Fatemeh Mahfoozi ¹ (Faculty of Chemistry, North Tehran Branch, Islamic Azad University, Hakimiyeh, Tehran, Iran.)
Ali Mahmoudi ² (Faculty of Chemistry, North Tehran Branch, Islamic Azad University, Hakimiyeh, Tehran, Iran.)
Mohammad Reza Sazegar ³ (Faculty of Chemistry, North Tehran Branch, Islamic Azad University, Hakimiyeh, Tehran, Iran.)
Khodadad Nazari ⁴ (Future Bioenergy Solutions Inc., North Vancouver, BC, V7P 3P9, Canada)

تاريخ الإرسال : 12 السبت , جمادى الثانية, 1443 تاريخ التأكيد : 06 الأحد , ذو القعدة, 1443 تاريخ الإصدار : 02 الأربعاء , ذو القعدة, 1443

الکلمات المفتاحية: Photocatalytic, Modification, Discoloration, MSN, Basic red 5,

ملخص المقالة :

Mesoporous silica nanoparticles (MSNs) were synthesized hydrothermally and modified with Co2+ and Zn2+. The as-prepared samples were denoted as MSN, Co-MSN(X), and Zn-MSN(X), where X is the Si/M molar ratio. In addition, co-modified MSN samples with both cations were also prepared and denoted as Co-Zn(Y)-MSN(X), where Y indicates the Zn2+ content in the range of 1-7 wt.% relative to Co2+. Correctness of the anticipated structures was approved by FTIR, XRD, SEM, EDX, BET, and XRF analyses. It was found that Co-Zn(7)-MSN(75) can be used as an efficient photocatalyst for discoloration of basic red 5 under very mild conditions. Up to 86% of basic red 5 was discolored after 3.75 h under the optimized conditions including catalyst dosage of 0.025 mg mL-1, pH=7, and irradiation of 4×8 W UV (254 nm) lamps. By using the Langmuir–Hinshelwood kinetics model, it was found that the reaction followed a pseudo-first-order kinetic.

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