Novel nanomagnetic material with dimethylamino tag: a selective and recyclable catalyst for the reaction of malononitrile, aryl aldehydes and dimedone
الموضوعات : Iranian Journal of CatalysisAysoda Ghobadpoor 1 , Mohammad Mehdi Eskandari 2 , Abdolkarim Zare 3 , Mostafa Karami 4
1 - Department of Chemistry, Payame Noor University, PO Box 19395-3697, Tehran, Iran.
2 - Nanotechnology Research Center, Research Institute of Petroleum Industry (RIPI), PO Box 1485733111, Tehran, Iran.
3 - Department of Chemistry, Payame Noor University, PO Box 19395-3697, Tehran, Iran.
4 - Department of Chemistry, Payame Noor University, PO Box 19395-3697, Tehran, Iran.
الکلمات المفتاحية: Multi-component reaction, Nanomagnetic catalyst, Nano-Fe3O4@SiO2@R-NMe2 ([NFSRN]), 2-Amino-tetrahydrobenzo[b]pyran,
ملخص المقالة :
A novel nanomagnetic material with a dimethylamino tag namely nano-Fe3O4@SiO2@R-NMe2 ([NFSRN]) was produced, and characterized by EDS, FT-IR, VSM, FE-SEM, XRD and TGA analyses. Then, it was applied as a highly effective and magnetically recyclable catalyst for the one-pot multi-component reaction of malononitrile, arylaldehydes and dimedone. Interestingly, in most entries, among the possible products which can be produced from the reactants, only 2-amino-tetrahydrobenzo[b]pyrans were obtained in high yields and relatively short times, and no other product was obtained.
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