Synthesis, characterization and using Fe3O4@SiO2@FeCl3 as a new nanocatalyst for aza-Michael reaction between amines and ethyl crotonate
الموضوعات : Iranian Journal of CatalysisHamid Parsa 1 , Mohammad Javad Taghizadeh 2 , Mojtaba Mossavi 3 , Jaber Hosseini 4
1 - Department of Chemistry, Faculty of Science, Imam Hossein University, Tehran 16597, Iran.
2 - Department of Chemistry, Faculty of Science, Imam Hossein University, Tehran 16597, Iran.
3 - Department of Chemistry, Faculty of Science, Imam Hossein University, Tehran 16597, Iran.
4 - Department of Chemistry, Faculty of Science, Imam Hossein University, Tehran 16597, Iran.
الکلمات المفتاحية: Aza-Michael reaction, Fe3O4@SiO2@FeCl3 nanocatalyst, α, β-Unsaturated carbonyl compounds,
ملخص المقالة :
In this article, recyclable Fe3O4@SiO2@FeCl3 was synthesized and entirely characterized by various techniques including XRD, FT-IR, SEM, EDX and VSM analysis. The catalytic ability of produced Fe3O4@SiO2@FeCl3 was studied in the aza-Michael reaction of diethyl amine and ethyl crotonate which lead to high yield of product. Also, this procedure was used to synthesize other derivatives resulted from different amines. Synthesized Fe3O4@SiO2@FeCl3 nanocatalyst has some great advantages such as easy preparation method, simple recovery and high efficiency.
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