3-Hydroxypropylammonium acetate (HPAA) ionic liquid: An effective acidic media in efficient conversion of anilines into aryl isocyanates
الموضوعات : Iranian Journal of Catalysis
Davood Azarifar
1
(Faculty of Chemistry, Bu-Ali Sina University, 65178, Hamedan, Iran)
Maryam Golbaghi
2
(Faculty of Chemistry, Bu-Ali Sina University, 65178, Hamedan, Iran)
Razieh Nejat-Yami
3
(Faculty of Chemistry, Tarbiat Modares University, Tehran, Iran)
الکلمات المفتاحية: aniline, Ionic Liquid, Isocyanates, 3-hydroxypropylammonium acetate, HPAA,
ملخص المقالة :
A simple and mild procedure for the conversion of anilines into aryl isocyanates is described using the 3-hydroxypropylammonium acetate (HPAA) ionic liquid as a novel and efficient media has been explored in the synthesis of aryl isocyanates from the reaction of substituted urea with sodium nitrite in a water immiscible solvent. This ionic liquid can be easily recovered and reused for many times without noticeable loss of activity.
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