L-Proline catalyzed synthesis of Betti bases and biscoumarin derivatives
الموضوعات : Iranian Journal of CatalysisSamaneh Zahiri 1 , Masoud Mokhtary 2 , Mogharab Torabi 3
1 - Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran
2 - Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran
3 - Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran
الکلمات المفتاحية: Biscoumarin, Multicomponent reaction, Betti base, L-proline, Mannich type reaction,
ملخص المقالة :
The direct three component modified Mannich reaction via condensation of aldehydes, 2-naphthol or 2,7-naphthalendiol and piperidine to generate Betti bases has been carried out over L-proline (20 mol%) with high efficiency under solvent free conditions at 70 OC. Also, the reaction of aromatic aldehyde and 4-hydroxycoumarin in the presence of L-proline (20 mol%) in the ethanol under reflux conditions, lead to biscoumarin derivatives
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