Sonochemical synthesis of undoped and Co-doped ZnO nanostructures and investigation of optical and photocatalytic properties
الموضوعات : Iranian Journal of CatalysisBahar Khodadadi 1 , Maryam Bordbar 2
1 - Department of Chemistry, Faculty of Science, University of Qom, Qom, Iran.
2 - Department of Chemistry, Faculty of Science, University of Qom, Qom, Iran.
الکلمات المفتاحية: Band gap, Sonochemical method, Phptocatalytic activity, ZnO nanostructure,
ملخص المقالة :
In this paper, undopedZnO and Co-ZnOnano structureswith different molar ratio of Cobalt have been synthesized by the sonochemical method. Structure have been characterized by Fourier Transform (FTIR) and UV–Vis spectroscopy,Scanning Electron Microscopy (SEM), Energy Dispersive Analytical X-Ray (EDAX), and X-Ray Diffraction (XRD) methods. Moreover, the direct band gap has been calculated by Tauc’s approach.Moreover, mean crystal size has been estimated by Scherrerequaton. Furthermore, photocatalytic activity for all samples has been investigated under UV irradiation in an aqueous medium. Compared with pure ZnO, the band gap of the Co-ZnOhas been shown decrease and it is dependent on the content of dopants. Also, photocatalytic activity improves in the presence of cobalt dopant.
[1] P. Mishra, R.S. Yadav, A.C. Pandey, Ultrason. Sonochem. 17 (2010) 560–565.
[2] Y. Yoshino, T. Makino, Y. Katayama, T. Hata, Vacuum 59 (2000) 538–545.
[3] M.H. Habibi, E. Askari, Iran. J. Catal. 1 (2011) 41–44.
[4] H. R. Pouretedal, M. Ahmadi, Iran J. Catal. 3 (2013) 149–155.
[5] M. Fu, Y. Li, S. wu, P. Lu, J. Liu, F. Dong, Appl. Surf. Sci. 258 (2011) 1587–1592.
[6] P. Jongnavakit, P. Amornpitoksuka, S. Suwanboon, N. Ndiege, App. Surf. Sci. 258 (2012) 8192–8198.
[7] B. Wang, J. Iqbal, X. Shan, G. Huang, H. Fu, R. Yu, D. Yu, Mater. Chem. Phys. 113 (2009) 103–106.
[8] R.S. Yadav, P. Mishra, A.C. Pandey, Ultrason. Sonochem. 15 (2008) 863–868.
[9] L. Vayssieres, Adv. Mater. 15 (2003) 464–466.
[10] L. Vayssieres, K. Keis, S. E. Lindquist, A. Hagfeldt, J. Phys. Chem. B 105 (2001) 3350–33502.
[11] L. Vayssieres, K. Keis, A. Hagfeldt, S. E. Linquist, Chem. Mater. 13 (2001) 4395– 4398.
[12] L.E. Greene, M. Law, J. Goldberger, F. Kim, J.C. Johnson, Y. Zhang, R.J. Saykally, P. Yang, Angew. Chem. Int. Edn. Engl. 42 (2003) 3031–3034.
[13] B. Lin, H.C. Zeng, J. Am. Chem. Soc. 125 (2003) 4430-4431.
[14] M. Samadi, H. Asghari Shivaee., M. Zanetti, A. Pourjavadic, A. Moshfegha J. Mol. Catal. A: Chem. 359 (2012) 42– 48.
[15] Y. Ni, X. Wei, J. Hong, Y. Ye, Mater. Sci. Eng. B 121 (2005) 42– 47.
[16] M. Bordbar, B. Khodadadi, N. Mollatayefe, A.Yeganeh- Faal, J. App. Chem. 8 (2013) 43– 47.
[17] M. Srivastava, A.K. Ojha, S. Chaubey, P.K. Sharma, A.C. Pandey, J. Alloy. Compd. 494 (2010) 275–284.
[18] A. Al-Hajry, A. Umar, Y.B. Hahn, D.H. Kim, Superlattice Microst. 45 (2009) 529–534.
[19] H. Fu, C. Pan, W. Yao, Y. Zhu, J. Phys. Chem. B 109 (2005) 22432–22439.
[20] R.A. Nyquist, C.L. Putzig, R.O. Kagel, M.A. Leugers, Academic press, 1971.
[21] R. Mohana, K. Krishnamoorthy S. Kima, Solid State Commun. 152 (2012) 375–380.
[22] J.C. Sin, S.M. Lam, K.T. Lee, A.R. Mohamed, Mater. Lett. 91 (2013) 1–4.
[23] X. Zhou, Y. Li, T. Peng, W. Xie, X. Zhao, Mater. Lett. 63 (2009) 1747–1749.
[24] S. Anandana, N. Ohashib, M. Miyauchi, Appl. Catal. B: Environ. 100 (2010) 502–509.
[25] B. Donkova, D. Dimitrov, M. Kostadinov, E. Mitkova, D. Mehandjiev, Mater. Chem. Phys. 123 (2010) 563-568.
[26] C. Wu, L. Shen, H. Yu, Y.C. Zhang, Q. Huang, Mater. Lett. 74 (2012) 236–238,
[27] J. Zhong, J. Li, X. He, J. Zeng, Y. Lu, W. Hu, K. Lin, Curr. Appl. Phys. 12 (2012) 998–1001.
[28] A. Patterson, Phys. Rev. 56 (1939) 978-982.
[29] X.C. Liu, E.W. Shi, Z.Z. Chen, H.W. Zhang, B. Xiao, L.X. Song, Appl. Phys. Lett. 88 (2006) 252501–252503.
[30] R. Hea, R. K. Hockingb, T. Tsuzukia, Mater. Chem. Phys. 132 (2012) 1035-1040.
[31] Y.H. Zheng, C.Q. Chen, Y.Y. Zhan, X.Y. Lin, Q. Zheng, K.M. Wei, J.F. Zhu, Y.J. Zhu, Inorg. Chem. 46 (2007) 6675-6682.
[32] N. Daneshvar, D. Salari, A.R. Khataee, J. Photochem. Photobiol. A: Chem. 162 (2004) 317-322.
[33] X. Qiu, G. Li, X. Sun, L. Li, X. Fu, Nanotechnology 19 (2008) 215703-21711.
[34] K.C. Barick, S. Singh, M. Aslam, D. Bahadur, Microporous Mesoporous Mater. 134 (2010) 195–202.
[35] L.Wang, Q. Hu., Z. Li, J. Guo, Y. Li, Mater. Lett. 79 (2012) 277–280.
