Phospho sulfonic acid: an efficient solid acid catalyst for the facile preparation of 1,4-dihydropyridines
الموضوعات : Iranian Journal of Catalysis
Sobhan Rezayati
1
(
Chemistry Department, Qaemshahr Branch, Islamic Azad University, Qaemshahr, I. R. Iran
)
Parisa Javanmardi
2
(
Chemistry Department, Qaemshahr Branch, Islamic Azad University, Qaemshahr, I. R. Iran
)
الکلمات المفتاحية: Aldehyde, Multi-component reactions, PO(OSO3H)3, Hantzsch synthesis, Heterogeneous solid acid,
ملخص المقالة :
A simple and mild one-pot three-component reaction for the preparation 1,4-dihydropyridines has been developed from various aldehyde substrates, 1,3-dicarbonyl compounds (dimedone) and ammonium acetate (Hantzsch method) in the presence of a catalytic amount of phospho sulfonic acid (PSA) as an efficient and heterogeneous solid acid in EtOH at room temperature. Preparation of PSA is straightforward and handling of the reagent is also easy. The attractive features of this protocol are: (i) The elimination of corrosive liquid acids; (ii) the use of an inexpensive and relatively non-toxic catalyst, and (iii) reusability of the catalyst.
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