A green protocol for synthesis of pyran annulated hetrocyclic systems using Na2SO4 as an efficient catalyst

الموضوعات : Iranian Journal of Catalysis

Malek Taher Maghsoodlou ¹ , Amin Masoumnia ² , Mir Rasul Mousavi ³ , Nourollah Hazeri ⁴ , Jasem Aboonajmi ⁵ , Sayyed Mostafa Habibi-Khorasani ⁶ , Shiva Kiaee ⁷

1 - Department of Chemistry, The University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran
2 - Department of Chemistry, The University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran
3 - Department of Chemistry, The University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran
4 - Department of Chemistry, The University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran
5 - Department of Chemistry, The University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran
6 - Department of Chemistry, The University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran
7 - Department of Chemistry, The University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran

تاريخ الإرسال : 08 الأربعاء , ذو القعدة, 1435 تاريخ التأكيد : 11 الأربعاء , صفر, 1436 تاريخ الإصدار : 14 الإثنين , شعبان, 1436

الکلمات المفتاحية: 4-hydroxycoumarin, Pyran annulated hetrocyclic systems, Na2SO4, Green protocol, Barbituric acid,

ملخص المقالة :

Na2SO4 as an inexpensive and effective catalyst has provided a green protocol for the synthesis of tetrahydrobenzo[b]pyran, pyrano[2,3-d]pyrimidinone and dihydropyrano[3,2c]chromene derivatives from the three-component domino reaction of aromatic aldehydes and malononitrile with 4-hydroxycoumarin/ dimedone/ barbituric acid in ethanol/water as a mixture of solvent that, this mixture entirely is green solvent. Products could simply be separated from the catalyst. Using neutral and mild conditions, short reaction time, environmentally benign procedure, high to excellent yields of the products and easy work-up without using column chromatography are the advantages of this method. By virtue of these advantages, sodium sulfate can be used as catalyst in the organic transformations.

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