Promoting effects of calcium on the performance of Cu-MgO catalyst in hydrogenation of furfuraldehyde
الموضوعات : Iranian Journal of CatalysisVahid Farzaneh 1 , Samira Shirvani 2 , Samahe Sadjadi 3 , Mohammad Ghashghaee 4
1 - Biomass Conversion Science and Technology (BCST) Division, Iran Polymer and Petrochemical Institute, P.O. Box 14975-115, Tehran, Iran.|
Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, P.O. Box 14975-112, Tehran, Iran.
2 - Biomass Conversion Science and Technology (BCST) Division, Iran Polymer and Petrochemical Institute, P.O. Box 14975-115, Tehran, Iran.|Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, P.O. Box 14975-112, Tehran, Iran.
3 - Biomass Conversion Science and Technology (BCST) Division, Iran Polymer and Petrochemical Institute, P.O. Box 14975-115, Tehran, Iran.|Gas Conversion Department, Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, P.O. Box 14975-112, Tehran, Iran.
4 - Biomass Conversion Science and Technology (BCST) Division, Iran Polymer and Petrochemical Institute, P.O. Box 14975-115, Tehran, Iran.|
Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, P.O. Box 14975-112, Tehran, Iran.
الکلمات المفتاحية: Heterogeneous catalyst, Hydrogenation, Furfuraldehyde, Furfuryl alcohol, Cu-MgO, Calcium promoter, Biomonomer,
ملخص المقالة :
In the present study, the effects of calcium doping on the performance of the co-precipitated Cu-MgO catalysts prepared with different calcium loadings in the selective hydrogenation of furfuraldehyde were investigated. The results proved that the addition of this promoter had a remarkable impact on the catalytic performance. The conversion of furfuraldehyde enhanced up to 83% and the furfuryl alcohol selectivity remained above 96% over the run length on the promoted Cu-Ca-MgO catalyst. However, the conversion level decreased to 60% after 240 min of operation period which was still superior with respect to the negligible conversion with the non-promoted Cu-MgO catalyst.
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