Fe3O4@SiO2 nanoparticles: An efficient, green and magnetically reusable catalyst for the one-pot synthesis of 14-aryl-14H-dibenzo[a,i]xanthene-8,13-dione derivatives

الموضوعات : Iranian Journal of Catalysis

Mohammad Ali Ghasemzadeh ¹ , Mina Azimi-Nasrabad ² , Javad Safaei-Ghomi ³

1 - Department of Chemistry, Qom Branch, Islamic Azad University, Qom, P.O. Box 37491-13191. R. Iran
2 - Department of Chemistry, Qom Branch, Islamic Azad University, Qom, P.O. Box 37491-13191. R. Iran
3 - Department of Chemistry, Qom Branch, Islamic Azad University, Qom, P.O. Box 37491-13191. R. Iran

تاريخ الإرسال : 27 الأحد , شعبان, 1436 تاريخ التأكيد : 14 الأحد , ذو الحجة, 1436 تاريخ الإصدار : 27 الإثنين , شوال, 1437

الکلمات المفتاحية: Nanoparticles, Multi-component reactions, Core-shell, Fe3O4@SiO2, Xanthene,

ملخص المقالة :

An efficient and eco-friendly method for the one-pot synthesis of 14-aryl-14H-dibenzo [a,i]xanthene-8,13-dione derivatives has been developed in the presence of Fe3O4@SiO2 core-shell nanoparticles. The multi-component reactions of 2-hydroxy-1,4-naphthoquinone, β-naphthol and aldehydes were efficiently catalyzed using novel nano-scale materials under reflux conditions. The present method offers several advantages such as environmentally benign, simple work-up, excellent yield of products, short reaction times, little catalyst loading and facile catalyst separation. The nanomagnetic catalyst could be readily recovered using a simple external magnet and reused several times without any significant loss in activity. The catalyst was fully characterized by FT-IR, SEM, XRD, EDX and VSM analysis.

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