Baker’s yeast catalyzed Henry reaction: Biocatalytic C-C bond formation
الموضوعات : Iranian Journal of CatalysisPrabhakar Shrivas 1 , Nitesh Punyapreddiwar 2 , Atul Wankhade 3 , Sangesh Zodape 4 , Umesh Pratap 5
1 - Department of Chemistry, Visvesvaraya National Institute of Technology, Nagpur, 440 010, India
2 - Department of Chemistry, Visvesvaraya National Institute of Technology, Nagpur, 440 010, India
3 - Department of Chemistry, Visvesvaraya National Institute of Technology, Nagpur, 440 010, India
4 - Department of Chemistry, Visvesvaraya National Institute of Technology, Nagpur, 440 010, India
5 - Department of Chemistry, Visvesvaraya National Institute of Technology, Nagpur, 440 010, India
الکلمات المفتاحية: Henry reaction, Biocatalysis, &beta, -Nitroalcohol, Baker’s yeast,
ملخص المقالة :
The C-C bond formation is an important reaction in organic synthesis to obtain value-added intermediates. Therefore, in this paper an attempt has been made to accelerate the Henry reaction (C-C bond formation) between aryl aldehydes and nitromethane using less expensive whole cell biocatalyst, baker’s yeast (BY). The scope of the methodology was also tested for the heteryl aldehyde i.e. 2-chloro-3-formyl quinoline to obtain the corresponding quinoline containing nitroalcohol. The developed protocol is highly efficient and completely environmentally friendly. The work addressed the issue of non-aqueous biocatalysis, since Henry reaction catalysed by baker's yeast has been carried out in ethanol.
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