Synthesis of novel tridentate ligand-based palladium catalyst and investigation of its reactivity towards Suzuki, Sonogashira and Heck coupling reactions

الموضوعات : Iranian Journal of Catalysis

Rajendran Nagarajan ¹ (Department of Chemistry, Kongju National University, Kongju, Chungnam, 32588, Republic of Korea)
Panneer Selvam Rajeswari ² (Department of Applied Chemistry, Karunya Institute of Technology and Sciences, Karunyar Nagar, Coimbatore, 641114, India)
Lourdusamy Emmanuvel ³ (Department of Applied Chemistry, Karunya Institute of Technology and Sciences, Karunyar Nagar, Coimbatore, 641114, India)

تاريخ الإرسال : 15 الجمعة , رمضان, 1441 تاريخ التأكيد : 23 السبت , صفر, 1442 تاريخ الإصدار : 16 الثلاثاء , ربيع الثاني, 1442

الکلمات المفتاحية: C-C Cross coupling, Pd complex, Tridentate ligand, Palladacycle,

ملخص المقالة :

We have demonstrated a simple and efficient route for the synthesis of a novel imine based tridentate ligand and its Pd-complex to investigate the C-C cross-coupling reactions, that involve column chromatography purification in only one step. The catalytic activity of the newly synthesized catalyst was studied for the Suzuki, Sonogashira and, Heck cross-coupling reactions under mild conditions. All synthesized molecules are thoroughly characterized by IR and NMR techniques. The pro-ligand was characterized by a single Crystal X-ray diffraction study. The catalyst has excellent activity and good yield was obtained with minimum catalyst loading. The obtained yields are good to excellent.

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