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کد مقاله : 699490 بازدید : 105 صفحه: 1 - 34

نوع مقاله: پژوهشی

مروری بر سلول‌های خورشیدی پروسکایت هالید فلز-آلی: چالش‌ها و فرصت‌ها

محورهای موضوعی : تحقیقات در علوم مهندسی سطح و نانو مواد

محمد بادروج 1 (گروه فیزیک، واحد دزفول، دانشگاه آزاد اسلامی، دزفول، ایران)

تاریخ دریافت : 1401/07/25 تاریخ پذیرش : 1401/09/20 تاریخ انتشار : 1401/09/01

کلید واژه: پایداری, سمیت, مواد پروسکایت, سلول‌های خورشیدی پروسکایت بدون سرب, پدیده پسماند,

چکیده مقاله :

سلول‌های خورشیدی مبتنی بر مواد پروسکایت، در سال های اخیر توجه زیادی را به خود جلب کرده‌اند. این فناوری‌ها، به دلیل توانایی در دستیابی به بازده بالا با صرف هزینه کم، موضوع تحقیقات متعددی را به خود اختصاص داده‌اند. بر این اساس، این تحقیق، با هدف دستیابی به بینش عمیق‌تر در این حوزه از فناوری، مروری جامع بر عوامل مؤثر بر فرآیندهای ساخت، دستاوردها و چالش‌های پیش روی سلول‌های خورشیدی پروسکایت هالید فلز-آلی دارد و راهکارهای بهبود عملکرد، افزایش پایداری و کاهش میزان سمیت لایه جاذب این نوع افزاره ها را به صورت گام به گام مورد مطالعه قرار می‌دهد. بررسی ها نشان داد که علاوه بر نوع روش لایه نشانی و نحوه معماری اجزاء، مهم‌ترین عوامل برای دستیابی به یک سلول خورشیدی پروسکایت با عملکرد فتوولتائیک بالا، بهبود ریخت شناسی، کاهش سد انرژی برای هسته سازی، کنترل رشد یکنواخت بلورهای پروسکایت و کاهش اثر پسماند می باشند و این پارامترها را می‌توان با استفاده از مهندسی حلال ها و مواد افزودنی، تنظیم متغیرهای پوشش‌دهی از قبیل دمای فرآوری و پسا فرآوری و مدیریت زمان واکنش ها بهینه کرد. همچنین، تحقیقات در خصوص جایگزینی عنصر سرب با سایر عناصر کم سمی تر نشان می دهد که تا کنون امیدوارکننده‌ترین نتایج برای سلول‌های خورشیدی پروسکایت مبتنی بر قلع، با بازده تبدیل توان حدود 12-9 % ، بدست آمده است. این بازده در مقایسه با پروسکایت‌های مبتنی بر سرب، که تا سال 2023 حدود 26 % است، هنوز قابل‌رقابت نیست و نیاز به تلاش های بیشتری در این حوزه از تحقیقات می باشد.

چکیده انگلیسی:

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