بررسی خواص نوری، مورفولوژی و اندازه نانو ذرات نقره تهیه شده با لیزر Nd:YAG نانوثانیه در مایع
محورهای موضوعی : روش ها و فرآیندهای نوین در تولید
احسان نادری سامانی
1
,
سید رضا شجاع رضوی
2
,
مهدی غلام پور
3
,
مهدی پولادزاده
4
,
حامد نادری سامانی
5
1 - تهران، بزرگراه شهید بابایی، لویزان، خیابان شعبانلو - دانشگاه مالک اشتر
2 - مجتمع مواد و فناوری های ساخت. دانشگاه صنعتی مالک اشتر تهران ایران
3 - گروه فیزیک، دانشکده علوم پایه، دانشگاه افسری امام علی (ع)
4 - دانشگاه صنعتی مالک اشتر، مجتمع دانشگاهی مواد و فناوری های ساخت
5 - دانشجوی دکتری، دانشگاه صنعتی مالک اشتر، مجتمع دانشگاهی مواد و فناوری های ساخت
کلید واژه: سنتز نانو ذرات نقره, فرایند فرسایش لیزری, محلول کلوئیدی,
چکیده مقاله :
در این مطالعه اثر طول‌موج، دمای محلول و محیط سنتز روی ماهیت نانو ذرات نقره تهیه شده به روش فرسایش لیزری در مایع (LAL) با استفاده از لیزر Nd:YAG نانوثانیه مورد بررسی قرار گرفت. نانو ذرات نقره با استفاده از روش LAL در طول‌موج‌های nm 532 و nm 1064، در دمای محیط و حمام یخ در آب مقطر سنتز شدند که بهترین نتایج مربوط به طول‌موج nm 1064 و دمای محیط بود. پس از یافتن طول‌موج و دمای بهینه (طول‌موج nm 1064 و دمای محیط)، سنتز نانو ذرات نقره در محیط‌های آب مقطر، استون، ستیل تری متیل آمونیوم کلرید (CTAC)، سدیم دودسیل سولفات (SDS) و پلی وینیل پیرولیدون (PVP) انجام گرفت. برای مشخصه یابی نانو ذرات سنتز شده از آنالیزهای طیف‌سنجی نوری مرئی – فرابنفش (UV-Vis)، طیف‌سنجی جذب اتمی (AAS)، پراش نور دینامیکی (DLS)، میکروسکپ الکترونی روبشی گسیل میدانی (FE-SEM)، میکروسکپ نیروی اتمی (AFM)، میکروسکپ الکترونی عبوری با بزرگنمایی بالا (HR-TEM) و الگوی پراش پرتو ایکس (XRD) استفاده شد. نتایج نشان داد که اندازه و بازده نانو ذرات نقره سنتز شده تحت تأثیر طول‌موج لیزر، دمای محلول و محیط سنتز است. نانو ذرات سنتز شده در محیط‌های مختلف دارای اندازه ذرات نانومتری و مورفولوژی کروی می‌باشند. بالاترین میزان بازده تولید نانو ذرات در محلول SDS برابر با ppm 8/33 است. میانگین اندازه نانو ذرات و بلورک‌های نانو ذرات نقره سنتز شده در محیط استون با توجه به آنالیزهای HR-TEM و XRD به ترتیب برابر با nm 65 و nm 44 به دست آمد.
In this study, the effect of wavelength, liquid temperature and synthesis environment on the nature of silver nanoparticles prepared by laser ablation in liquid (LAL) using nanosecond Nd:YAG laser was investigated. Silver nanoparticles were synthesized using the LAL method at wavelengths of 532 nm and 1064 nm, at ambient temperature and ice bath in distilled water, and the best results were related to the wavelength of 1064 nm and ambient temperature. After finding the optimal wavelength and temperature (wavelength 1064 nm and ambient temperature), silver nanoparticles were synthesized in distilled water, acetone, cetyltrimethylammonium chloride (CTAC), sodium dodecyl sulfate (SDS), and polyvinylpyrrolidone (PVP). For the characterization of synthesized nanoparticles from ultraviolet visible spectroscopy (UV-Vis), atomic absorption spectroscopy (AAS), dynamic light Scattering (DLS), field emission scanning electron microscopy (FE-SEM), atomic Force Microscopy (AFM) ), high Resolution-Transmission Electron Microscopy (HR-TEM) and X-ray diffraction (XRD) were used. The results showed that the size and yield of synthesized silver nanoparticles are affected by laser wavelength, liquid temperature and synthesis environment. Nanoparticles synthesized in different environments have nanometer particle size and spherical morphology. The highest production efficiency of nanoparticles in SDS solution equals 33.8 ppm. According to HR-TEM and XRD analysis, the size of nanoparticles and crystallite of silver nanoparticles synthesized in an acetone environment were 65 nm and 44 nm, respectively.
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