بررسی خواص الکتروشیمیایی و مکانیکی پیل سوختی اکسید جامد ساخته شده توسط چاپگر سه بعدی

محورهای موضوعی : روش ها و فرآیندهای نوین در تولید

کیوان میرزائی فشالمی ¹ , زهرا صادقیان ² , رامین ابراهیمی ³

1 - دانشجوی دکتری، گروه مهندسی مواد، دانشگاه شیراز، شیراز، ایران. مربی، گروه مهندسی، دانشگاه پیام نور، تهران، ایران
2 - دانشیار، گروه مهندسی مواد، پژوهشگاه صنعت نفت، تهران، ایران.
3 - استاد، گروه مهندسی مواد، دانشگاه شیراز، شیراز، ایران.

تاریخ دریافت : 1400/06/24 تاریخ پذیرش : 1400/11/26 تاریخ انتشار : 1401/04/01

کلید واژه: خواص مکانیکی, هدایت الکتریکی, پیل سوختی اکسید جامد, پرینتر سه بعدی, خواص الکتروشیمیایی,

چکیده مقاله :

تاکنون روش‌‌های متنوعی برای ساخت پیل‌های سوختی اکسید جامد معرفی شده‌اند. در این پژوهش از تکنولوژی چاپ سه بعدی (3 D printing) برای تولید پیل‌های سوختی اکسید استفاده گردیده است. در همین راستا ابتدا چاپگر سه بعدی مناسبی که توانایی چاپ دوغاب لایه‌های آند، کاتد و الکترولیت با ضخامت و سرعت مورد نظر را داشته باشد، ساخته شد. سپس دوغاب مناسب متشکل از مواد NiO-YSZ برای لایه‌ آند، YSZ برای لایه الکترولیت و LSM برای کاتد، به همراه حلال و افزودنی‌های مناسب تولید گردید و با استفاده از چاپگر سه بعدی لایه نشانی لایه‌ها صورت گرفت. پس از تشکیل پیل، خشک کردن و سپس تف‌جوشی1 لایه‌ها انجام شد. در ادامه برای تشخیص عناصر موجود، تعیین ریز ساختار، دانسیته و ضخامت لایه‌ها، آزمایش SEM، Mapping، EDS و XRD صورت گرفت. منحنی I-V-P با جریان ثابت اکسیژن نشان داد که در دمای OC800 بیشترین توان چگالی در حدود W/cm2 84/0 و در محدوده ولتاژ 5/ 0 ولت وجود دارد. منحنی امپدانس نیز تحت ولتاژ مدار باز و در فرکانس بالا، مقداری برابر 23/0 و در محدوده فرکانس پایین، مقدار 25/1 را نشان داد. با انجام آزمون کشش، مدول یانگ پیل GPa 111 و استحکام شکست و استحکام تسلیم به ترتیب در حدود MPa 137 و MPa 120 به دست آمد.

چکیده انگلیسی:

Nowadays, various methods have been introduced for the fabrication of solid oxide fuel cells (SOFC). In this research, 3D printing technology has been used to produce oxide fuel cells. First, a 3D printer was constructed that has the ability to print the slurry of anode, cathode and electrolyte layers with the desired thickness and speed. Then a suitable slurry consisting of NiO-YSZ materials was produced for the anode layer, YSZ for the electrolyte layer and LSM for the cathode, with suitable solvents and additives. After cell formation, drying and then sintering of the layers were performed. The composition and microstructure characterization of layers has been performed by XRD, SEM, Mapping, EDS. The I-V-P curve showed the maximum power is around 0.84 W / cm2 at 800 OC with constant oxygen. The impedance curve values under open-circuit voltage were 0.23 Ωcm-2 and 1.25 Ωcm-2 at high and low frequencies, respectively. The tensile experiments indicated values 111 GPa for Young modulus and 137 MPa and 120 MPa values for the fracture toughness and the yield strength, respectively.

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