The Effect of Hydrogen Bonding and π–π Stacking to Stabilization of 3D Networks of a New Proton Compound, (a-6-mpyH)(Hpyzd) H2O

Subject Areas : Journal of Physical & Theoretical Chemistry

R. Mohammadinasab ¹ (-)
M. Tabatabaee ² (-)
M. A. Seyed Sadjadi ³ (-)

Received: 2015-05-04 Accepted : 2015-05-04 Published : 2012-08-01

Keywords: (Hamp-6-pic)(Hpyzd).H2O, Proton transfer, hydrogen bonds, π…π stacking,

Abstract :

A new proton transfer compound, formulated as (Hamp-6-pic)(Hpyzd) ∙H2O (1), has been synthesized from the reaction of pyrazine-2,3-dicarboxylic acid (H2pyzd) and 2-amino-6-methyl pyridine (amp-6-pic), in 1:1 molar ratio. Extensive O−H×××O, N−H×××N and O−H×××O hydrogen bonds involving (Hamp-6-pic)+ cation, (Hpyzd)- anion and co-crystal water molecule٫ static electronic٫ and π…π stacking interactions form a three-dimensional network.

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The Effect of Hydrogen Bonding and π–π Stacking to Stabilization of 3D Networks of a New Proton Compound, (a-6-mpyH)(Hpyzd) H2O