Study on the Interaction of Dioxovanadium(V) with Nitrilotriacetic Acid at Different Ionic Strengths by Using Extended Debye-Hiickel Equation

Subject Areas : Journal of Physical & Theoretical Chemistry

K. Zare ¹ , S. Rezaienejad ²

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Received: 2015-05-09 Accepted : 2015-05-09 Published : 2008-05-01

Keywords: Complexation, Extended Debye-Htickel type Eq, NTA, Dioxovanadium(V),

Abstract :

In this research complexation of dioxovanadium(V) with nitrilotriacetic acid (NTA) at differentionic strengths (0.1 to 1.0 mol dm-3) of sodium perchlorate as supporting electrolyte and pH rangeof 1.00-2.50 at 25 °C has been investigated by a combination of potentiometric and UVspectrophotometric measurements. Stability constants of two species, V0211L- and VO2H2L havebeen calculated. Ionic strength dependence semi-empirical parameters for the dissociation andstability constants were derived on the basis of extended Debye-Htickel type equation.