Thermodynamic study of Cu(II) ion-selective membrane electrode based on his (N-salicylidene-3,32-diamino dip hen y sulfone

Subject Areas : Journal of Physical & Theoretical Chemistry

E. Baghdar ¹ , F. Fekri dar ² , M. Giahi ³ , S. Farhadi ⁴ , M. Aghaie ⁵

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Received: 2015-05-30 Accepted : 2015-05-30 Published : 2010-08-01

Keywords: Temperature coefficient: Mixed, Nernstian response,

Abstract :

The effect or temperature on the behavior of Cu(II) Mr electrode based on bis(N-sahcylidenc-3.3'-4iaminodiphenyl) sulfune(BSDDS) was studied. This electrode showed a good Nemstian response in the temperaturerange of 20-50 C. Also, the behavior of the synthesized electrode was inngigated in the mixed solvents'ethanol+water" and "dioxane +water'.

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Thermodynamic study of Cu(II) ion-selective membrane electrode based on his (N-salicylidene-3,32-diamino dip hen y sulfone