سنتز نانو ذرات اکسید فلزی مس - قلع به روش انفجار الکتریکی سیم و بررسی خواص ضد باکتری آن
محورهای موضوعی : فصلنامه علمی - پژوهشی مواد نوینداود یارعلی 1 , رضا احمدی 2 , رامین حسینی 3
1 - دانشجوی کارشناسی ارشد مهندسی مواد، دانشکده فنی مهندسی، دانشگاه بین المللی امام خمینی (ره)، قزوین، ایران
2 - استادیار، دانشکده فنی و مهندسی، گروه مواد وسرامیک، دانشگاه بین المللی امام خمینی (ره)، قزوین، ایران
3 - دانشیار، دانشکده فنی و مهندسی، گروه مهندسی بیوتکنولوژی، دانشگاه بین المللی امام خمینی (ره)، قزوین، ایران
کلید واژه: نانو ذره, انفجار الکتریکی سیم, اکسید مس - قلع, آنتی باکتریال,
چکیده مقاله :
به دلیل خواص فیزیکی- شیمیایی منحصر به فرد نانو ذرات در مهار رشد باکتری، پژوهش بر روی نانو ذرات و کاربردهایشان به عنوان عامل ضد میکروبی افزایش یافته است. در این بررسی نانو ذرات مس- قلع و اکسیدهای آن به روش انفجار الکتریکی در محیط آب بین الکترودهای مس- قلع سنتز شد. این روش امکان تهیه نانو ذرات اکسیدی و فلزی با نرخ تولید بالا و فعالیت سطحی زیاد را فراهم میآورد. نانو ذرات اکسید مس و اکسید قلع به عنوان نانو ذرات کاربردی با فعالیت ضد باکتری موثر شناخته شدهاند. مشخصهیابی نانو ذرات ساخته شده با استفاده از تکنیک پراش پرتو ایکس، طیف سنج مرئی- فرابنفش، میکروسکوپ الکترونی روبشی و آنالیز BET انجام شد. نتایج نشان داد با تغییر شدت جریان اعمالی، نانوذرات اکسید مس - قلع با اندازه میانگین حدود ۱۹ تا 5/37 نانومتر به روش انفجار الکتریکی سیم تشکیل شدند. فعالیت ضد باکتری نانوذرات در برابر باکتری اشرشیاکولی با استفاده از غلظتهای مختلف نمونههای نانو ذرات اکسید مس- قلع به روش تعیین چگالی نوری مورد بررسی قرار گرفت. نتایج نشان دادند که نانو ذرات اکسید مس- قلع دارای خاصیت ضد باکتری هستند و این خاصیت با افزایش غلظت نانو ذره در محیط مایع و کاهش متوسط اندازه دانه، افزایش مییابد.
Due to the unique physicochemical properties of nanoparticles with the ability to inhibit the growth of bacteria, research has increased on nanoparticles and their applications as the antimicrobial agents. In this study, nanoparticles of copper - tin oxide were synthesized via
electrical explosion in water between copper-tin electrodes. This method provides the possibility of producing oxide and metal nanoparticles with high production rates and high surface activity. Copper oxide and tin oxide nanoparticles are known as practical nanoparticles with antibacterial activity. Nanoparticles characterization was performed using the X-ray diffraction, scanning electron microscopy, UV-visible absorption recording and BET analysis. The results showed that by changing the intensity of the applied current, oxide copper - tin with an average size of about 19 to 37.5 nm were formed by electrical explosion of wire. Antibacterial activity of nanoparticles against the E. coli bacteria was evaluated by determining the optical density of various samples with different concentrations of tin and copper oxide nanoparticles. The results showed that the copper - tin oxide nanoparticles possess antibacterial properties and this activity enhances by increasing the concentration of nanoparticles in the liquid medium and reduction the average grain size.
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