Separation and Quantification of Hydrocarbons of LPG Using Novel MWCNT-Silica Gel Nanocomposite as Packed Column Adsorbent of Gas Chromatography

Subject Areas : Journal of Nanoanalysis

Seyed Mojtaba Mostafavi ¹ , Masoumeh Piryaei ² , Ahmad Rouhollahi ³ , Ali Mohajeri ⁴

1 - Department of Chemistry, K.N. Toosi University of Technology, Tehran, Iran
2 - Department of Biology, Faculty of Science, Payam Nour University, Tehran, Iran
3 - Department of Chemistry, K.N. Toosi University of Technology, Tehran, Iran
4 - Research Institute of Petroleum Industry, Tehran, Iran

Received: 2017-05-31 Accepted : 2017-05-31 Published : 2014-04-01

Keywords: nanocomposite, Gas Chromatography, Sol-gel process, MWCNTs-SiO2, LPG, Hydrocarbon, Alkanes,

Abstract :

In this study, a new silica gel based adsorbent was fabricated and its ability in separation and quantification of alkanes mixture was investigated. Silica gel (SiO2) is a polar absorbent which is mainly used to separate polar compounds. Also, the carbon materials such as activated carbon and recently carbon nanotube (CNTs), have been widely used for separation of nonpolar materials. Carbon nanotubes are nanosized carbon-based sorbents that have a high surface area and a large aspect ratio and are known to be stable at high temperatures. It is, therefore, conceivable to use of their unique properties in gas chromatography. In this work, a MWCNT-Silica gel nanocomposite was prepared by Sol-Gel process and it was used as stationary phase in gas chromatography for separation of alkanes mixture. In first part, ability of silica gel adsorbent was studied and then results were compared with new MWCNT-Silica gel nanocomposite. Finally, a quantitative investigation was done on a LPG sample and propane, 2-methylpropane, n-butane, 2,2-dimethylpropane, 2-methylbutane and n-pentane were measured by standard addition.