The Effect of Multi-Walled Carbon Nanotubes on CO2/N2 Separation Using Sulfonated Polyether Ether Ketone/Polyetherimide Nano Composite Membrane

Subject Areas : Chemical Engineering (Polymers)

Habibollah  Bahreini ¹ (Department of Chemical Engineering, Shahreza Branch, Islamic Azad University, Shahreza, Iran)
Elham  Ameri ² (Department of Chemical Engineering, Najafabad Branch, Islamic Azad University,Nagafabad,Iran)
Hassan  Ebadi-Dehaghani ³ (Department of Chemical Engineering, Shahreza Branch, Islamic Azad University, Shahreza, Iran)

Received: 2023-09-16 Accepted : 2023-11-27 Published : 2023-02-01

Keywords: gas separation, Membrane, Multi-walled carbon nanotubes, polyetherimide, Sulfonated Polyether Ether Ketone,

Abstract :

Membrane technology has attracted significant research attention due to its many advantages in gas separation. In the present study, Blended membranes were fabricated utilizing sulfonated poly (ether ether ketone) (SPEEK) and poly (etherimide) (PEI) with varying quantities of multi-wall carbon nanotubes (MWCNTs) (up to 2 wt.%). The membranes produced were analyzed using X-ray diffraction (XRD), scanning field emission electron microscopy (FESEM), and Fourier transformed infrared spectroscopy (FTIR). The impact of the SPEEK/PEI composition on membrane selectivity was examined at various feed pressures ranging from 2 to 8 bar. The selectivity and gas permeability values varied between the individual polymers and showed systematic fluctuations with changes in the SPEEK/PEI content in the blends. The incorporation of MWCNTs into the blend resulted in an enhancement of the CO2/ N2 selectivity. The membrane containing the same amount of SPEEK and PEI, along with 1 wt.% of MWCNTs (designated as SP55M1), exhibited an approximately 22% increase in the selectivity of CO2/N2 compared to the pristine membrane.

References:

[1] H. Ning, Z. Yang, D. Wang, Z. Meng, Y. Li, X. Ju, C. Wang, "Graphene-based semi-coke porous carbon with n-rich hierarchical sandwich-like structure for efficient separation of co2/n2", Microporous and Mesoporous Materials, Vol. 311, No.  2021, pp. 110700.

[2] A. Aydani, A. Brunetti, H. Maghsoudi, G. Barbieri, "Co2 separation from binary mixtures of ch4, n2, and h2 by using ssz-13 zeolite membrane", Separation and Purification Technology, Vol. 256, No.  2021, pp. 117796.

[3] J. Chang, C. Hou, D. Wan, X. Zhang, B. Xu, H. Tian, X. Wang, Q. Guo, "Enhanced co2 adsorption capacity of bi-amine co-tethered flue gas desulfurization gypsum with water of hydration", Journal of CO2 Utilization, Vol. 35, No.  2020, pp. 115-125.

[4] I. Akbarian, A. Fakhar, E. Ameri, M. Sadeghi, "Gas‐separation behavior of poly (ether sulfone)–poly (ethylene glycol) blend membranes", Journal of Applied Polymer Science, Vol. 135, No. 44, 2018, pp. 46845.

[5] G. Li, W. Kujawski, K. Knozowska, J. Kujawa, "The effects of pei hollow fiber substrate characteristics on pdms/pei hollow fiber membranes for co2/n2 separation", Membranes, Vol. 11, No. 1, 2021, pp. 56.

[6] E. Ameri, M. Sadeghi, N. Zarei, A. Pournaghshband, "Enhancement of the gas separation properties of polyurethane membranes by alumina nanoparticles", Journal of Membrane Science, Vol. 479, No.  2015, pp. 11-19.

[7] M.T. Ravanchi, T. Kaghazchi, A. Kargari, "Application of membrane separation processes in petrochemical industry: A review", Desalination, Vol. 235, No. 1-3, 2009, pp. 199-244.

[8] P. Pandey, R. Chauhan, "Membranes for gas separation", Progress in Polymer Science, Vol. 26, No. 6, 2001, pp. 853-893.

[9] H. Cong, M. Radosz, B.F. Towler, Y. Shen, "Polymer–inorganic nanocomposite membranes for gas separation", Separation and purification technology, Vol. 55, No. 3, 2007, pp. 281-291.

[10] A.Y. Alentiev, K. Loza, Y.P. Yampolskii, "Development of the methods for prediction of gas permeation parameters of glassy polymers: Polyimides as alternating co-polymers", journal of Membrane Science, Vol. 167, No. 1, 2000, pp. 91-106.

[11] A. Rybak, A. Rybak, S. Boncel, A. Kolanowska, W. Kaszuwara, S.D. Kolev, "Hybrid organic–inorganic membranes based on sulfonated poly (ether ether ketone) matrix and iron-encapsulated carbon nanotubes and their application in co 2 separation", RSC advances, Vol. 12, No. 21, 2022, pp. 13367-13380.

[12] B. Seoane, C. Téllez, J. Coronas, C. Staudt, "Nh2-mil-53 (al) and nh2-mil-101 (al) in sulfur-containing copolyimide mixed matrix membranes for gas separation", Separation and Purification Technology, Vol. 111, No.  2013, pp. 72-81.

[13] Y. Alqaheem, A. Alomair, "Recent developments in polyetherimide membrane for gas separation", Journal of the Chinese Chemical Society, Vol. 66, No. 12, 2019, pp. 1738-1744.

[14] H. Ahmadizadegan, S. Esmaielzadeh, "Fabrication and characterization of novel polyester thin‐film nanocomposite membranes achieved by functionalized sio2 nanoparticles for gas separation", Polymer Engineering & Science, Vol. 59, No. S1, 2019, pp. E237-E247.

[15] N.P. Esfahani, N. Koupaei, H. Bahreini, "Fabrication and characterization of a novel hydrogel network composed of polyvinyl alcohol/polyvinylpyrrolidone/nano-rgo as wound dressing application", Journal of Polymer Research, Vol. 30, No. 2, 2023, pp. 56.

[16] N. Ismail, A. Ismail, A. Mustafa, A. Zulhairun, F. Aziz, N. Bolong, A. Razali, "Polymer clay nanocomposites for gas separation: A review", Environ. Contam. Rev, Vol. 2, No.  2019, pp. 01-05.

[17] K. Zarshenas, A. Raisi, A. Aroujalian, "Mixed matrix membrane of nano-zeolite nax/poly (ether-block-amide) for gas separation applications", Journal of Membrane Science, Vol. 510, No.  2016, pp. 270-283.

[18] T. Eljaddi, J. Bouillon, D. Roizard, L. Lebrun, "Pebax-based composite membranes with high transport properties enhanced by zif-8 for co2 separation", Membranes, Vol. 12, No. 9, 2022, pp. 836.

[19] A.V. Mahenthiran, Z.A. Jawad, "A prospective concept on the fabrication of blend pes/peg/dmf/nmp mixed matrix membranes with functionalised carbon nanotubes for co2/n2 separation", Membranes, Vol. 11, No. 7, 2021, pp. 519.

[20] N. Azizi, M. Arzani, H.R. Mahdavi, T. Mohammadi, "Synthesis and characterization of poly (ether-block-amide) copolymers/multi-walled carbon nanotube nanocomposite membranes for co2/ch4 separation", Korean Journal of Chemical Engineering, Vol. 34, No. 9, 2017, pp. 2459-2470.

[21] A. Shameli, E. Ameri, "Synthesis of cross-linked pva membranes embedded with multi-wall carbon nanotubes and their application to esterification of acetic acid with methanol", Chemical Engineering Journal, Vol. 309, No.  2017, pp. 381-396.

[22] M. Salahchini Javanmardi, E. Ameri, "Pervaporation characteristics of pdms/pmhs nanocomposite membranes inclusive multi-walled carbon nanotubes for improvement of acetic acid–methanol esterification reaction", Polymer Bulletin, Vol. 77, No. 5, 2020, pp. 2591-2609.

[23] A.F. Ismail, P.S. Goh, S.M. Sanip, M. Aziz, "Transport and separation properties of carbon nanotube-mixed matrix membrane", Separation and Purification Technology, Vol. 70, No. 1, 2009, pp. 12-26.

[24] L. Li, J. Zhang, Y. Wang, "Sulfonated poly(ether ether ketone) membranes for direct methanol fuel cell", Journal of Membrane Science, Vol. 226, No. 1, 2003, pp. 159-167.

[25] R.Y.M. Huang, P. Shao, C.M. Burns, X.-s. Feng, "Sulfonation of poly(ether ether ketone)(peek): Kinetic study and characterization", Journal of Applied Polymer Science, Vol. 82, No.  2001, pp. 2651-2660.

[26] J. Jaafar, A.F. Ismail, A. Mustafa, "Physicochemical study of poly(ether ether ketone) electrolyte membranes sulfonated with mixtures of fuming sulfuric acid and sulfuric acid for direct methanol fuel cell application", Materials Science and Engineering: A, Vol. 460-461, No.  2007, pp. 475-484.

[27] Q. Xin, H. Wu, Z. Jiang, Y. Li, S. Wang, Q. Li, X. Li, X. Lu, X. Cao, J. Yang, "Speek/amine-functionalized tio2 submicrospheres mixed matrix membranes for co2 separation", Journal of Membrane Science, Vol. 467, No.  2014, pp. 23-35.

[28] H.R. Mahdavi, N. Azizi, T. Mohammadi, "Performance evaluation of a synthesized and characterized pebax1657/peg1000/γ-al2o3 membrane for co2/ch4 separation using response surface methodology", Journal of Polymer Research, Vol. 24, No. 5, 2017, pp. 67.

[29] B. Flaconnèche, J.M. Martin, M.H. Klopffer, "Transport properties of gases in polymers: Experimental methods", Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole, Vol. 56, No.  2001, pp. 245-259.

[30] K. Ghosal, B.D. Freeman, "Gas separation using polymer membranes: An overview", Polymers for advanced technologies, Vol. 5, No. 11, 1994, pp. 673-697.

[31] P. Xing, G.P. Robertson, M.D. Guiver, S.D. Mikhailenko, K. Wang, S. Kaliaguine, "Synthesis and characterization of sulfonated poly(ether ether ketone) for proton exchange membranes", Journal of Membrane Science, Vol. 229, No. 1, 2004, pp. 95-106.

[32] D.X. Luu, E.-B. Cho, O.H. Han, D. Kim, "Saxs and nmr analysis for the cast solvent effect on speek membrane properties", The Journal of Physical Chemistry B, Vol. 113, No. 30, 2009, pp. 10072-10076.

[33] V.S. Rangasamy, S. Thayumanasundaram, J.W. Seo, J.-P. Locquet, "Vibrational spectroscopic study of pure and silica-doped sulfonated poly(ether ether ketone) membranes", Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 138, No.  2015, pp. 693-699.

[34] J. Xi, Z. Li, L. Yu, B. Yin, L. Wang, L. Liu, X. Qiu, L. Chen, "Effect of degree of sulfonation and casting solvent on sulfonated poly(ether ether ketone) membrane for vanadium redox flow battery", Journal of Power Sources, Vol. 285, No.  2015, pp. 195-204.

[35] M. Rajagopalan, J.-H. Jeon, I.-K. Oh, "Electric-stimuli-responsive bending actuator based on sulfonated polyetherimide", Sensors and Actuators B: Chemical, Vol. 151, No. 1, 2010, pp. 198-204.

[36] V. Yadav, A. Rajput, P.P. Sharma, P.K. Jha, V. Kulshrestha, "Polyetherimide based anion exchange membranes for alkaline fuel cell: Better ion transport properties and stability", Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 588, No.  2020, pp. 124348.

[37] T. Ramanathan, F.T. Fisher, R.S. Ruoff, L.C. Brinson, "Amino-functionalized carbon nanotubes for binding to polymers and biological systems", Chemistry of Materials, Vol. 17, No. 6, 2005, pp. 1290-1295.

[38] L. Li, J. Wang, W. Liu, R. Wang, F. Yang, L. Hao, Z. Tianlu, W. Jiao, L. Jiang, "Remarkable improvement in interfacial shear strength of carbon fiber/epoxy composite by large‐scare sizing with epoxy sizing agent containing amine‐treated mwcnts", Polymer Composites, Vol. 39, No.  2018, pp. 2734-2742.

[39] P. Nie, C. Min, H.-J. Song, X. Chen, Z. Zhang, K. Zhao, "Preparation and tribological properties of polyimide/carboxyl-functionalized multi-walled carbon nanotube nanocomposite films under seawater lubrication", Tribology Letters, Vol. 58, No. 1, 2015, pp. 1-12.

[40] M. Rabiei, A. Palevicius, A. Monshi, S. Nasiri, A. Vilkauskas, G. Janusas, "Comparing methods for calculating nano crystal size of natural hydroxyapatite using x-ray diffraction", Nanomaterials, Vol. 10, No. 9, 2020, pp. 1627.

[41] E.M. Sadek, D.E. El-Nashar, A.A. Ward, S.M. Ahmed, "Study on the properties of multi-walled carbon nanotubes reinforced poly (vinyl alcohol) composites", Journal of Polymer Research, Vol. 25, No. 12, 2018, pp. 249.

[42] X. Yang, Y. He, G. Zeng, Y. Zhan, Y. Pan, H. Shi, Q. Chen, "Novel hydrophilic pvdf ultrafiltration membranes based on a zro2–multiwalled carbon nanotube hybrid for oil/water separation", Journal of Materials Science, Vol. 51, No. 19, 2016, pp. 8965-8976.

[43] S. Wang, Y. Liu, S. Huang, H. Wu, Y. Li, Z. Tian, Z. Jiang, "Pebax–peg–mwcnt hybrid membranes with enhanced co2 capture properties", Journal of Membrane Science, Vol. 460, No.  2014, pp. 62-70.

[44] Z. Han, A. Fina, "Thermal conductivity of carbon nanotubes and their polymer nanocomposites: A review", Progress in polymer science, Vol. 36, No. 7, 2011, pp. 914-944.

[45] A.A. Shamsabadi, A. Kargari, M.B. Babaheidari, S. Laki, H. Ajami, "Role of critical concentration of pei in nmp solutions on gas permeation characteristics of pei gas separation membranes", Journal of Industrial and Engineering Chemistry, Vol. 19, No. 2, 2013, pp. 677-685.

[46] Q. Xin, T. Liu, Z. Li, S. Wang, Y. Li, Z. Li, J. Ouyang, Z. Jiang, H. Wu, "Mixed matrix membranes composed of sulfonated poly(ether ether ketone) and a sulfonated metal–organic framework for gas separation", Journal of Membrane Science, Vol. 488, No. 2015, pp. 67-78.

[47] A.L. Khan, C. Klaysom, A. Gahlaut, X. Li, I.F. Vankelecom, "Speek and functionalized mesoporous mcm-41 mixed matrix membranes for co 2 separations", Journal of Materials Chemistry, Vol. 22, No. 37, 2012, pp. 20057-20064.

[48] C. Song, M. Mujahid, R. Li, S. Ahmad, Q. Liu, B. Zhang, Y. Kitamura, "Pebax/mwcnts-nh2 mixed matrix membranes for enhanced co2/n2 separation", Greenhouse Gases: Science and Technology, Vol. 10, No. 2, 2020, pp. 408-420.