Fabricating the Tribological Properties and Investigating of Ni3Al-MoS2 Composite Coating

Subject Areas : Surface Engineering

Mahdi  Mirzaaghaei ¹ (Student, department of Materials Engineering, Naghshe Jahan University, Isfahan, Iran)
Mohammad-Hossein  Enayati ² (Department of Materials Engineering, Isfahan University of Technology, Isfahan, 84154, Iran)
Mahdi  Ahmadi ³ (Department of Materials Engineering, Naghshe Jahan University, Isfahan, 77142, Iran)

Received: 2020-04-25 Accepted : 2020-07-30 Published : 2021-01-01

Keywords: Wear, Magnetron sputtering, Ni3Al, MoS2,

Abstract :

Self-lubricant coatings are among the newly improved type of coatings to reduce the coefficient of friction and protect the substrate in various conditions. Magnetron sputtering is the best technology to fabricate coatings with good morphology. In this paper, the tribological properties of magnetron sputtered Ni3Al-MoS2 coating on 4340 steel are reported. For this purpose, five tablets of Ni3Al-30 wt.% MoS2 were prepared as the target material and were placed in a copper holder. At last, we have sputtered from the target using the best sputtering condition to get a good morphology and microstructure of the coating. The morphology and microstructure of the coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The tribological properties of Ni3Al-MoS2 coating were investigated using a ball-on-disc tribometer at atmospheric conditions at room temperature. SEM was used to examine the morphology of the wear track after the ball-on-disc test. The Ni3Al-MoS2 composite coating showed lower frictions coefficient and higher wear resistance because of the hard Ni3Al matrix and soft MoS2 particles.

References:

[1] S. Sun, J. Chen, Y. Wang, L. Wang, and Z. Sun, "Structural sensitivity of MoS₂-based films in solid space lubrication," Surface Engineering, vol. 36, pp. 106-113, 2020/01/02 2020.

[2] Freschi, M., Di Virgilio, M., Zanardi, G., Mariani, M., Lecis, N., and Dotelli, G., 2021, “Employment of Micro- and Nano-WS2 Structures to Enhance the Tribological Properties of Copper Matrix Composites,” Lubricants, 9(5).

[3] H. Torres, H. Rojacz, L. Čoga, M. Kalin, and M. Rodríguez Ripoll, "Local mechanical and frictional properties of Ag/MoS₂-doped self-lubricating Ni-based laser claddings and resulting high temperature vacuum performance," Materials & Design, vol. 186, p. 108296, 2020/01/15/ 2020.

[4] M. S. Libório, G. B. Praxedes, L. L. F. Lima, I. G. Nascimento, R. R. M. Sousa, M. Naeem, et al., "Surface modification of M2 steel by combination of cathodic cage plasma deposition and magnetron sputtered MoS₂-TiN multilayer coatings," Surface and Coatings Technology, vol. 384, p. 125327, 2020/02/25/ 2020.

[5] H. Du, C. Sun, W. Hua, T. Wang, J. Gong, X. Jiang, et al., Structure, mechanical and sliding wear properties of WC–Co/MoS₂–Ni coatings by detonation gun spray, J. Mater. Sci. Eng: A. 445–446 (2007) 122-134.

[6] Rajesh Kumar, L., Saravanakumar, A., Bhuvaneswari, V., Jithin Karunan, M. P., Karthick Raja, N., and Karthi, P., 2020, “Tribological Behaviour of AA2219/MoS2 Metal Matrix Composites under Lubrication,” AIP Conf. Proc., 2207(February).

[7] Devaganesh, S., Kumar, P. K. D., Venkatesh, N., and Balaji, R., 2020, “Study on the Mechanical and Tribological Performances of Hybrid SiC-Al7075 Metal Matrix Composites,” J. Mater. Res. Technol., 9(3), pp. 3759–3766.

[8] Liu, C., Chen, Y., Qiu, L., Liu, H., Bai, M., and Xiao, P., 2020, “The Al-Enriched γ’-Ni3Al-Base Bond Coat for Thermal Barrier Coating Applications,” Corros. Sci., 167(2517), p. 108523.

[9] Yang, Z. W., Lian, J., Wang, J., Cai, X. Q., Wang, Y., Wang, D. P., Wang, Z. M., and Liu, Y. C., 2020, “Diffusion Bonding of Ni3Al-Based Alloy Using a Ni Interlayer,” J. Alloys Compd., 819, p. 153324.

[10] K. P. Furlan, J. D. B. de Mello, and A. N. Klein, "Self-lubricating composites containing MoS₂: A review," Tribology International, vol. 120, pp. 280-298, 2018/04/01/ 2018.

[11] S. Zhu, J. Cheng, Z. Qiao, and J. Yang, "High temperature solid-lubricating materials: A review," Tribology International, vol. 133, pp. 206-223, 2019/05/01/ 2019.

[12] Yuan, J., Ph, D., Wang, Q., Liu, X., Lou, S., Li, Q., and Wang, Z., 2020, “Microstructures and High-Temperature Wear Behavior of NiAl / WC-Fe x Coatings on Carbon Steel by Plasma Cladding,” J. Alloys Compd., 842, p. 155850.

[13] Shi, X., Song, S., Zhai, W., Wang, M., Xu, Z., Yao, J., Qamar ud Din, A., and Zhang, Q., 2014, “Tribological Behavior of Ni3Al Matrix Self-Lubricating Composites Containing WS2, Ag and HBN Tested from Room Temperature to 800°C,” Mater. Des., 55, pp. 75–84.

[14] Yao, Q., Jia, J., Chen, T., Xin, H., Shi, Y., He, N., Feng, X., Shi, P., and Lu, C., 2020, “High Temperature Tribological Behaviors and Wear Mechanisms of NiAl-MoO3/CuO Composite Coatings,” Surf. Coatings Technol., 395(March), p. 125910.

[15] Dong, C., Cui, Q., Gao, X., Jiang, D., Fu, Y., Wang, D., Weng, L., Hu, M., and Sun, J., 2020, “Tribological Property of MoS2-Cr3O4 Nanocomposite Films Prepared by PVD and Liquid Phase Synthesis,” Surf. Coatings Technol., 403(July), p. 126382.

[16] Mirzaaghaei, M., Enayati, M. H., and Ahmadi, M., 2016, “The Tribological Properties of Cu-Ni 3 Al-MoS2 Composite Coating Deposited by Magnetron Sputtering,” 4(4), pp. 37–45.

[17] A. Erdemir, in: B. Bhushan (Eds.), Modern Tribology Handbook, vol. II, CRC Press, Boca Raton, FL, 2001, p. 736.

[18] E. Arslan, F. Bülbül, A. Alsaran, A. Celik, and I. Efeoglu, The effect of deposition parameters and Ti content on structural and wear properties of MoS2Ti coatings, Wear 259 (2005) 814-819.

[19] F. Bülbül, İ. Efeoğlu, E. Arslan, The effect of bias voltage and working pressure on S/Mo ratio at MoS₂–Ti composite films, Appl. Surf. Sci. 253 (2007) 4415-4419.

[20] N. M. Renevier, V. C. Fox, D. G. Teer, J. Hampshire, Coating characteristics and tribological properties of sputter-deposited MoS2/metal composite coatings deposited by closed field unbalanced magnetron sputter ion plating, Surf. Coat. Technol. 127 (2000) 24-37.

[21] W. Heinke, A. Leyland, A. Matthews, G. Berg, C. Friedrich, E. Broszeit, Evaluation of PVD nitride coatings, using impact, scratch and Rockwell-C adhesion tests, Thin Solid Films 270 (1995) 431-438.

[22] S. Tokumaru and M. Hashimoto, "High resistivity AlOx thin films deposited by a novel two-step sputtering process," Surface and Coatings Technology, vol. 54-55, pp. 303-307, 1992/11/16/ 1992.

[23] Verein Deutscher Ingenieure Normen, VDI 3198, VDI-Verlag, Dusseldorf, 1991.

[24] Vidakis N., Antoniadis A., and Bilalis N., The VDI 3198 in dentationtest evaluation of areliable qualitative control for layered compounds. J . Mater. Proc. Technol., pp. 143-144, 2003.

[25] Heinke W., Leyland A., Matthews A., Berg G., Friedrich C., and Broszeit E., Evaluation of PVD nitrid ecoatings, using impact, scratch and Rockwell-C adhesion tests. Thin Solid Films., pp. 431-270, 1995.

[26] Brainard, W.A. (1969) The thermal stability and friction of the disulfides, diselenides and ditellurides of molybdenum and tungsten in vacuum (10^-9 to 10^-6 torr). NASA TN D-5141.

[27] H. E. Sliney, Solid lubricant materials for high temperatures—a review, Tribol. Int. 15 (1982) 303-315.

[28] S. V. Prasad, J. S. Zabinski, Tribology of tungsten disulphide (WS₂): characterization of wear-induced transfer films, J. Mater. Sci. Lett. 12 (1993) 1413-1415.

[29] T. W. Scharf, S. V. Prasad, Solid lubricants: a review, J. Mater. Sci. 48 (2010) 511-513.